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Ancylite | |
---|---|
![]() Nenadkevichite with ancylite crystals on the side | |
General | |
Category | Carbonate mineral |
Formula (repeating unit) | Sr(Ce,La)(CO3)2(OH)·H2O |
IMA symbol | Anc [1] |
Strunz classification | 5.DC.05 |
Dana classification | 16b.1.1.1 |
Crystal system | Orthorhombic |
Crystal class | Dipyramidal (mmm) H-M symbol: (2/m 2/m 2/m) |
Space group | Pmcn |
Identification | |
Color | Light yellow, orange-yellow, yellow-brown, grey |
Cleavage | None |
Fracture | Splintery |
Tenacity | Brittle |
Mohs scale hardness | 4–4.5 |
Luster | Dull |
Streak | White |
Diaphaneity | Translucent |
Density | 3.95 g/cm3 |
Ancylite is a group of hydrous strontium carbonate minerals containing cerium, lanthanum and minor amounts of other rare-earth elements. The chemical formula is Sr(Ce,La)(CO3)2(OH)·H2O with ancylite-Ce enriched in cerium and ancylite-La in lanthanum. [2] [3]
Ancylite was first described in 1899 for an occurrence in the Narsarsuk pegmatite in west Greenland and named from the Ancient Greek : αυκιλος for curved in reference to its rounded or distorted crystal form. [2] [4]
Euxenite, or euxenite-(Y), is a brownish black mineral with a metallic luster.
Gadolinite, sometimes known as ytterbite, is a silicate mineral consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with the formula (Ce,La,Nd,Y)2FeBe2Si2O10. It is called gadolinite-(Ce) or gadolinite-(Y), depending on the prominent composing element. It may contain 35.5% yttria sub-group rare earths, 2.2% ceria earths, as much as to 11.6% BeO, and traces of thorium. It is found in Sweden, Norway, and the US.
Allanite (also called orthite) is a sorosilicate group of minerals within the broader epidote group that contain a significant amount of rare-earth elements. The mineral occurs mainly in metamorphosed clay-rich sediments and felsic igneous rocks. It has the general formula A2M3Si3O12[OH], where the A sites can contain large cations such as Ca2+, Sr2+, and rare-earth elements, and the M sites admit Al3+, Fe3+, Mn3+, Fe2+, or Mg2+ among others. However, a large amount of additional elements, including Th, U, Be, Zr, P, Ba, Cr and others may be present in the mineral. The International Mineralogical Association lists four minerals in the allanite group, each recognized as a unique mineral: allanite-(Ce), allanite-(La), allanite-(Nd), and allanite-(Y), depending on the dominant rare earth present: cerium, lanthanum, neodymium or yttrium.
Abenakiite-(Ce) is a mineral of sodium, cerium, neodymium, lanthanum, praseodymium, thorium, samarium, oxygen, sulfur, carbon, phosphorus, and silicon with a chemical formula Na26Ce6(SiO3)6(PO4)6(CO3)6(S4+O2)O. The silicate groups may be given as the cyclic Si6O18 grouping. The mineral is named after the Abenaki, an Algonquian Indian tribe of New England. Its Mohs scale rating is 4 to 5.
Aeschynite-(Ce) is a rare earth mineral of cerium, calcium, iron, thorium, titanium, niobium, oxygen, and hydrogen with chemical formula (Ce,Ca,Fe,Th)(Ti,Nb)2(O,OH)6. Its name comes from the Greek word αισχύνη ("aeschyne") for "shame" because early chemists had difficulty with separations of titanium from zirconium.
Cerite is a complex silicate mineral group containing cerium, formula (Ce,La,Ca)
9(Mg,Fe3+
)(SiO
4)
6(SiO
3OH)(OH)
3. The cerium and lanthanum content varies with the Ce rich species and the La rich species. Analysis of a sample from the Mountain Pass carbonatite gave 35.05% Ce
2O
3 and 30.04% La
2O
3.
Kukharenkoite-(Ce) is a barium cerium fluoride carbonate mineral, formula Ba2CeF(CO3)3. It was identified from samples found in the Mont-Saint-Hilaire alkaline intrusive complex, Quebec, and the Khibiny Massif, Kola peninsula, Russia. It was named for Russian mineralogist Alexander A. Kukharenko (1914–1993).
Mckelveyite-(Y) is a hydrated sodium, barium, yttrium, and uranium–containing carbonate mineral, with the chemical formula Ba3Na(Ca,U)Y(CO3)6·3H2O.
Loparite-(Ce) is a granular, brittle oxide mineral of the perovskite class. It is black to dark grey and may appear grey to white in reflected light on polished thin section with reddish brown internal reflections. It has the chemical formula of (Ce,Na,Ca)(Ti,Nb)O3. Nioboloparite is a variation of Loparite-(Ce) containing niobium.
Dollaseite-(Ce) is a sorosilicate end-member epidote rare-earth mineral which was discovered by Per Geijer (1927) in the Ostanmossa mine, Norberg district, Sweden. Dollaseite-(Ce), although not very well known, is part of a broad epidote group of minerals which are primarily silicates, the most abundant type of minerals on earth. Dollaseite-(Ce) forms as dark-brown subhedral crystals primarily in Swedish mines. With the ideal chemical formula, CaREE3+
Mg
2AlSi
3O
11,(OH)F, dollaseite-(Ce) can be partially identified by its content of the rare earth element cerium.
Stillwellite-(Ce) is a rare-earth boro-silicate mineral with chemical formula (Ce,La,Ca)BSiO5.
Zirsilite-(Ce) is a very rare mineral of the eudialyte group, with formula (Na,□)12(Ce,Na)3Ca6Mn3Zr3NbSi(Si9O27)2(Si3O9)2O(OH)3(CO3)·H2O. The original formula was extended to show the presence of cyclic silicate groups and the presence of silicon at the M4 site, according to the nomenclature of the eudialyte group.according to the nomenclature of eudialyte group. Zirsilite-(Ce) differs from carbokentbrooksite in cerium-dominance over sodium only. Both minerals are intimately associated. The only other currently known representative of the eudialyte group having rare earth elements (in particular cerium, as suggested by the "-Ce)" Levinson suffix in the name) in dominance is johnsenite-(Ce).
Ferrokentbrooksite is a moderately rare mineral of the eudialyte group, with formula Na15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3(Cl,F,OH)2. The original formula was extended form to show the presence of cyclic silicate groups and presence of silicon at the M4 site, according to the nomenclature of eudialyte group. As suggested by its name, it is the (ferrous) iron analogue of kentbrooksite. When compared to the latter, it is also chlorine-dominant instead of being fluorine-dominant. The original (holotype) material is also relatively enriched in rare earth elements, including cerium and yttrium.
Mogovidite is a very rare mineral of the eudialyte group, with formula Na9(Ca,Na)6Ca6(Fe3+,Fe2+)2Zr3[]Si(Si9O27)2(Si3O9)2(CO3)(OH,H2O)4. The formula given is based on the original one but extended to show the presence of cyclic silicate groups. It is similar to feklichevite, differing from it in the presence of essential vacancies and carbonate group. Another specific feature is the dominance of ferric iron - a feature shared with other eudialyte-group members, including feklichevite, fengchengite, golyshevite and ikranite. Similarly to golyshevite, it is calcium-dominant, however on three sites: M(1), N(3) and N(4). It has a molecular mass of 3,066.24 gm.
Florencite-(Sm) is a very rare mineral of the plumbogummite group (alunite supergroup) with simplified formula SmAl3(PO4)2(OH)6. Samarium in florencite-(Sm) is substituted by other rare earth elements, mostly neodymium. It does not form separate crystals, but is found as zones in florencite-(Ce), which is cerium-dominant member of the plumbogummite group. Florencite-(Sm) is also a samarium-analogue of florencite-(La) (lanthanum-dominant) and waylandite (bismuth-dominant), both being aluminium-rich minerals.
Anzaite-(Ce) is a rare-earth element (REE) oxide mineral with the formula Ce4Fe2+Ti6O18(OH)2. An example of chemically related mineral is lucasite-(Ce), although it contains no iron. Cerium in anzaite-(Ce) is mainly substituted by neodymium, lanthanum, calcium and praseodymium. Titanium is substituted by niobium. Trace elements include thorium. The mineral is monoclinic, space group C2/m. Anzaite-(Ce) is hydrothermal mineral found in a carbonatite from the mineralogically prolific Kola Peninsula. The mineral name honors Anatoly N. Zaitsev, who is known for studies of carbonatites and REE.
Cerianite-(Ce) is a relatively rare oxide mineral, belonging to uraninite group with the formula (Ce,Th)O
2. It is one of a few currently known minerals containing essential tetravalent cerium, the other examples being stetindite and dyrnaesite-(La).
Parisite-(La) is mineral discovered by Daniel Atencio of the University of São Paulo and colleagues in the Mula claim, Bahia, Brazil. Parisite-(La) is the lanthanum analog of parisite-(Ce), which has the same structure, but with cerium substituted for lanthanum. Parisite-(La) is chemically similar to synchysite-(La).
Monazite-(Ce) is the most common representative of the monazite group. It is the cerium-dominant analogue of monazite-(La), monazite-(Nd), and monazite-(Sm). It is also the phosphorus analogue of gasparite-(Ce). The group contains simple rare earth phosphate minerals with the general formula of ATO4, where A = Ce, La, Nd, or Sm (or, rarely, Bi), and B = P or, rarely, As. The A site may also bear Ca and Th.
Monazite-(La) is a relatively rare representative of the monazite group, with lanthanum being the dominant rare earth element in its structure. As such, it is the lanthanum analogue of monazite-(Ce), monazite-(Nd), and monazite-(Sm). It is also the phosphorus analogue of gasparite-(La). The group contains simple rare earth phosphate minerals with the general formula of ATO4, where A = Ce, La, Nd, or Sm (or, rarely, Bi), and B = P or, rarely, As. The A site may also bear Ca and Th.