Calcium caseinate

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Casein molecule Bovine b-casomorphin 7.svg
Casein molecule

Calcium caseinate is one of several milk proteins derived from casein in skim and 1% milk. Calcium caseinate has a papery, sweet and overall bland flavor, and is primarily used in meal preparation and fat breakdown. [1] Caseinates are produced by adding an alkali to another derivative of casein, acid casein. The type of caseinate is determined by the cation added alongside the acid casein. [2] Other cations used to form caseinates besides calcium include ammonium, potassium, and sodium.

Contents

Calcium caseinate contains about 17% glutamic acid. Calcium caseinate is mostly composed of 3.5% moisture, 1.0% fat, 90.9% protein, 0.1% lactose, 4.5% ash, although this may vary slightly by manufacturer. [3] Calcium caseinate is semi-soluble in water, contrary to acid casein and rennet casein which are not soluble in water. Sodium caseinate is more water soluble than calcium caseinate, due to its polarity.

Physical properties

Caseins are found in milk which is held together by colloidal calcium phosphate. Calcium caseinate is generally stable at a pH above 5.7, and appears as a milky liquid. This is unlike ammonium, potassium, and sodium caseinates, which are practically clear. At a neutral or acidic pH, casein is relatively insoluble in water, and is easily separated from other milk proteins, sugars, and minerals. Casein can be resuspended by alternating the pH levels with NaOH or Ca(OH)2, resulting in aqueous solutions of sodium caseinate or calcium caseinate. [4] Most caseinates are capable of withstanding temperatures of up to 140°C (284°F), however calcium caseinate is influenced by heat with temperatures as low as 50°C (122°F). [2] Calcium is a divalent cation, allowing it to form bonds with several caseinate anions. The binding of a calcium ion is able to reduce the electrostatic repulsion and induces a net attraction between caseins. [4] This leads to the formation of several covalent bonds between caseinate anions, which can ultimately cause the cross-linked caseinate to form pockets of hydrophobic regions. [5] Calcium caseinate forms visco-elastic suspensions which increase remarkably when increasing concentration (50–300 g L−1) and decreasing temperature(10–50 °C). [4]

Application in food

Powder milk Milk powder.jpg
Powder milk

Several foods, baked goods, creamers, and toppings all contain a variety of caseinates. Calcium caseinate's nutritional benefits include improving the structure configuration of foods; emulsifying and stabilizing fat; and enhancing foaming and foam stability. Sodium caseinate acts as a greater food additive for stabilizing processed foods, however companies could opt to use calcium caseinate to increase calcium content and decrease sodium levels in their products. [5]

There are two Calcium Caseinate forms, spray-dried (Scaca) or roller-dried (Rcaca) which are used for multiple applications. [6] Scaca can be found in dry milk powder, instant soups, medications, and instant coffee. It plays an important role in the conversion of fruit and vegetable juices into instant powders, instant coffees and teas, drying of eggs and dairy products such as ice cream mixes. Rcaca is mostly used in meat products and processed cheese. [6]

At high temperatures, Scaca can decrease while there is no impact on Rcaca. Some mechanical properties such as Fibrous calcium caseinate gel shows that its structure is more anisotropic than plant-based meat analogue candidates. [7] Its formation is strongly influenced because of its solvent isotope effect. 30% of Scaca mixed with H2O gives more anisotropic fibers. On the other hand, Rcaca results in a homogeneous gel meaning that there is no effect. [7] This demonstrates that both Scaca and Rcaca make a significant impact in the field of food science, given that these methods are commonly used for the industrial production of food biopolymers.

Calcium caseinate role in the body

Muscle mass

Caseinate, being a protein, plays an important role for muscle hypertrophy, which is the enlargement of muscle mass. Caseinate in particular has demonstrated to be more effective with this process compared to other types of proteins, such as soy- and whey-derived proteins. Consumption of caseinate leads to higher muscle weight and less fat weight gain compared to the other two proteins. [8]

Blood pressure and insulin regulation

In addition to the impact caseinate has on the body's muscle mass, it also has shown to help lower serum TAG for those who are hypertensive. Calcium caseinate supplementation has shown improvement in several cardiometabolic risk factors, such as blood pressure, arterial reactivity, lipid levels and blood vessel function. [9] Furthermore, Calcium caseinate can help lower central systolic blood pressure by improving endothelial function. This leads to better control of vascular relaxation and contraction, as well as blood clotting regulation, immune function and platelet adhesion. [9]

Calcium caseinate has also significantly lower insulin compared to whey protein and maltodextrin which reflected in reduced plasma nonesterified fatty acids and was also able to induce lower postprandial TAG concentrations. [9]

Related Research Articles

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Cream is a dairy product composed of the higher-fat layer skimmed from the top of milk before homogenization. In un-homogenized milk, the fat, which is less dense, eventually rises to the top. In the industrial production of cream, this process is accelerated by using centrifuges called "separators". In many countries, it is sold in several grades depending on the total butterfat content. It can be dried to a powder for shipment to distant markets, and contains high levels of saturated fat.

<span class="mw-page-title-main">Dairy product</span> Food product made from milk

Dairy products or milk products, also known as lacticinia, are food products made from milk. The most common dairy animals are cow, water buffalo, nanny goat, and ewe. Dairy products include common grocery store food around the world such as yogurt, cheese, milk and butter. A facility that produces dairy products is a dairy. Dairy products are consumed worldwide to varying degrees. Some people avoid some or all dairy products because of lactose intolerance, veganism, environmental concerns, other health reasons or beliefs.

<span class="mw-page-title-main">Milk</span> White liquid produced by the mammary glands of mammals

Milk is a white liquid food produced by the mammary glands of mammals. It is the primary source of nutrition for young mammals before they are able to digest solid food. Immune factors and immune-modulating components in milk contribute to milk immunity. Early-lactation milk, which is called colostrum, contains antibodies that strengthen the immune system and thus reduce the risk of many diseases. Milk contains many nutrients, including calcium and protein, but also lactose and saturated fat.

<span class="mw-page-title-main">Rennet</span> Complex of enzymes from the stomachs of young ruminant mammals, used in the production of cheese

Rennet is a complex set of enzymes produced in the stomachs of ruminant mammals. Chymosin, its key component, is a protease enzyme that curdles the casein in milk. In addition to chymosin, rennet contains other enzymes, such as pepsin and a lipase.

<span class="mw-page-title-main">Casein</span> Family of proteins found in milk

Casein is a family of related phosphoproteins that are commonly found in mammalian milk, comprising about 80% of the proteins in cow's milk and between 20% and 60% of the proteins in human milk. Sheep and cow milk have a higher casein content than other types of milk with human milk having a particularly low casein content.

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Whey is the liquid remaining after milk has been curdled and strained. It is a byproduct of the manufacturing of cheese or casein and has several commercial uses. Sweet whey is a byproduct resulting from the manufacture of rennet types of hard cheese, like cheddar or Swiss cheese. Acid whey is a byproduct brought out during the making of acid types of dairy products, such as strained yogurt.

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Buttermilk is a fermented dairy drink. Traditionally, it was the liquid left behind after churning butter out of cultured cream. As most modern butter in Western countries is not made with cultured cream but uncultured sweet cream, most modern buttermilk in Western countries is cultured separately. It is common in warm climates where unrefrigerated milk sours quickly.

<span class="mw-page-title-main">Processed cheese</span> Food product

Processed cheese is a product made from cheese mixed with an emulsifying agent. Additional ingredients, such as vegetable oils, unfermented dairy ingredients, salt, food coloring, or sugar may be included. As a result, many flavors, colors, and textures of processed cheese exist. Processed cheese typically contains around 50 to 60% cheese and 40 to 50% other ingredients.

<span class="mw-page-title-main">Powdered milk</span> Dehydrated milk product

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The Dietary Approaches to Stop Hypertension or the DASH diet is a diet to control hypertension promoted by the U.S.-based National Heart, Lung, and Blood Institute, part of the National Institutes of Health (NIH), an agency of the United States Department of Health and Human Services. The DASH diet is rich in fruits, vegetables, whole grains, and low-fat dairy foods. It includes meat, fish, poultry, nuts, and beans, and is limited in sugar-sweetened foods and beverages, red meat, and added fats. In addition to its effect on blood pressure, it is designed to be a well-balanced approach to eating for the general public. DASH is recommended by the United States Department of Agriculture (USDA) as a healthy eating plan. The DASH diet is one of three healthy diets recommended in the 2015–20 U.S. Dietary Guidelines, which also include the Mediterranean diet and a vegetarian diet. The American Heart Association (AHA) considers the DASH diet "specific and well-documented across age, sex and ethnically diverse groups."

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Cheese is a dairy product produced in a range of flavors, textures, and forms by coagulation of the milk protein casein. It comprises proteins and fat from milk. During production, milk is usually acidified and either the enzymes of rennet or bacterial enzymes with similar activity are added to cause the casein to coagulate. The solid curds are then separated from the liquid whey and pressed into finished cheese. Some cheeses have aromatic molds on the rind, the outer layer, or throughout.

<span class="mw-page-title-main">Sodium lactate</span> Chemical compound

Sodium lactate is the sodium salt of lactic acid, and has a mild saline taste. It is produced by fermentation of a sugar source, such as corn or beets, and then, by neutralizing the resulting lactic acid to create a compound having the formula NaC3H5O3.

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Pea protein is a food product and protein supplement derived and extracted from yellow and green split peas, Pisum sativum. It can be used as a dietary supplement to increase an individual's protein or other nutrient intake, or as a substitute for other food products. As a powder, it is used as an ingredient in food manufacturing, such as a thickener, foaming agent, or an emulsifier.

<span class="mw-page-title-main">Sour cream</span> Fermented dairy product

Sour cream is a dairy product obtained by fermenting regular cream with certain kinds of lactic acid bacteria. The bacterial culture, which is introduced either deliberately or naturally, sours and thickens the cream. Its name comes from the production of lactic acid by bacterial fermentation, which is called souring. Crème fraîche is one type of sour cream with a high fat content and less sour taste.

References

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  3. Hrsg., Caballero, Benjamin (2003). Encyclopedia of food sciences and nutrition. Acad. Press. ISBN   0-12-227074-6. OCLC   1071910943.{{cite book}}: CS1 maint: multiple names: authors list (link)
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  7. 1 2 Tian, Bei; Garcia Sakai, Victoria; Pappas, Catherine; van der Goot, Atze Jan; Bouwman, Wim G. (2019-11-02). "Fibre formation in calcium caseinate influenced by solvent isotope effect and drying method – A neutron spectroscopy study". Chemical Engineering Science. 207: 1270–1277. Bibcode:2019ChEnS.207.1270T. doi:10.1016/j.ces.2019.07.023. ISSN   0009-2509. S2CID   199071620.
  8. Aoyama, Shinya; Hirooka, Rina; Shimoda, Takeru; Shibata, Shigenobu (2019-12-01). "Effect of different sources of dietary protein on muscle hypertrophy in functionally overloaded mice". Biochemistry and Biophysics Reports. 20: 100686. doi:10.1016/j.bbrep.2019.100686. ISSN   2405-5808. PMC   6742840 . PMID   31528720.
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