A brinicle (brine icicle, also known as ice stalactite) is a downward-growing hollow tube of ice enclosing a plume of descending brine that is formed beneath developing sea ice.
As seawater freezes in the polar ocean, salt brine concentrates are expelled from the sea ice creating a downward flow of dense, extremely cold, and saline water, with a lower freezing point than the surrounding water. When this plume comes into contact with the neighboring ocean water, its extremely low temperature causes ice to instantly form around the flow. This creates a hollow stalactite or icicle referred to as a brinicle.
The formation of ice from salt water produces marked changes in the composition of the nearby unfrozen water. When water freezes, most impurities are excluded from the water crystals; even ice from seawater is relatively fresh compared to the seawater from which it is formed. As a result of forcing the impurities out (such as salt and other ions) sea ice is very porous and spongelike, quite different from the solid ice produced when fresh water freezes.
As the seawater freezes and salt is forced out of the pure ice crystal lattice, the surrounding water becomes more saline as concentrated brine leaks out. This lowers its freezing temperature and increases its density. Lowering the freezing temperature allows this surrounding, brine-rich water to remain liquid and not freeze immediately. The increase in density causes this layer to sink. [1] Tiny tunnels called brine channels are created all through the ice as this supersaline, supercooled water sinks away from the frozen pure water. The stage is now set for the creation of a brinicle.
As this supercooled saline water reaches unfrozen seawater below the ice, it will cause the creation of additional ice. Water moves from high to low concentrations. Because the brine possesses a lower concentration of water, it therefore attracts the surrounding water. [2] Due to the cold temperature of the brine, the newly attracted water freezes. If the brine channels are relatively evenly distributed, the ice pack grows downward evenly. However, if brine channels are concentrated in one small area, the downward flow of the cold brine (now so salt-rich that it cannot freeze at its normal freezing point) begins to interact with unfrozen seawater as a flow. Just as hot air from a fire rises as a plume, this cold, dense water sinks as a plume. Its outer edges begin accumulating a layer of ice as the surrounding water, cooled by this jet to below its freezing point, ices up. A brinicle has now been formed, resembling an inverted "chimney" of ice enclosing a downward flow of this supercooled, super salinated water.
When the brinicle becomes thick enough, it becomes self-sustaining. As ice accumulates around the down-flowing cold jet, it forms an insulating layer that prevents the cold, saline water from diffusing and warming. As a result, the ice jacket surrounding the jet grows downward with the flow. The inner wall temperature of the stalactite remains on the salinity-determined freezing curve, so as the stalactite grows and the temperature deficit of the brine goes into the growth of ice, the inner wall melts to dilute and cool the adjacent brine back to its freezing point. [3] It is like an icicle turned inside-out; rather than cold air freezing liquid water into layers, down-rushing cold water is freezing the surrounding water, enabling it to descend even deeper. As it does, it creates more ice, and the brinicle grows longer.
A brinicle is limited in size by the depth of the water, the growth of the overlying sea ice fueling its flow, and the surrounding water itself. In 2011, brinicle formation was filmed for the first time. [4] The salinity of the liquid water within the brinicle has been confirmed to vary depending on the temperature of the air. The lower the temperature, the greater the brine concentration. A January 2014 along the coast of the White Sea recorded that at an air temperature of −1 °C the brine salinity was between 30 and 35 psu while the salinity at sea was 28 psu. When the temperature was −12 °C the salinity of the brine increased to between 120 and 156 psu. [5]
At the time of its creation, a brinicle resembles a pipe of ice reaching down from the underside of a layer of sea ice. Inside the pipe is extremely cold and saline water produced by the growth of the sea ice above, accumulated through brine channels. At first, brinicles are very fragile, the walls are thin, but the constant flow of colder brine sustains the brinicle growth and hinders its melt that would be caused by the contact with the less cold surrounding water. As ice accumulates and the walls becomes thicker, brinicles becomes more stable.
A brinicle can, under the proper conditions, reach down to the seafloor. To do so, the supercold brine from the pack ice overhead must continue to flow, the surrounding water must be significantly less saline than the brine, the water cannot be very deep, the overhead sea ice pack must be still, and currents in the area must be minimal or still. If the surrounding water is too saline, its freezing point will be too low to create a significant amount of ice around the brine plume. If the water is too deep, the brinicle is likely to break free under its own weight before reaching the seafloor. If the icepack is mobile or currents too strong, strain will break the brinicle.
Under the right conditions, including favorable ocean floor topography, a brine pool may be created. However, unlike brine pools created by cold seeps, brinicle brine pools are likely to be very transient as the brine supply will eventually cease.
On reaching the seafloor, it will continue to accumulate ice as surrounding water freezes. The brine will travel along the seafloor in a down-slope direction until it reaches the lowest possible point, where it will pool. Any bottom-dwelling sea creatures, including starfish or sea urchins, can be encased in this expanding web of ice and be trapped, ultimately freezing to death.
Brinicles have been known since the 1960s. The generally accepted model of their formation was proposed by the US oceanographer Seelye Martin in 1974. [3] The formation of a brinicle was first filmed in 2011 by producer Kathryn Jeffs and cameramen Hugh Miller and Doug Anderson for the BBC series Frozen Planet . [4] The first numerical model for a brinicle formation was developed in 2023 [6] by researchers at the National University of Colombia in collaboration with the Lawrence Livermore National Laboratory .
Frost is a thin layer of ice on a solid surface, which forms from water vapor that deposits onto a freezing surface. Frost forms when the air contains more water vapor than it can normally hold at a specific temperature. The process is similar to the formation of dew, except it occurs below the freezing point of water typically without crossing through a liquid state.
A stalactite is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble and that can be deposited as a colloid, or is in suspension, or is capable of being melted, may form a stalactite. Stalactites may be composed of lava, minerals, mud, peat, pitch, sand, sinter, and amberat. A stalactite is not necessarily a speleothem, though speleothems are the most common form of stalactite because of the abundance of limestone caves.
Brine is water with a high-concentration solution of salt. In diverse contexts, brine may refer to the salt solutions ranging from about 3.5% up to about 26%. Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking, for de-icing of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial processes, such as desalination, so it requires wastewater treatment for proper disposal or further utilization.
Freezing rain is rain maintained at temperatures below freezing by the ambient air mass that causes freezing on contact with surfaces. Unlike a mixture of rain and snow or ice pellets, freezing rain is made entirely of liquid droplets. The raindrops become supercooled while passing through a sub-freezing layer of air hundreds of meters above the ground, and then freeze upon impact with any surface they encounter, including the ground, trees, electrical wires, aircraft, and automobiles. The resulting ice, called glaze ice, can accumulate to a thickness of several centimeters and cover all exposed surfaces. The METAR code for freezing rain is FZRA.
An icicle is a spike of ice formed when water falling from an object freezes.
Supercooling, also known as undercooling, is the process of lowering the temperature of a liquid below its freezing point without it becoming a solid. It is achieved in the absence of a seed crystal or nucleus around which a crystal structure can form. The supercooling of water can be achieved without any special techniques other than chemical demineralization, down to −48.3 °C (−54.9 °F). Supercooled water can occur naturally, for example in the atmosphere, animals or plants.
Thermohaline circulation (THC) is a part of the large-scale ocean circulation that is driven by global density gradients created by surface heat and freshwater fluxes. The adjective thermohaline derives from thermo- referring to temperature and -haline referring to salt content, factors which together determine the density of sea water. Wind-driven surface currents travel polewards from the equatorial Atlantic Ocean, cooling en route, and eventually sinking at high latitudes. This dense water then flows into the ocean basins. While the bulk of it upwells in the Southern Ocean, the oldest waters upwell in the North Pacific. Extensive mixing therefore takes place between the ocean basins, reducing differences between them and making the Earth's oceans a global system. The water in these circuits transport both energy and mass around the globe. As such, the state of the circulation has a large impact on the climate of the Earth.
A polynya is an area of open water surrounded by sea ice. It is now used as a geographical term for an area of unfrozen seawater within otherwise contiguous pack ice or fast ice. It is a loanword from the Russian полынья, which refers to a natural ice hole and was adopted in the 19th century by polar explorers to describe navigable portions of the sea.
Frazil ice is a collection of loose, randomly oriented ice crystals millimeter and sub-millimeter in size, with various shapes, e.g. elliptical disks, dendrites, needles and of an irregular nature. Frazil ice forms during the winter in open-water reaches of rivers as well as in lakes and reservoirs, where and when the water is in a turbulent state, which is, in turn, induced by the action of waves and currents. Turbulence causes the water column to become supercooled, as the heat exchange between the air and the water is such that the water temperature drops below its freezing point. The vertical mixing associated with that turbulence provides enough energy to overcome the crystals' buoyancy, thus keeping them from floating at the surface. Frazil ice also forms in oceans, where windy conditions, wave regimes and cold air also favor the establishment of a supercooled layer. Frazil ice can be found on the downwind side of leads, and in polynyas. In these environments, that ice can eventually accumulate at the water surface into what is referred to as grease ice.
In oceanography, a halocline is a cline, a subtype of chemocline caused by a strong, vertical salinity gradient within a body of water. Because salinity affects the density of seawater, it can play a role in its vertical stratification. Increasing salinity by one kg/m3 results in an increase of seawater density of around 0.7 kg/m3.
An ice spike is an ice formation, often in the shape of an inverted icicle, that projects upwards from the surface of a body of frozen water. Ice spikes created by natural processes on the surface of small bodies of frozen water have been reported for many decades, although their occurrence is quite rare. A mechanism for their formation, now known as the Bally–Dorsey model, was proposed in the early 20th century but this was not tested in the laboratory for many years. In recent years a number of photographs of natural ice spikes have appeared on the Internet as well as methods of producing them artificially by freezing distilled water in domestic refrigerators or freezers. This has allowed a small number of scientists to test the hypothesis in a laboratory setting and, although the experiments appear to confirm the validity of the Bally–Dorsey model, they have raised further questions about how natural ice spikes form, and more work remains to be done before the phenomenon is fully understood. Natural ice spikes can grow into shapes other than a classic spike shape, and have been variously reported as ice candles, ice towers or ice vases as there is no standard nomenclature for these other forms. One particularly unusual form takes the shape of an inverted pyramid.
Anchor ice is defined by the World Meteorological Organization as "submerged ice attached or anchored to the bottom, irrespective of the nature of its formation". It may also be called bottom-fast ice. Anchor ice is most commonly observed in fast-flowing rivers during periods of extreme cold, at the mouths of rivers flowing into very cold seawater, in the shallow sub or intertidal during or after storms when the air temperature is below the freezing point of the water, and the subtidal in the Antarctic along ice shelves or near floating glacier tongues, and in shallow lakes.
Bottom water is the lowermost water mass in a water body, by its bottom, with distinct characteristics, in terms of physics, chemistry, and ecology.
Slurry ice is a phase changing refrigerant made up of millions of ice "micro-crystals" formed and suspended within a solution of water and a freezing point depressant. Some compounds used in the field are salt, ethylene glycol, propylene glycol, alcohols like isobutyl and ethanol, and sugars like sucrose and glucose. Slurry ice has greater heat absorption compared to single phase refrigerants like brine, because the melting enthalpy of the ice is also used.
A lead is a large fracture within an expanse of sea ice, defining a linear area of open water that can be used for navigation purposes. Leads vary in width from meters to hundreds of meters. As is the case for polynyas, leads allow the direct interaction between the atmosphere and the ocean, and are important for Arctic sea ice ecology. Additionally it has been lately found that ice leads contribute significantly to the amount of mercury deposited onto surface and leaked into the ocean. If the air is cold enough, the water within a lead quickly refreezes, such that in many cases, leads are partly or entirely covered by a thin layer of new ice.
Frost flowers are ice crystals commonly found growing on young sea ice and thin lake ice in cold, calm conditions. The ice crystals are similar to hoar frost, and are commonly seen to grow in patches around 3–4 cm in diameter. Frost flowers growing on sea ice have extremely high salinities and concentrations of other sea water chemicals and, because of their high surface area, are efficient releasers of these chemicals into the atmosphere.
Paleosalinity is the salinity of the global ocean or of an ocean basin at a point in geological history.
Sea ice is a complex composite composed primarily of pure ice in various states of crystallization, but including air bubbles and pockets of brine. Understanding its growth processes is important for climate modellers and remote sensing specialists, since the composition and microstructural properties of the ice affect how it reflects or absorbs sunlight.
Brine rejection is a process that occurs when salty water freezes. The salts do not fit in the crystal structure of water ice, so the salt is expelled.
A sea ice brine pocket is an area of fluid sea water with a high salt concentration trapped in sea ice as it freezes. Due to the nature of their formation, brine pockets are most commonly found in areas below −2 °C (28 °F), where it is sufficiently cold for seawater to freeze and form sea ice. Though the high salinity and low light conditions of brine pockets create a challenging environment for marine mammals, brine pockets serve as a habitat to various microbes. Sampling and studying these pockets requires specialized equipment and alterations to methodologies to accommodate the hyper-saline conditions and subzero temperatures.
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