Silver(I,III) oxide

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Silver(I,III) oxide
AgO-monoclinic-xtal-2x2x2-oxcol-3D-bs-17.png
Ag(I) Ag(III) O
Names
IUPAC name
silver(I,III) Oxide
Other names
tetrasilver tetroxide, silver peroxide, argentic oxide, silver suboxide, divasil
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.726 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-098-2
PubChem CID
UNII
  • InChI=1S/4Ag.4O
    Key: RARXNJBGGSMBMG-UHFFFAOYSA-N
  • [Ag]O[Ag].O=[Ag]O[Ag]=O
Properties
Ag4O4

Ag2O.Ag2O3

Molar mass 123.87 g/mol
Appearancegrey-black powder
diamagnetic
Density 7.48 g/cm3
Melting point >100 °C, decomposition
.0027 g/100 mL
Solubility soluble in alkalis
Hazards
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-acid.svg GHS-pictogram-exclam.svg
Danger
H272, H315, H319, H335
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Silver(I,III) oxide or tetrasilver tetroxide is the inorganic compound with the formula Ag4O4. It is a component of silver zinc batteries. It can be prepared by the slow addition of a silver(I) salt to a persulfate solution e.g. AgNO3 to a Na2S2O8 solution. [1] It adopts an unusual structure, being a mixed-valence compound. [2] It is a dark brown solid that decomposes with evolution of O2 in water. It dissolves in concentrated nitric acid to give brown solutions containing the Ag2+ ion. [3]

Contents

Structure

Although its empirical formula, AgO, suggests that the compound tetrasilver tetraoxide has silver in the +2 oxidation state, each unit has two monovalent silver atoms bonded to an oxygen atom, and two trivalent silver atoms bonded to three oxygen atoms, and it is in fact diamagnetic. X-ray diffraction studies show that the silver atoms adopt two different coordination environments, one having two collinear oxide neighbours and the other four coplanar oxide neighbours. [1] tetrasilver tetraoxide is therefore formulated as AgIAgIIIO2 [4] or Ag2O·Ag2O3. It has previously been called silver peroxide, which is incorrect since it does not contain the peroxide ion, O22−.

Uses

Tetrasilver tetroxide has been marketed under a trade name "Tetrasil." In 2010, the FDA issued a warning letter to an American company concerning the firm's marketing of Tetrasil and Genisil ointments of tetrasilver tetroxide for herpes and similar conditions. [5]

Related Research Articles

In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and plus (+) and minus (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name since it does not contain any words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae.

<span class="mw-page-title-main">Coordination complex</span> Molecule or ion containing ligands datively bonded to a central metallic atom

A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals, are coordination complexes.

<span class="mw-page-title-main">Oxide</span> Chemical compound where oxygen atoms are combined with atoms of other elements

An oxide is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 that protects the foil from further oxidation.

In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero. While fully ionic bonds are not found in nature, many bonds exhibit strong ionicity, making oxidation state a useful predictor of charge.

<span class="mw-page-title-main">Ferrous</span> The element iron in its +2 oxidation state

In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ferrous or the prefix ferro- is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl2). The adjective ferric is used instead for iron(III) salts, containing the cation Fe3+. The word ferrous is derived from the Latin word ferrum, meaning "iron".

<span class="mw-page-title-main">Oxidizing agent</span> Chemical compound used to oxidize another substance in a chemical reaction

An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens.

<span class="mw-page-title-main">Sodium thiosulfate</span> Chemical compound

Sodium thiosulfate is an inorganic compound with the formula Na2S2O3·(H2O)(x) .Typically it is available as the white or colorless pentahydrate, It is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications.

<span class="mw-page-title-main">Cyanate</span> Anion with formula OCN and charge –1

The cyanate ion is an anion with the chemical formula OCN. It is a resonance of three forms: [O−C≡N] (61%) ↔ [O=C=N] (30%) ↔ [O+≡C−N2−] (4%).

The coordination geometry of an atom is the geometrical pattern defined by the atoms around the central atom. The term is commonly applied in the field of inorganic chemistry, where diverse structures are observed. The coordination geometry depends on the number, not the type, of ligands bonded to the metal centre as well as their locations. The number of atoms bonded is the coordination number. The geometrical pattern can be described as a polyhedron where the vertices of the polyhedron are the centres of the coordinating atoms in the ligands.

<span class="mw-page-title-main">Silver oxide</span> Chemical compound

Silver oxide is the chemical compound with the formula Ag2O. It is a fine black or dark brown powder that is used to prepare other silver compounds.

<span class="mw-page-title-main">Silver(II) fluoride</span> Chemical compound

Silver(II) fluoride is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound - silver usually exists in its +1 oxidation state. It is used as a fluorinating agent.

<span class="mw-page-title-main">Uranate</span>

A uranate is a ternary oxide involving the element uranium in one of the oxidation states 4, 5 or 6. A typical chemical formula is MxUyOz, where M represents a cation. The uranium atom in uranates(VI) has two short collinear U–O bonds and either four or six more next nearest oxygen atoms. The structures are infinite lattice structures with the uranium atoms linked by bridging oxygen atoms.

<span class="mw-page-title-main">Keggin structure</span> Best known structural form for heteropoly acids

The Keggin structure is the best known structural form for heteropoly acids. It is the structural form of α-Keggin anions, which have a general formula of [XM12O40]n, where X is the heteroatom, M is the addendum atom, and O represents oxygen. The structure self-assembles in acidic aqueous solution and is a commonly used type of polyoxometalate catalysts.

<span class="mw-page-title-main">Oxygen compounds</span>

The oxidation state of oxygen is −2 in almost all known compounds of oxygen. The oxidation state −1 is found in a few compounds such as peroxides. Compounds containing oxygen in other oxidation states are very uncommon: −12 (superoxides), −13 (ozonides), 0, +12 (dioxygenyl), +1, and +2.

<span class="mw-page-title-main">Antimony tetroxide</span> Chemical compound

Antimony tetroxide is an inorganic compound with the formula Sb2O4. This material, which exists as the mineral cervantite, is white but reversibly yellows upon heating. The material, with empirical formula SbO2, is called antimony tetroxide to signify the presence of two kinds of Sb centers.

<span class="mw-page-title-main">Bromous acid</span> Chemical compound

Bromous acid is the inorganic compound with the formula of HBrO2. It is an unstable compound, although salts of its conjugate base – bromites – have been isolated. In acidic solution, bromites decompose to bromine.

Zinc compounds are chemical compounds containing the element zinc which is a member of the group 12 of the periodic table. The oxidation state of zinc in most compounds is the group oxidation state of +2. Zinc may be classified as a post-transition main group element with zinc(II). Zinc compounds are noteworthy for their nondescript appearance and behavior: they are generally colorless, do not readily engage in redox reactions, and generally adopt symmetrical structures.

Explosophores are functional groups in organic chemistry that give organic compounds explosive properties.

<span class="mw-page-title-main">Hydrogen polyoxide</span> Chemical compound

Hydrogen polyoxides are chemical compounds that consist only of hydrogen and oxygen atoms, are bonded exclusively by single bonds, and are acyclic. They can, therefore, be classed as hydrogen chalcogenides.

<span class="mw-page-title-main">Niobium(V) ethoxide</span> Chemical compound

Niobium(V) ethoxide is an metalorganic compound with formula Nb2(OC2H5)10. It is a colorless liquid that dissolves in some organic solvents but hydrolyzes readily. It is mainly used for the sol-gel processing of materials containing niobium oxides.

References

  1. 1 2 Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN   0-19-855370-6
  2. David Tudela "Silver(II) Oxide or Silver(I,III) Oxide?" J. Chem. Educ., 2008, volume 85, p 863. doi : 10.1021/ed085p863
  3. Peter Fischer, Martin Jansen "Electrochemical Syntheses of Binary Silver Oxides" 1995, vol. 30, pp. 50–55. doi : 10.1002/9780470132616.ch11
  4. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8. p. 1181.
  5. "FDA Warning Letter to Aidance Skincare and Topical Solutions, LLC | Quackwatch". 19 July 2010.