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Azzedine Bousseksou (born 2 December 1964) is a Franco-Algerian physical chemist known for his contributions to molecular materials and spintronics.
Azzedine Bousseksou received his diploma in Material Physics from the Université de Bab Ezzouar in Algiers, in 1983, his Diplôme d'études approfondies (DEA) in Materials Science from the University of Nantes, in 1988, and his PhD in Materials Science from Pierre and Marie Curie University in Paris, in 1992. His doctoral internship was at the Inorganic Chemistry Laboratory of Johannes Gutenberg University of Mainz. [1]
Bousseksou began his career as a research fellow at the French National Centre for Scientific Research (CNRS) Coordination Chemistry Laboratory in Toulouse, in 1993. [1] [2] In January 2003, while in charge of Research at the LCC-CNRS Toulouse, he created and directed the scientific team "Switchable Molecular Materials". [3] From 2005 and 2009, he also directed the GDR Magnétisme et Commutation Moléculaires and co-coordinated the GDRI France-Japan on multifunctional molecular materials between 2006-2010. Between 2011 and 2013, he was Deputy Director of the LCC-CNRS Toulouse and has been Director since 2013. [4] Azzedine Bousseksou was a member of the CNRS national committee for the evaluation of researchers and research laboratories from 2000 to 2004 and from 2010 to 2015 and has coordinated and/or led several European, national, and regional projects. He has been a member of the European Network of Excellence on Molecular Magnetism, REX MAGMANET, [5] and is a member of the European Institute on Molecular Magnetism (EIMM).
He and his team developed three complementary conceptual approaches, which include:
With his research team is made up of 3 other permanent staff members (Gabor Molnar, DR-CNRS, Lionel Salmon DR-CNRS and William Nicolazzi, MCF-Université Paul Sabatier), among his achievements are the following:
He has supervised about twenty post-doctoral students and more than thirty theses.
He has registered 12 patents, 2 of which are being exploited, and one startup in incubation.
Bousseksou is a founding member of the Algerian Academy of Sciences and Technologies (2015), as well as a member of the French Academy of Sciences (2013), [27] the European Academy of Sciences and Arts (2012) and the European Academy of sciences (2014).
Supramolecular chemistry refers to the branch of chemistry concerning chemical systems composed of a discrete number of molecules. The strength of the forces responsible for spatial organization of the system range from weak intermolecular forces, electrostatic charge, or hydrogen bonding to strong covalent bonding, provided that the electronic coupling strength remains small relative to the energy parameters of the component. While traditional chemistry concentrates on the covalent bond, supramolecular chemistry examines the weaker and reversible non-covalent interactions between molecules. These forces include hydrogen bonding, metal coordination, hydrophobic forces, van der Waals forces, pi–pi interactions and electrostatic effects.
Molecular machines are a class of molecules typically described as an assembly of a discrete number of molecular components intended to produce mechanical movements in response to specific stimuli, mimicking macromolecular devices such as switches and motors. Naturally occurring or biological molecular machines are responsible for vital living processes such as DNA replication and ATP synthesis. Kinesins and ribosomes are examples of molecular machines, and they often take the form of multi-protein complexes. For the last several decades, scientists have attempted, with varying degrees of success, to miniaturize machines found in the macroscopic world. The first example of an artificial molecular machine (AMM) was reported in 1994, featuring a rotaxane with a ring and two different possible binding sites. In 2016 the Nobel Prize in Chemistry was awarded to Jean-Pierre Sauvage, Sir J. Fraser Stoddart, and Bernard L. Feringa for the design and synthesis of molecular machines.
James Mitchell Tour is an American chemist and nanotechnologist. He is a Professor of Chemistry, Professor of Materials Science and Nanoengineering at Rice University in Houston, Texas.
A single-molecule magnet (SMM) is a metal-organic compound that has superparamagnetic behavior below a certain blocking temperature at the molecular scale. In this temperature range, an SMM exhibits magnetic hysteresis of purely molecular origin. In contrast to conventional bulk magnets and molecule-based magnets, collective long-range magnetic ordering of magnetic moments is not necessary.
Pierre Braunstein is a French chemist. He was director of the Laboratoire de Chimie de Coordination of Strasbourg (France) and is a member of the French Academy of Science.
In chemistry and physics, LIESST is a method of changing the electronic spin state of a compound by means of irradiation with light.
Electromanipulation is a micro-material analyzing method mostly used for manipulations of biological cells that uses properties of diverse electric fields. In nanotechnology, nanomaterials are so small that they can hardly be directly mechanically manipulated. Hence, electric fields are applied to them to make field-induced movements or deformations. It is a recently developed technology and is still in progress of widening applications. Types of Electronmanipulation includes dielectrophoresis, electro-rotation, electro-deformation, electro-disruption, electro-destruction, electroporation, and electro-fusion. Diverse electromanipulations are achieved using various electric fields including AC(alternating current), DC(direct current), and pulsed(deliver high-energy discharges at very short periods) electrical fields. Electromanipulation of cells permits diverse cell manipulations with minimal mechanical contact between cells and device structures. Although predominantly used in cells, elctromanipulation also contributes to other scientific fields such as Hybridoma technology and nanoelectronic devices development.
Spin crossover (SCO) is a phenomenon that occurs in some metal complexes wherein the spin state of the complex changes due to an external stimulus. The stimuli can include temperature or pressure. Spin crossover is sometimes referred to as spin transition or spin equilibrium behavior. The change in spin state usually involves interchange of low spin (LS) and high spin (HS) configuration.
Guy Bertrand, born on July 17, 1952, at Limoges is a chemistry professor at the University of California, San Diego.
Didier Astruc carried out his studies in chemistry in Rennes. After a Ph. D. with professor R. Dabard in organometallic chemistry, he did post-doctoral studies with professor R. R. Schrock at the Massachusetts Institute of Technology Cambridge, Massachusetts, in the U.S. and later a sabbatical year with professor K. P. C. Vollhardt at the University of California at Berkeley. He became a CNRS Director of research in Rennes, then in 1983 full Professor of Chemistry at the University Bordeaux 1. He is known for his work on electron-reservoir complexes and dendritic molecular batteries, catalytic processes using nanoreactors and molecular recognition using gold nanoparticles and metallodendrimers.
Low molecular-mass organic gelators (LMOGs) are the monomeric sub-unit which form self-assembled fibrillar networks (SAFINs) that entrap solvent between the strands. SAFINs arise from the formation of strong non-covalent interactions between LMOG monomeric sub-units. As SAFINs are forming, the long fibers become intertwined and trap solvent molecules. Once solvent molecules are entrapped within the network, they are immobilized by surface tension effects. The stability of a gel is dependent on the equilibrium between the assembled network and the dissolved gelators. One characteristic of an LMOG, that demonstrates its stability, is its ability to contain an organic solvent at the boiling point of that solvent due to extensive solvent-fibrillar interactions. Gels self-assemble through non-covalent interactions such as π-stacking, hydrogen-bonding, or Van der Waals interactions to form volume-filling 3D networks. Self-assembly is key to gel formation and dependent upon reversible bond formation. The propensity of a low molecular weight molecule to form LMOGs is classified by its Minimum Gelation Concentration (MGC). The MGC is the lowest possible gelator concentration needed to form a stable gel. A lower MGC is desired to minimize the amount of gelator material needed to form gels. Super gelators have a MGC of less than 1 wt%.
The Weak-Link Approach (WLA) is a supramolecular coordination-based assembly methodology, first introduced in 1998 by the Mirkin Group at Northwestern University. This method takes advantage of hemilabile ligands -ligands that contain both strong and weak binding moieties- that can coordinate to metal centers and quantitatively assemble into a single condensed ‘closed’ structure. Unlike other supramolecular assembly methods, the WLA allows for the synthesis of supramolecular complexes that can be modulated from rigid ‘closed’ structures to flexible ‘open’ structures through reversible binding of allosteric effectors at the structural metal centers. The approach is general and has been applied to a variety of metal centers and ligand designs including those with utility in catalysis and allosteric regulation.
Ayyappanpillai Ajayaghosh is a research scientist/academician in the domain of interdisciplinary chemistry, and the former Director of the National Institute for Interdisciplinary Science and Technology. He is known for his studies on supramolecular assemblies, organogels, photoresponsive materials, chemosensory and security materials systems and is an elected fellow of all the three major Indian science academies viz. the National Academy of Sciences, India, Indian National Science Academy and the Indian Academy of Sciences as well as The World Academy of Sciences. The Council of Scientific and Industrial Research, the apex agency of the Government of India for scientific research, awarded him the Shanti Swarup Bhatnagar Prize for Science and Technology, one of the highest Indian science awards for his contributions to Chemical Sciences in 2007. He is the first chemist to receive the Infosys Science Prize for physical sciences, awarded by the Infosys Science Foundation. He received the TWAS Prize of The World Academy of Sciences in 2013 and the Goyal prize in 2019.
Paolo Samorì is an Italian physical chemist and Distinguished Professor (PRCE) at the Institut de Science et d'Ingénierie Supramoléculaires (ISIS) of the Université de Strasbourg (UNISTRA) & CNRS where he heads the Nanochemistry Laboratory and he has been institute director (2012-2023).
A chemiresistor is a material that changes its electrical resistance in response to changes in the nearby chemical environment. Chemiresistors are a class of chemical sensors that rely on the direct chemical interaction between the sensing material and the analyte. The sensing material and the analyte can interact by covalent bonding, hydrogen bonding, or molecular recognition. Several different materials have chemiresistor properties: semiconducting metal oxides, some conductive polymers, and nanomaterials like graphene, carbon nanotubes and nanoparticles. Typically these materials are used as partially selective sensors in devices like electronic tongues or electronic noses.
Jean-Marie Tarascon FRSC is Professor of Chemistry at the Collège de France in Paris and Director of the French Research Network on Electrochemical Energy Storage (RS2E).
Oleg V. Prezhdo is a Ukrainian–American physical chemist whose research focuses on non-adiabatic molecular dynamics and time-dependent density functional theory (TDDFT). His research interests range from fundamental aspects of semi-classical and quantum-classical physics to excitation dynamics in condensed matter and biological systems. His research group focuses on the development of new theoretical models and computational tools aimed at understanding chemical reactivity and energy transfer at a molecular level in complex condensed phase environment. Since 2014, he is a professor of chemistry and of physics & astronomy at the University of Southern California.
Lynda Soderholm is a physical chemist at the U.S. Department of Energy's (DOE) Argonne National Laboratory with a specialty in f-block elements. She is a senior scientist and the lead of the Actinide, Geochemistry & Separation Sciences Theme within Argonne's Chemical Sciences and Engineering Division. Her specific role is the Separation Science group leader within Heavy Element Chemistry and Separation Science (HESS), directing basic research focused on low-energy methods for isolating lanthanide and actinide elements from complex mixtures. She has made fundamental contributions to understanding f-block chemistry and characterizing f-block elements.
Nicholas Frederick Chilton is an Australian chemist and a Professor in the Research School of Chemistry at The Australian National University and The Department of Chemistry at The University of Manchester. His research is in the areas of magnetochemistry and computational chemistry, and includes the design of high-temperature single molecule magnets, molecular spin qubits for quantum information science, methods and tools for modelling magnetic calculations.
Richard Eric Parry Winpenny FRSC FLSW is a British chemist and a professor in the Department of Chemistry at the University of Manchester. Winpenny's research is within the fields of inorganic chemistry and magnetochemistry, specifically the areas of single-molecule magnetism, inorganic synthesis, supramolecular chemistry and polymetallic caged complexes.