The bead test is a traditional part of qualitative inorganic analysis to test for the presence of certain metals. The oldest one is the borax bead test or blister test. It was introduced by Berzelius in 1812. [1] Since then other salts were used as fluxing agents, such as sodium carbonate or sodium fluoride. The most important one after borax is microcosmic salt, [1] which is the basis of the microcosmic salt bead test. [2]
A small loop is made in the end of a platinum wire and heated in a Bunsen burner flame until red hot. A stick made of another inert substance such as a magnesia stick (MgO) may also be used. It is then dipped into powdered borax and held in the hottest part of the flame where it swells up as it loses its water of crystallization and then shrinks, forming a colourless, transparent glass-like bead (a mixture of sodium metaborate and boric anhydride).
The bead is allowed to cool and then wetted and dipped into the sample to be tested such that only a tiny amount of the substance adheres to the bead. If too much substance is used, the bead will become dark and opaque. The bead and adhering substance is then heated in the lower, reducing, part of the flame, allowed to cool, and the colour observed. It is then heated in the upper, oxidizing, part of the flame, allowed to cool, and the colour observed again. [2]
Characteristic coloured beads are produced with salts of copper, iron, chromium, manganese, cobalt and nickel. After the test, the bead is removed by heating it to fusion point, and plunging it into a vessel of water.
Metal [3] | Oxidizing flame | Reducing flame [4] |
---|---|---|
Aluminum | colorless (hot and cold), opaque | colorless, opaque |
Antimony | colorless, yellow or brown (hot) | gray and opaque |
Barium | colorless | |
Bismuth | colorless, yellow or brownish (hot) | gray and opaque |
Cadmium | colorless | gray and opaque |
Calcium | colorless | |
Cerium | red (hot) | colorless (hot and cold) |
Copper | sky blue (hot and cold), opaque | red, opaque |
Iron | yellow (hot and cold), opaque | bottle-green, opaque |
Manganese | pink (hot and cold), opaque | colorless, opaque |
Cobalt | deep blue (hot and cold), opaque | deep blue, opaque |
Nickel | yellow-brown (hot and cold), opaque | grey, opaque |
Silver | colourless (hot and cold), opaque | grey, opaque |
Vanadium | colourless(hot and cold), opaque | green, opaque |
Uranium | yellow-brown (hot and cold), opaque | green, opaque |
Chromium | green (hot and cold), opaque | green, opaque |
Platinum | colourless(hot and cold), opaque | grey, opaque |
Gold | yellow-brown (hot and cold), opaque | grey, opaque |
Tin | colourless(hot and cold), opaque | colourless, opaque |
Titanium | colourless (hot and cold), opaque | yellow, opaque (hot) violet (cold) |
Tungsten | colourless(hot and cold), opaque | brown, opaque |
Magnesium | colourless(hot and cold), opaque | colourless, opaque |
Molybdenum | colourless(hot and cold), opaque | yellow or brown, opaque |
Strontium | colourless(hot and cold), opaque | colourless, opaque |
Thorium | colourless(hot and cold), opaque | colourless, opaque |
Yttrium | colourless(hot and cold), opaque | colourless, opaque |
Neodymium | colourless(hot and cold), opaque | colourless, opaque |
Praseodymium | colourless(hot and cold), opaque | colourless, opaque |
Silicon | colourless(hot and cold), opaque | colourless, opaque |
Germanium | colourless(hot and cold), opaque | colourless, opaque |
Sodium is a chemical element with the symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable isotope is 23Na. The free metal does not occur in nature, and must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust and exists in numerous minerals such as feldspars, sodalite, and halite (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans.
Borax is a salt, a hydrated or anhydrous borate of sodium, with the chemical formula Na2H20B4O17. It is a colorless crystalline solid, that dissolves in water to make a basic solution.
A test tube, also known as a culture tube or sample tube, is a common piece of laboratory glassware consisting of a finger-like length of glass or clear plastic tubing, open at the top and closed at the bottom.
Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils. Because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.
The color of chemicals is a physical property of chemicals that in most cases comes from the excitation of electrons due to an absorption of energy performed by the chemical. What is seen by the eye is not the color absorbed, but the complementary color from the removal of the absorbed wavelengths. This spectral perspective was first noted in atomic spectroscopy.
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to an electron making a transition from a high energy state to a lower energy state. The photon energy of the emitted photon is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances.
Potassium tetraiodomercurate(II) is an inorganic compound consisting of potassium cations and the tetraiodomercurate(II) anion. It is mainly used as Nessler's reagent, a 0.09 mol/L solution of potassium tetraiodomercurate(II) (K2[HgI4]) in 2.5 mol/L potassium hydroxide, used to detect ammonia.
Barium sulfate (or sulphate) is the inorganic compound with the chemical formula BaSO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs as the mineral barite, which is the main commercial source of barium and materials prepared from it. The white opaque appearance and its high density are exploited in its main applications.
Lead(II) sulfide is an inorganic compound with the formula PbS. Galena is the principal ore and the most important compound of lead. It is a semiconducting material with niche uses.
Antimony trisulfide is found in nature as the crystalline mineral stibnite and the amorphous red mineral metastibnite. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. It also is used in the production of ruby-colored glass and in plastics as a flame retardant. Historically the stibnite form was used as a grey pigment in paintings produced in the 16th century. In 1817, the dye and fabric chemist, John Mercer discovered the non-stoichiometric compound Antimony Orange, the first good orange pigment available for cotton fabric printing.
Microcosmic salt (see infobox for other names) is a salt found in urine with the formula Na(NH4)HPO4. It is left behind in the residues after extracting the urea from dried urine crystals with alcohol. In the mineral form, microcosmic salt is called stercorite.
Classical qualitative inorganic analysis is a method of analytical chemistry which seeks to find the elemental composition of inorganic compounds. It is mainly focused on detecting ions in an aqueous solution, therefore materials in other forms may need to be brought to this state before using standard methods. The solution is then treated with various reagents to test for reactions characteristic of certain ions, which may cause color change, precipitation and other visible changes.
A flame test is an analytical procedure used in chemistry to detect the presence of certain elements, primarily metal ions, based on each element's characteristic flame emission spectrum. The color of flames in general also depends on temperature and oxygen fed; see flame color.
Acid salts are a class of salts that produce an acidic solution after being dissolved in a solvent. Its formation as a substance has a greater electrical conductivity than that of the pure solvent. An acidic solution formed by acid salt is made during partial neutralization of diprotic or polyprotic acids. A half-neutralization occurs due to the remaining of replaceable hydrogen atoms from the partial dissociation of weak acids that have not been reacted with hydroxide ions to create water molecules.
The Beilstein test is a simple qualitative chemical test for organic halides. It was developed by Friedrich Konrad Beilstein.
Ammonium metavanadate is the inorganic compound with the formula NH4VO3. It is a white salt, although samples are often yellow owing to impurities of V2O5. It is an important intermediate in the purification of vanadium.
Sodium hexanitritocobaltate(III) is inorganic compound with the formula Na3[Co(NO2)6]. The anion of this yellow-coloured salt consists of the transition metal nitrite complex [Co(NO2)6]3−. It was a reagent for the qualitative test for potassium and ammonium ions.
Tetrahydroxyborate is an inorganic anion with the chemical formula [BH4O4]− or [B(OH)4]−. It contributes no colour to tetrahydroxyborate salts. It is found in the mineral hexahydroborite, Ca(B(OH)4)2 · 2 H2O, originally formulated CaB2O4 · 6 H2O. It is one of the boron oxoanions, and acts as a weak base. The systematic names are tetrahydroxyboranuide (substitutive) and tetrahydroxidoborate(1−) (additive). It can be viewed as the conjugate base of boric acid.
Bismuth(III) iodide is the inorganic compound with the formula BiI3. This gray-black salt is the product of the reaction of bismuth and iodine, which once was of interest in qualitative inorganic analysis.
Platinum tetrafluoride is the inorganic compound with the chemical formula PtF
4. In the solid state, the compound features platinum(IV) in octahedral coordination geometry.