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A buffer gas is an inert or nonflammable gas. In the Earth's atmosphere, nitrogen acts as a buffer gas. A buffer gas adds pressure to a system and controls the speed of combustion with any oxygen present. Any inert gas such as helium, neon, or argon will serve as a buffer gas.
Buffer gases are commonly used in many applications from high pressure discharge lamps to reduce line width of microwave transitions in alkali atoms. A buffer gas usually consists of atomically inert gases such as helium, [1] [2] argon, or nitrogen. [3] Krypton, neon, and xenon are also used, primarily for lighting.[ citation needed ] In most scenarios, buffer gases are used in conjunction with other molecules for the main purpose of causing collisions with the other co-existing molecules.
In fluorescent lamps, mercury is used as the primary ion from which light is emitted. Krypton is the buffer gas used in conjunction with the mercury which is used to moderate the momentum of collisions of mercury ions in order to reduce the damage done to the electrodes in the fluorescent lamp. Generally speaking, the longest lasting lamps are those with the heaviest noble gases as buffer gases.[ citation needed ]
Buffer gas loading techniques have been developed for use in cooling paramagnetic atoms and molecules at ultra-cold temperatures. The buffer gas most commonly used in this sort of application is helium. Buffer gas cooling can be used on just about any molecule, as long as the molecule is capable of surviving multiple collisions with low energy helium atoms, which most molecules are capable of doing. Buffer gas cooling is allowing the molecules of interest to be cooled through elastic collisions with a cold buffer gas inside a chamber. If there are enough collisions between the buffer gas and the other molecules of interest before the molecules hit the walls of the chamber and are gone, the buffer gas will sufficiently cool the atoms. Of the two isotopes of helium (3He and 4He), the rarer 3He is sometimes used over 4He as it provides significantly higher vapor pressures and buffer gas density at sub-kelvin temperatures.[ citation needed ]
Buffer gases are also commonly used in compressors used in power plants for supplying gas to gas turbines. The buffer gas fills the spaces between seals in the compressor. This space is usually about 2 micrometres wide.[ citation needed ] The gas must be completely dry and free of any contaminants. Contaminants can potentially lodge in the space between the seal and cause metal to metal contact in the compressor, leading to compressor failure.[ citation needed ] In this case the buffer gas acts in a way much like oil does in an automotive engine's bearings.
Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934%. It is more than twice as abundant as water vapor, 23 times as abundant as carbon dioxide, and more than 500 times as abundant as neon. Argon is the most abundant noble gas in Earth's crust, comprising 0.00015% of the crust.
The noble gases are the naturally occurring members of group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn). Under standard conditions, these elements are odorless, colorless, monatomic gases with very low chemical reactivity and cryogenic boiling points.
Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of air.
An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. The noble gases often do not react with many substances and were historically referred to as the inert gases. Inert gases are used generally to avoid unwanted chemical reactions degrading a sample. These undesirable chemical reactions are often oxidation and hydrolysis reactions with the oxygen and moisture in air. The term inert gas is context-dependent because several of the noble gases can be made to react under certain conditions.
In the signage industry, neon signs are electric signs lighted by long luminous gas-discharge tubes that contain rarefied neon or other gases. They are the most common use for neon lighting, which was first demonstrated in a modern form in December 1910 by Georges Claude at the Paris Motor Show. While they are used worldwide, neon signs were popular in the United States from about the 1920s to 1950s. The installations in Times Square, many originally designed by Douglas Leigh, were famed, and there were nearly 2,000 small shops producing neon signs by 1940. In addition to signage, neon lighting is used frequently by artists and architects, and in plasma display panels and televisions. The signage industry has declined in the past several decades, and cities are now concerned with preserving and restoring their antique neon signs.
In chemistry, noble gas compounds are chemical compounds that include an element from the noble gases, group 18 of the periodic table. Although the noble gases are generally unreactive elements, many such compounds have been observed, particularly involving the element xenon.
A breathing gas is a mixture of gaseous chemical elements and compounds used for respiration. Air is the most common and only natural breathing gas, but other mixtures of gases, or pure oxygen, are also used in breathing equipment and enclosed habitats. Oxygen is the essential component for any breathing gas. Breathing gases for hyperbaric use have been developed to improve on the performance of ordinary air by reducing the risk of decompression sickness, reducing the duration of decompression, reducing nitrogen narcosis or allowing safer deep diving.
A gas-filled tube, also commonly known as a discharge tube or formerly as a Plücker tube, is an arrangement of electrodes in a gas within an insulating, temperature-resistant envelope. Gas-filled tubes exploit phenomena related to electric discharge in gases, and operate by ionizing the gas with an applied voltage sufficient to cause electrical conduction by the underlying phenomena of the Townsend discharge. A gas-discharge lamp is an electric light using a gas-filled tube; these include fluorescent lamps, metal-halide lamps, sodium-vapor lamps, and neon lights. Specialized gas-filled tubes such as krytrons, thyratrons, and ignitrons are used as switching devices in electric devices.
An excimer laser, sometimes more correctly called an exciplex laser, is a form of ultraviolet laser which is commonly used in the production of microelectronic devices, semiconductor based integrated circuits or "chips", eye surgery, and micromachining.
An ion laser is a gas laser that uses an ionized gas as its lasing medium. Like other gas lasers, ion lasers feature a sealed cavity containing the laser medium and mirrors forming a Fabry–Pérot resonator. Unlike helium–neon lasers, the energy level transitions that contribute to laser action come from ions. Because of the large amount of energy required to excite the ionic transitions used in ion lasers, the required current is much greater, and as a result almost all except for the smallest ion lasers are water-cooled. A small air-cooled ion laser might produce, for example, 130 milliwatts of output light with a tube current of about 10 amperes and a voltage of 105 volts. Since one ampere times one volt is one watt, this is an electrical power input of about one kilowatt. Subtracting the (desirable) light output of 130 mW from power input, this leaves the large amount of waste heat of nearly one kW. This has to be dissipated by the cooling system. In other words, the power efficiency is very low.
Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders.
Gas-discharge lamps are a family of artificial light sources that generate light by sending an electric discharge through an ionized gas, a plasma.
A Penning mixture, named after Frans Michel Penning, is a mixture of gases used in electric lighting or displaying fixtures. Although the popular phrase for the most common of these is a neon lamp, it is more efficient to have the glass tube filled not with pure neon, but with a Penning mixture, which is defined as a mixture of one inert gas with a minute amount of another gas, one that has lower ionization voltage than the main constituent.
Krypton is a chemical element; it has symbol Kr and atomic number 36. It is a colorless, odorless, tasteless noble gas that occurs in trace amounts in the atmosphere and is often used with other rare gases in fluorescent lamps. Krypton is chemically inert.
The helium hydride ion, hydridohelium(1+) ion, or helonium is a cation (positively charged ion) with chemical formula HeH+. It consists of a helium atom bonded to a hydrogen atom, with one electron removed. It can also be viewed as protonated helium. It is the lightest heteronuclear ion, and is believed to be the first compound formed in the Universe after the Big Bang.
In chemistry, the term chemically inert is used to describe a substance that is not chemically reactive. From a thermodynamic perspective, a substance is inert, or nonlabile, if it is thermodynamically unstable yet decomposes at a slow, or negligible rate.
An air separation plant separates atmospheric air into its primary components, typically nitrogen and oxygen, and sometimes also argon and other rare inert gases.
A cryogenic gas plant is an industrial facility that creates molecular oxygen, molecular nitrogen, argon, krypton, helium, and xenon at relatively high purity. As air is made up of nitrogen, the most common gas in the atmosphere, at 78%, with oxygen at 19%, and argon at 1%, with trace gasses making up the rest, cryogenic gas plants separate air inside a distillation column at cryogenic temperatures to produce high purity gasses such as argon, nitrogen, oxygen, and many more with 1 ppm or less impurities. The process is based on the general theory of the Hampson-Linde cycle of air separation, which was invented by Carl von Linde in 1895.
In physics and chemistry, "monatomic" is a combination of the words "mono" and "atomic", and means "single atom". It is usually applied to gases: a monatomic gas is a gas in which atoms are not bound to each other. Examples at standard conditions of temperature and pressure include all the noble gases, though all chemical elements will be monatomic in the gas phase at sufficiently high temperature. The thermodynamic behavior of a monatomic gas is much simpler when compared to polyatomic gases because it is free of any rotational or vibrational energy.
Helium is the smallest and the lightest noble gas and one of the most unreactive elements, so it was commonly considered that helium compounds cannot exist at all, or at least under normal conditions. Helium's first ionization energy of 24.57 eV is the highest of any element. Helium has a complete shell of electrons, and in this form the atom does not readily accept any extra electrons nor join with anything to make covalent compounds. The electron affinity is 0.080 eV, which is very close to zero. The helium atom is small with the radius of the outer electron shell at 0.29 Å. Helium is a very hard atom with a Pearson hardness of 12.3 eV. It has the lowest polarizability of any kind of atom, however, very weak van der Waals forces exist between helium and other atoms. This force may exceed repulsive forces, so at extremely low temperatures helium may form van der Waals molecules. Helium has the lowest boiling point of any known substance.