Bice

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Bice, from the French bis, originally meaning dark-coloured, is a green or blue pigment. In French the terms vert bis and azur bis mean dark green and dark blue respectively. Bice pigments were generally prepared from basic copper carbonates, but sometimes ultramarine or other pigments were used. [1]

Historic usage

In 1522 a stone cross with gilt lead stars was erected at the Bullstake in Canterbury, and painted with bice and gilded by Florence the painter. The bice cost 6 shillings the pound. [2]

Jo Kirby of the National Gallery London notes the occurrence of the pigment bice in three grades in an account of Tudor painting at Greenwich Palace in 1527. In this case, the three grades indicate the use of the mineral azurite rather than a manufactured blue copper carbonate. Similarly, green bice in other 16th-records may sometimes have been the mineral malachite. [3] Ian Bristow, a historian of paint, concluded that the pigment blue bice found in records of British interior-decoration until the first half of the 17th century was azurite. The expensive natural mineral azurite was superseded by manufactured blue verditer. [4]

The color is also referenced in Edith Nesbit's novel The Treasure Seekers: "...Alice looked up from her painting. She was trying to paint a fairy queen's frock with green bice, and it wouldn't rub. There is something funny about green bice. It never will rub off; no matter how expensive your paintbox is-and even boiling water is very little use. She said, ‘Bother the bice’!..." [5]

Related Research Articles

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Basic copper carbonate Chemical compound

Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It is an ionic compound consisting of the ions copper(II) Cu2+
, carbonate CO2−
3
, and hydroxide OH
.

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Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur.

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Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's Natural History under the Greek name kuanos (κυανός: "deep blue," root of English cyan) and the Latin name caeruleum. Since antiquity, azurite's exceptionally deep and clear blue has been associated with low-humidity desert and winter skies. The modern English name of the mineral reflects this association, since both azurite and azure are derived via Arabic from the Persian lazhward (لاژورد), an area known for its deposits of another deep-blue stone, lapis lazuli ("stone of azure").

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Copper carbonate may refer to :

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2
CO
3
(OH)2), and, when near the sea, basic copper chloride (Cu2(OH)3Cl). Still other sources describe verdigris as Cu(CH3CO2)2.(Cu(OH)2)n where n varies from 0 to 3. The alchemical symbol for verdigris is 🜨 (unicode U+1F728).

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Copper(II) hydroxide is the hydroxide of copper with the chemical formula of Cu(OH)2. It is a pale greenish blue or bluish green solid. Some forms of copper(II) hydroxide are sold as "stabilized" copper(II) hydroxide, although they likely consist of a mixture of copper(II) carbonate and hydroxide. Cupric hydroxide is a strong base, although its low solubility in water makes this hard to observe directly.

Lapis armenus, also known as Armenian stone or lapis stellatus, in natural history, is a variety of precious stone, resembling lapis lazuli, except that it is softer, and instead of veins of pyrite, is intermixed with green. "The Armenian stone" is so similar to lapis lazuli that it has often not been distinguished from it; Webster's Revised Unabridged Dictionary for instance treats the two terms as synonyms. The Dictionary of Traded Goods and Commodities 1550-1820 defines lapis armenus as

Armenian stone, or azurite, a naturally occurring basic copper carbonate, originally from Armenia, but later from Germany, from which blue bice was prepared. It was often found in association with another copper carbonate, malachite from which green bice was prepared... Probably because they were both blue, blue bice was sometimes misinterpreted to mean lapis lazuli.

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Stil de grain yellow or sap green is a pigment derived from berries of the buckthorn species Rhamnus saxatilis, which are commonly called Avignon berries or Persian berries after two historical areas of supply; latterly Italy was a major source. The color, whose principal chemical component is rhamnetin, was formerly called pink ; latterly, to distinguish it from light red "pink", the yellow "pink" was qualified as Dutch pink, brown pink, English pink, Italian pink, or French pink — the first three also applied to similar quercitron dyes from the American eastern black oak, Quercus velutina. Other names are Persian berries lake, yellow berries and buckthorn berries.

Chalconatronite

Chalconatronite is a carbonate mineral and rare secondary copper mineral that contains copper, sodium, carbon, oxygen, and hydrogen, its chemical formula is Na2Cu(CO3)2•3(H2O). Chalconatronite is partially soluble in water, and only decomposes, although chalconatronite is soluble while cold, in dilute acids. The name comes from the mineral's compounds, copper ("chalcos" in Greek) and natron, naturally forming sodium carbonate. The mineral is thought to be formed by water carrying alkali carbonates (possibly from soil) reacting with bronze. Similar minerals include malachite, azurite, and other copper carbonates. Chalconatronite has also been found and recorded in Australia, Germany, and Colorado.

<span class="mw-page-title-main">Blue in culture</span>

The colour blue has been important in culture, politics, art and fashion since ancient times. Blue was used in ancient Egypt for jewellery and ornament. In the Renaissance, blue pigments were prized for paintings and fine blue and white porcelain. in the Middle Ages, deep rich blues made with cobalt were used in stained glass windows. In the 19th century, the colour was often used for military uniforms and fashion.

<span class="mw-page-title-main">Blue pigments</span>

Blue pigments are natural or synthetic materials, usually made from minerals and insoluble with water, used to make the blue colors in painting and other arts. The raw material of the earliest blue pigment, lapis lazuli, came from mines in Afghanistan, was refined into the pigment ultramarine. It was widely used for painting in the Middle Ages and Renaissance. Since the late 18th and 19th century, blue pigments are largely synthetic, manufactured in laboratories and factories.

<span class="mw-page-title-main">Green pigments</span>

Green pigments are the materials used to create the green colors seen in painting and the other arts. Most come from minerals, particularly those containing compounds of copper. Green pigments reflect the green portions of the spectrum of visible light, and absorb the others. Important green pigments in art history include Malachite and Verdigris, found in tomb paintings in Ancient Egypt, and the Green earth pigments popular in the Middle Ages. More recent greens, such as Cobalt Green, are largely synthetic, made in laboratories and factories.

References

  1. Wikisource-logo.svg One or more of the preceding sentences incorporates text from a publication now in the public domain : Chisholm, Hugh, ed. (1911). "Bice". Encyclopædia Britannica . Vol. 3 (11th ed.). Cambridge University Press. p. 911.
  2. HMC 9th Report: Canterbury (London, 1883), p. 150.
  3. Roskill & Hand, ed., Hans Holbein, Paintings, Prints, and Reception (Yale, 2001), p. 119.
  4. Bristow, Ian C., Interior house-Painting Colours and Technology, 1615-1640 (Yale, 1996), p. 17.
  5. Chapter 9 of "The Treasure Seekers" by E.Nesbit