Indium(III) oxide

Last updated
Indium(III) oxide
Kristallstruktur Indiumoxid.png
Names
Other names
indium trioxide, indium sesquioxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.813 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-193-9
PubChem CID
UNII
  • InChI=1S/2In.3O/q2*+3;3*-2 Yes check.svgY
    Key: PJXISJQVUVHSOJ-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/2In.3O/q2*+3;3*-2
    Key: PJXISJQVUVHSOJ-UHFFFAOYAL
  • [O-2].[O-2].[O-2].[In+3].[In+3]
Properties
In2O3
Molar mass 277.64 g/mol
Appearanceyellowish green odorless crystals
Density 7.179 g/cm3
Melting point 1,910 °C (3,470 °F; 2,180 K)
insoluble
Band gap ~3 eV (300 K)
56.0·10−6 cm3/mol
Structure
Cubic, (Bixbyite) cI80
Ia3, No. 206
a = 1.0117(1) nm [1]
16 formula per cell
Hazards
GHS labelling: [2]
GHS-pictogram-exclam.svg GHS-pictogram-silhouette.svg
Danger
H315, H319, H335
P260, P261, P264, P270, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P314, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Indium(III) oxide (In2 O3) is a chemical compound, an amphoteric oxide of indium.

Contents

Physical properties

Crystal structure

Amorphous indium oxide is insoluble in water but soluble in acids, whereas crystalline indium oxide is insoluble in both water and acids. The crystalline form exists in two phases, the cubic (bixbyite type) [1] and rhombohedral (corundum type). Both phases have a band gap of about 3 eV. [3] [4] The parameters of the cubic phase are listed in the infobox.

The rhombohedral phase is produced at high temperatures and pressures or when using non-equilibrium growth methods. [5] It has a space group R3c No. 167, Pearson symbol hR30, a = 0.5487 nm, b = 0.5487 nm, c = 1.4510 nm, Z = 6 and calculated density 7.31 g/cm3. [6]

Conductivity and magnetism

Thin films of chromium-doped indium oxide (In2−xCrxO3) are a magnetic semiconductor displaying high-temperature ferromagnetism, single-phase crystal structure, and semiconductor behavior with high concentration of charge carriers. It has possible applications in spintronics as a material for spin injectors. [7]

Thin polycrystalline films of indium oxide doped with Zn2+ are highly conductive (conductivity ~105 S/m) and even superconductive at liquid helium temperatures. The superconducting transition temperature Tc depends on the doping and film structure and is below 3.3 K. [8]

Synthesis

Bulk samples can be prepared by heating indium(III) hydroxide or the nitrate, carbonate or sulfate. [9] Thin films of indium oxide can be prepared by sputtering of indium targets in an argon/oxygen atmosphere. They can be used as diffusion barriers ("barrier metals") in semiconductors, e.g. to inhibit diffusion between aluminium and silicon. [10]

Monocrystalline nanowires can be synthesized from indium oxide by laser ablation, allowing precise diameter control down to 10 nm. Field effect transistors were fabricated from those. [11] Indium oxide nanowires can serve as sensitive and specific redox protein sensors. [12] The sol–gel method is another way to prepare nanowires.[ citation needed ]

Indium oxide can serve as a semiconductor material, forming heterojunctions with p-InP, n-GaAs, n-Si, and other materials. A layer of indium oxide on a silicon substrate can be deposited from an indium trichloride solution, a method useful for manufacture of solar cells. [13]

Reactions

When heated to 700 °C, indium(III) oxide forms In2O, (called indium(I) oxide or indium suboxide), at 2000 °C it decomposes. [9] It is soluble in acids but not in alkali. [9] With ammonia at high temperature indium nitride is formed: [14]

In2O3 + 2 NH3 → 2 InN + 3 H2O

With K2O and indium metal the compound K5InO4 containing tetrahedral InO45− ions was prepared. [15] Reacting with a range of metal trioxides produces perovskites [16] for example:

In2O3 + Cr2O3 → 2InCrO3

Applications

Indium oxide is used in some types of batteries, thin film infrared reflectors transparent for visible light (hot mirrors), some optical coatings, and some antistatic coatings. In combination with tin dioxide, indium oxide forms indium tin oxide (also called tin doped indium oxide or ITO), a material used for transparent conductive coatings.

In semiconductors, indium oxide can be used as an n-type semiconductor used as a resistive element in integrated circuits. [17]

In histology, indium oxide is used as a part of some stain formulations.

See also

Related Research Articles

<span class="mw-page-title-main">Indium</span> Chemical element, symbol In and atomic number 49

Indium is a chemical element; it has symbol In and atomic number 49. It is a silvery-white post-transition metal and one of the softest elements. Chemically, indium is similar to gallium and thallium, and its properties are largely intermediate between the two. It was discovered in 1863 by Ferdinand Reich and Hieronymous Theodor Richter by spectroscopic methods and named for the indigo blue line in its spectrum.

A nanowire is a nanostructure in the form of a wire with the diameter of the order of a nanometre. More generally, nanowires can be defined as structures that have a thickness or diameter constrained to tens of nanometers or less and an unconstrained length. At these scales, quantum mechanical effects are important—which coined the term "quantum wires".

<span class="mw-page-title-main">Aluminium oxide</span> Chemical compound with formula Al2O3

Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al2O3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and applications. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire. Al2O3 is significant in its use to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point.

Indium tin oxide (ITO) is a ternary composition of indium, tin and oxygen in varying proportions. Depending on the oxygen content, it can be described as either a ceramic or an alloy. Indium tin oxide is typically encountered as an oxygen-saturated composition with a formulation of 74% In, 8% Sn, and 18% O by weight. Oxygen-saturated compositions are so typical that unsaturated compositions are termed oxygen-deficient ITO. It is transparent and colorless in thin layers, while in bulk form it is yellowish to gray. In the infrared region of the spectrum it acts as a metal-like mirror.

<span class="mw-page-title-main">Zinc oxide</span> White powder insoluble in water

Zinc oxide is an inorganic compound with the formula ZnO. It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cement, lubricants, paints, sunscreens, ointments, adhesives, sealants, pigments, foods, batteries, ferrites, fire retardants, semi conductors, and first-aid tapes. Although it occurs naturally as the mineral zincite, most zinc oxide is produced synthetically.

Magnetic semiconductors are semiconductor materials that exhibit both ferromagnetism and useful semiconductor properties. If implemented in devices, these materials could provide a new type of control of conduction. Whereas traditional electronics are based on control of charge carriers, practical magnetic semiconductors would also allow control of quantum spin state. This would theoretically provide near-total spin polarization, which is an important property for spintronics applications, e.g. spin transistors.

<span class="mw-page-title-main">Tin(IV) oxide</span> Chemical compound known as stannic oxide, cassiterite and tin ore

Tin(IV) oxide, also known as stannic oxide, is the inorganic compound with the formula SnO2. The mineral form of SnO2 is called cassiterite, and this is the main ore of tin. With many other names, this oxide of tin is an important material in tin chemistry. It is a colourless, diamagnetic, amphoteric solid.

Hybrid solar cells combine advantages of both organic and inorganic semiconductors. Hybrid photovoltaics have organic materials that consist of conjugated polymers that absorb light as the donor and transport holes. Inorganic materials in hybrid cells are used as the acceptor and electron transporter in the structure. The hybrid photovoltaic devices have a potential for not only low-cost by roll-to-roll processing but also for scalable solar power conversion.

<span class="mw-page-title-main">Vanadium(IV) oxide</span> Chemical compound

Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO2. It is a dark blue solid. Vanadium(IV) dioxide is amphoteric, dissolving in non-oxidising acids to give the blue vanadyl ion, [VO]2+ and in alkali to give the brown [V4O9]2− ion, or at high pH [VO4]4−. VO2 has a phase transition very close to room temperature (~68 °C (341 K)). Electrical resistivity, opacity, etc, can change up several orders. Owing to these properties, it has been used in surface coating, sensors, and imaging. Potential applications include use in memory devices, phase-change switches, passive radiative cooling applications, such as smart windows and roofs, that cool or warm depending on temperature, aerospace communication systems and neuromorphic computing.

<span class="mw-page-title-main">Gallium(III) oxide</span> Chemical compound

Gallium(III) oxide is an inorganic compound and ultra-wide-bandgap semiconductor with the formula Ga2O3. It is actively studied for applications in power electronics, phosphors, and gas sensing. The compound has several polymorphs, of which the monoclinic β-phase is the most stable. The β-phase’s bandgap of 4.7–4.9 eV and large-area, native substrates make it a promising competitor to GaN and SiC-based power electronics applications and solar-blind UV photodetectors. The orthorhombic ĸ-Ga2O3 is the second most stable polymorph. The ĸ-phase has shown instability of subsurface doping density under thermal exposure. Ga2O3 exhibits reduced thermal conductivity and electron mobility by an order of magnitude compared to GaN and SiC, but is predicted to be significantly more cost-effective due to being the only wide-bandgap material capable of being grown from melt. β-Ga2O3 is thought to be radiation-hard, which makes it promising for military and space applications.

Indium(III) sulfate (In2(SO4)3) is a sulfate salt of the metal indium. It is a sesquisulfate, meaning that the sulfate group occurs 11/2 times as much as the metal. It may be formed by the reaction of indium, its oxide, or its carbonate with sulfuric acid. An excess of strong acid is required, otherwise insoluble basic salts are formed. As a solid indium sulfate can be anhydrous, or take the form of a pentahydrate with five water molecules or a nonahydrate with nine molecules of water. Indium sulfate is used in the production of indium or indium containing substances. Indium sulfate also can be found in basic salts, acidic salts or double salts including indium alum.

Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction () with a magnitude of 90–95 μC/cm2.

Organic photovoltaic devices (OPVs) are fabricated from thin films of organic semiconductors, such as polymers and small-molecule compounds, and are typically on the order of 100 nm thick. Because polymer based OPVs can be made using a coating process such as spin coating or inkjet printing, they are an attractive option for inexpensively covering large areas as well as flexible plastic surfaces. A promising low cost alternative to conventional solar cells made of crystalline silicon, there is a large amount of research being dedicated throughout industry and academia towards developing OPVs and increasing their power conversion efficiency.

<span class="mw-page-title-main">Transparent conducting film</span> Optically transparent and electrically conductive material

Transparent conducting films (TCFs) are thin films of optically transparent and electrically conductive material. They are an important component in a number of electronic devices including liquid-crystal displays, OLEDs, touchscreens and photovoltaics. While indium tin oxide (ITO) is the most widely used, alternatives include wider-spectrum transparent conductive oxides (TCOs), conductive polymers, metal grids and random metallic networks, carbon nanotubes (CNT), graphene, nanowire meshes and ultra thin metal films.

<span class="mw-page-title-main">Allotropes of boron</span> Materials made only out of boron

Boron can be prepared in several crystalline and amorphous forms. Well known crystalline forms are α-rhombohedral (α-R), β-rhombohedral (β-R), and β-tetragonal (β-T). In special circumstances, boron can also be synthesized in the form of its α-tetragonal (α-T) and γ-orthorhombic (γ) allotropes. Two amorphous forms, one a finely divided powder and the other a glassy solid, are also known. Although at least 14 more allotropes have been reported, these other forms are based on tenuous evidence or have not been experimentally confirmed, or are thought to represent mixed allotropes, or boron frameworks stabilized by impurities. Whereas the β-rhombohedral phase is the most stable and the others are metastable, the transformation rate is negligible at room temperature, and thus all five phases can exist at ambient conditions. Amorphous powder boron and polycrystalline β-rhombohedral boron are the most common forms. The latter allotrope is a very hard grey material, about ten percent lighter than aluminium and with a melting point (2080 °C) several hundred degrees higher than that of steel.

C<sub>70</sub> fullerene Chemical compound

C70 fullerene is the fullerene molecule consisting of 70 carbon atoms. It is a cage-like fused-ring structure which resembles a rugby ball, made of 25 hexagons and 12 pentagons, with a carbon atom at the vertices of each polygon and a bond along each polygon edge. A related fullerene molecule, named buckminsterfullerene (or C60 fullerene) consists of 60 carbon atoms.

<span class="mw-page-title-main">Nickel(II) titanate</span> Chemical compound

Nickel(II) titanate, also known as nickel titanium oxide, is an inorganic compound with the chemical formula NiTiO3. It is a coordination compound between nickel(II), titanium(IV) and oxide ions. It has the appearance of a yellow powder. Nickel(II) titanate has been used as a catalyst for toluene oxidation.

Indium(III) hydroxide is the chemical compound with the formula In(OH)3. Its prime use is as a precursor to indium(III) oxide, In2O3. It is sometimes found as the rare mineral dzhalindite.

Corundum is the name for a structure prototype in inorganic solids, derived from the namesake polymorph of aluminum oxide (α-Al2O3). Other compounds, especially among the inorganic solids, exist in corundum structure, either in ambient or other conditions. Corundum structures are associated with metal-insulator transition, ferroelectricity, polar magnetism, and magnetoelectric effects.

References

  1. 1 2 Marezio, M. (1966). "Refinement of the crystal structure of In2O3 at two wavelengths". Acta Crystallographica. 20 (6): 723–728. doi:10.1107/S0365110X66001749.
  2. "Indium oxide". pubchem.ncbi.nlm.nih.gov.
  3. Walsh, A; et al. (2008). "Nature of the Band Gap of In2O3 Revealed by First-Principles Calculations and X-Ray Spectroscopy" (PDF). Physical Review Letters. 100 (16): 167402. Bibcode:2008PhRvL.100p7402W. doi:10.1103/PhysRevLett.100.167402. PMID   18518246. Archived from the original (PDF) on 2017-12-15. Retrieved 2016-11-25.
  4. King, P. D. C.; Fuchs, F.; et al. (2009). "Band gap, electronic structure, and surface electron accumulation of cubic and rhombohedral In2O3" (PDF). Physical Review B. 79 (20): 205211. Bibcode:2009PhRvB..79t5211K. doi:10.1103/PhysRevB.79.205211. S2CID   53118924. Archived from the original (PDF) on 2019-12-31.
  5. The Minerals Metals & Materials Society (Tms); The Minerals, Metals & Materials Society (TMS) (6 April 2011). TMS 2011 140th Annual Meeting and Exhibition, General Paper Selections. John Wiley and Sons. pp. 51–. ISBN   978-1-118-06215-9 . Retrieved 23 September 2011.
  6. Prewitt, Charles T.; Shannon, Robert D.; Rogers, Donald Burl; Sleight, Arthur W. (1969). "C rare earth oxide-corundum transition and crystal chemistry of oxides having the corundum structure". Inorganic Chemistry. 8 (9): 1985–1993. doi:10.1021/ic50079a033.
  7. "New Material Puts Its Own Spin on Electronics". Biomedical Instrumentation & Technology. 40 (4): 267. 2006. doi:10.2345/i0899-8205-40-4-267.1.
  8. Makise, Kazumasa; Kokubo, Nobuhito; Takada, Satoshi; Yamaguti, Takashi; Ogura, Syunsuke; Yamada, Kazumasa; Shinozaki, Bunjyu; Yano, Koki; et al. (2008). "Superconductivity in transparent zinc-doped In2O3 films having low carrier density". Science and Technology of Advanced Materials. 9 (4): 044208. Bibcode:2008STAdM...9d4208M. doi:10.1088/1468-6996/9/4/044208. PMC   5099639 . PMID   27878025.
  9. 1 2 3 Downs, Anthony John (1993). Chemistry of aluminium, gallium, indium, and thallium. Springer. ISBN   0-7514-0103-X.
  10. Kolawa, E. and Garland, C. and Tran, L. and Nieh, C. W. and Molarius, J. M. and Flick, W. and Nicolet, M.-A. and Wei, J. (1988). "Indium oxide diffusion barriers for Al/Si metallizations". Applied Physics Letters. 53 (26): 2644–2646. Bibcode:1988ApPhL..53.2644K. doi: 10.1063/1.100541 .{{cite journal}}: CS1 maint: multiple names: authors list (link)
  11. Li, C; Zhang, D; Han, S; Liu, X; Tang, T; Lei, B; Liu, Z; Zhou, C (2003). "Synthesis, Electronic Properties, and Applications of Indium Oxide Nanowires". Annals of the New York Academy of Sciences. 1006 (1): 104–21. Bibcode:2003NYASA1006..104L. doi:10.1196/annals.1292.007. PMID   14976013. S2CID   5176429.
  12. "Applying Indium Oxide Nanowires as Sensitive and Specific Redox Protein Sensors". Foresight Nanotech Institute. Archived from the original on 2008-08-08. Retrieved 2008-10-29.
  13. Feng, Tom and Ghosh, Amal K. (1984) "Method for forming indium oxide/n-silicon heterojunction solar cells" U.S. patent 4,436,765
  14. Wiberg, Egon and Holleman, Arnold Frederick (2001) Inorganic Chemistry, Elsevier ISBN   0123526515
  15. Lulei, M.; Hoppe, R. (1994). "Über "Orthoindate" der Alkalimetalle: Zur Kenntnis von K5[InO4]". Zeitschrift für anorganische und allgemeine Chemie. 620 (2): 210–224. doi:10.1002/zaac.19946200205.
  16. Shannon, Robert D. (1967). "Synthesis of some new perovskites containing indium and thallium". Inorganic Chemistry. 6 (8): 1474–1478. doi:10.1021/ic50054a009. ISSN   0020-1669.
  17. "In2O3 (Indium Oxide)". CeramicMaterials.info. Archived from the original on 2008-06-30. Retrieved 2008-10-29.