A carbon print is a photographic print with an image consisting of pigmentedgelatin, rather than of silver or other metallic particles suspended in a uniform layer of gelatin, as in typical black-and-white prints, or of chromogenic dyes, as in typical photographic color prints.
In the original version of the printing process, carbon tissue (a temporary support sheet coated with a layer of gelatin mixed with a pigment—originally carbon black, from which the name derives) is bathed in a potassium dichromate sensitizing solution, dried, then exposed to strong ultraviolet light through a photographic negative, hardening the gelatin in proportion to the amount of light reaching it. The tissue is then developed by treatment with warm water, which dissolves the unhardened gelatin. The resulting pigment image is physically transferred to a final support surface, either directly or indirectly. In an important early 20th century variation of the process, known as carbro (carbon-bromide) printing, contact with a conventional silver bromide paper print, rather than exposure to light, was used to selectively harden the gelatin. A wide variety of colored pigments can be used instead of carbon black.
The process can produce images of very high quality which are exceptionally resistant to fading and other deterioration. It was developed in the mid-19th century in response to concerns about the fading of early types of silver-based black-and-white prints, which was already becoming apparent within a relatively few years of their introduction.
The most recent development in the process was made by the American photographer Charles Berger in 1993 with the introduction of a non-toxic sensitizer that presented none of the health and safety hazards of the toxic (now EU-restricted) dichromate sensitizer.
Carbon tissue
Carbon tissue, a layer of unsensitized pigmentedgelatin on a thin paper support sheet,[1] was introduced by Britishphysicist and chemistJoseph Swan[2][3] in 1864.[4] Marketing began in 1866. Initially, his ready-made tissues were sold in only three colors: black, sepia and purple-brown.[1][3] Eventually, a wide array of hues became available. Carbon tissue was a stock item in Europe and the US well into the 20th century,[1] but by the 1950s carbon printing was very rare and supplies for it became an exotic specialty item. Some companies produced small quantities of carbon tissue and transfer papers for monochrome and three-color work until around 1990.[1][3]
Overview and history of carbon printing
The carbon process, initially a black-and-white process using lampblack (carbon black), was invented by Alphonse Poitevin in 1855. The process was later adapted to color, through the use of pigments, by Louis Ducos du Hauron in 1868. Carbon printing remained commercially popular through the first half of the 20th century. It was replaced over time by the dye-transfer process, chromogenic, dye-bleach (or dye destruction, i.e. Cibachrome) and, now, digital printing processes. The efficiencies gained through these more modern automated processes relegated carbon printing to the commercial backwaters in the latter half of the 20th century. It is now only found in the darkrooms of the rare enthusiast and a few exotic labs.
Carbon printing is based on the fact that gelatin, when sensitized to light by a dichromate, is hardened and made insoluble in water when exposed to ultraviolet light. Because of the comparative insensitivity of the material, sunlight or another strong source of UV light is normally used to minimize the required exposure time. To make a full-color print, three negatives photographed through red, green and blue filters are printed on dichromate-sensitized sheets of pigmented gelatin (traditionally called "carbon tissue" regardless of the pigment incorporated) containing, respectively, cyan, magenta and yellow pigments. They are developed in warm water, which dissolves the unhardened gelatin, leaving a colored relief image that is thickest where it received the strongest exposure. The three images are then transferred, one at a time, onto a final support such as a heavy sheet of smooth gelatin-sized paper. Usually, the yellow image is transferred first, then the magenta image is applied on top of it, great care being taken to superimpose it in exact register, and then the cyan image is similarly applied. A fourth black pigment "key" layer is sometimes added, as in mechanical printing processes, to improve edge definition and mask any spurious color cast in the dark areas of the image, but it is not a traditional component.
The resulting finished print, whether composed of several layers and in full color or having only a single monochrome layer, exhibits a very slight bas-relief effect and a variation of texture on its surface, both distinctive characteristics of a carbon print. The process is time-consuming and labor-intensive. Each color carbon print requires three, or four, round trips in the darkroom to create the finished print. An individual, using existing pigmented sheets and separations, can prepare, print and process enough material, 60 sheets including the support, to produce about twelve 20" x 24" four-color prints in a 40-hour work week. However, this investment of time and effort can create prints of outstanding visual quality and proven archival permanence.
The carbon process can be used to produce:
Monochrome prints, usually black-and-white, but they may be sepia, cyan or any other preferred color.
Duochrome (duotone) prints, an effect many printers are familiar with, using complementary or associated colors to their best effect.
Trichrome prints, traditional full-color prints made by layering YMC (yellow, magenta and cyan) pigment sheets.
Quadrachrome prints, essentially full-color trichrome prints with an added black K (key) layer to increase density and mask any spurious color in dark areas.
Any combination of layers, in any color, is possible to achieve whatever ends the printer desires. There are two primary techniques used in carbon printing: single transfer and double transfer. This has to do with the negatives (separations) being right- or wrong-reading and the image "flopping" during the transfer process.
Because the carbon printing process uses pigments instead of dyes, it is capable of producing a far more archivally stable (permanent) print than any of the other color processes. Good examples of the color stability of pigments can be found in the paintings of the great masters, the true colors of which, in many cases, have survived all these centuries. A more contemporary example of the color stability of pigments is found in the paints used on automobiles today, which must survive intense daily exposure to very harsh lighting, under extreme conditions. The useful life of many (but not all) pigment formulations has been projected out to be several centuries and beyond (perhaps millennia, if cave paintings of Lascaux, the wall paintings in the tombs of the Valley of the Kings and the frescoes of Pompeii are relevant examples), often being limited only to the useful life of the particular support used. Additionally, the use of pigment also produces a wider color gamut than any of the other color processes, allowing for a greater range and subtlety of color reproduction.
Though carbon printing always has been, and remains, a labor-intensive, time-consuming and technologically demanding process, there are still those that prefer the high aesthetic of its remarkable beauty and longevity over all other processes.
Chronological History of Carbon (Pigment) Printing
Magenta is a purplish-red color. On color wheels of the RGB (additive) and CMY (subtractive) color models, it is located precisely midway between red and blue. It is one of the four colors of ink used in color printing by an inkjet printer, along with yellow, cyan, and black to make all the other colors. The tone of magenta used in printing, printer's magenta, is redder than the magenta of the RGB (additive) model, the former being closer to rose.
Photographic processing or photographic development is the chemical means by which photographic film or paper is treated after photographic exposure to produce a negative or positive image. Photographic processing transforms the latent image into a visible image, makes this permanent and renders it insensitive to light.
Photographic paper is a paper coated with a light-sensitive chemical formula, like photographic film, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion. The most common chemistry was based on silver halide but other alternatives have also been used.
Subtractive color or subtractive color mixing predicts the spectral power distribution of light after it passes through successive layers of partially absorbing media. This idealized model is the essential principle of how dyes and pigments are used in color printing and photography, where the perception of color is elicited after white light passes through microscopic "stacks" of partially absorbing media allowing some wavelengths of light to reach the eye and not others, and also in painting, whether the colors are mixed or applied in successive layers.
Photographic printing is the process of producing a final image on paper for viewing, using chemically sensitized paper. The paper is exposed to a photographic negative, a positive transparency , or a digital image file projected using an enlarger or digital exposure unit such as a LightJet or Minilab printer. Alternatively, the negative or transparency may be placed atop the paper and directly exposed, creating a contact print. Digital photographs are commonly printed on plain paper, for example by a color printer, but this is not considered "photographic printing".
Photogravure is a process for printing photographs, also sometimes used for reproductive intaglio printmaking. It is a photo-mechanical process whereby a copper plate is grained and then coated with a light-sensitive gelatin tissue which had been exposed to a film positive, and then etched, resulting in a high quality intaglio plate that can reproduce detailed continuous tones of a photograph.
Color printing or colour printing is the reproduction of an image or text in color.
Potassium dichromate, K2Cr2O7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in laboratories because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.
The term alternative process refers to any non-traditional or non-commercial photographic printing process. Currently, the standard analog photographic printing process for black-and-white photographs is the gelatin silver process. Standard digital processes include the pigment print, and digital laser exposures on traditional color photographic paper.
Gum printing is a way of making photographic reproductions without the use of silver halides. The process uses salts of dichromate in common with a number of other related processes such as sun printing.
Color motion picture film refers both to unexposed color photographic film in a format suitable for use in a motion picture camera, and to finished motion picture film, ready for use in a projector, which bears images in color.
A Woodburytype is both a printing process and the print that it produces. In technical terms, the process is a photomechanical rather than a photographic one, because sensitivity to light plays no role in the actual printing. The process produces very high quality continuous tone images in monochrome, with surfaces that show a slight relief effect. Essentially, a Woodburytype is a mold produced copy of an original photographic negative with a tonal range similar to a Carbon print.
Thermal paper is a special fine paper that is coated with a material formulated to change color locally when exposed to heat. It is used in thermal printers, particularly in inexpensive devices such as adding machines, cash registers, and credit card terminals and small, lightweight portable printers.
Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films, paper, or fabric. The substrate is often flexible and known as a film base.
Dye transfer is a continuous-tone color photographic printing process. It was used to print Technicolor films, as well as to produce paper colour prints used in advertising, or large transparencies for display.
Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast, and resolution of the film. Film is typically segmented in frames, that give rise to separate photographs.
Technicolor is a series of color motion picture processes, the first version dating back to 1916, and followed by improved versions over several decades.
Art photography print types refers to the process and paper of how the photograph is printed and developed.
The oil print process is a photographic printmaking process that dates to the mid-19th century. Oil prints are made on paper on which a thick gelatin layer has been sensitized to light using dichromate salts. After the paper is exposed to light through a negative, the gelatin emulsion is treated in such a way that highly exposed areas take up an oil-based paint, forming the photographic image.
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