Chanabayaite

Last updated
Chanabayaite
Chanabayaite.jpg
General
Category Organic mineral
Formula
(repeating unit)
Cu
2
(N
3
C
2
H
2
Cl(NH
3
,Cl,H
2
O,[])
4
IMA symbol Cba [1]
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Imma
Unit cell a = 19.48, b = 7.21,
c = 11.999 [Å] (approximated); Z = 4
Identification
ColorBlue
Crystal habit Prisms (imperfect); radial aggregates
Cleavage (001), perfect; (100) and (010), imperfect
Tenacity Brittle
Mohs scale hardness2
Density 1.48 (measured)
Pleochroism Deep blue to pale blue with gray hue (strong)
References [2] [3] [4]

Chanabayaite is the first recognized triazolate mineral, having the formula Cu
2
(N
3
C
2
H
2
Cl(NH
3
,Cl,H
2
O,[])
4
.

Contents

Minor iron admixture is also present. [3] It is also one of a few currently known minerals containing ammine groups, including also ammineite, joanneumite and shilovite. [5] [6] [7] All the minerals are rare and were found in a single guano deposit in Chile, called Pabellón de Pica. [4] A similar natural phase, formula NaCu
2
Cl
3
[N
3
C
2
H
2
]
2
[NH
3
]
2
•4H
2
O
, likely a precursor of chanabayaite, is described by Zubkova et al. 2016. [8]

Crystal structure

The main features of the crystal structure of chanabayaite are: [3]

Association

Chanabayaite coexists with halite, joanneumite, nitratine, salammoniac and paragenetically-unrelated chalcopyrite. Chalcopyrite is present in an amphibole- and plagioclase-bearing gabbro, that contacts the guano deposit. [3]

Formation

Three suggested processes account for the formation of chanabayaite: [3]

Related Research Articles

<span class="mw-page-title-main">Zorite</span>

Zorite is a silicate mineral with the chemical formula of Na2Ti(Si,Al)3O9·nH2O. It is named because of its pink color, after the Russian word "zoria" which refers to the rosy hue of the sky at dawn. It is primarily found in Mount Karnasurta, Lovozero Massif, Kola Peninsula, Russia. The Lovozero Massif is an area with an igneous mountain range, home to various types of minerals such as eudialyte, loparite, and natrosilitite.

Farneseite is a mineral from the cancrinite sodalite group with 14 layer stacking. It is a complex silicate mineral with formula (Na,Ca,K)56(Al6Si6O24)7(SO4)12·6H2O. It was named after a location in Farnese, Lazio, Italy. It is a member of the cancrinite-sodalite group, approved in 2004 as a new mineral species. The group is characterized by the number of stacking layers making up each member, with farneseite being one of newest minerals in the group with a 14 layer stacking structure. It is a clear transparent mineral and has a hexagonal crystal system with crystal class of 6/m and space group of P63/m. The specimens discovered in Farnese were in a pyroclastic rock from the Làtera Cauldera region.

<span class="mw-page-title-main">Ammineite</span>

Ammineite is the first recognized mineral containing ammine groups. Its formula is [CuCl2(NH3)2]. The mineral is chemically pure. It was found in a guano deposit in Chile. At the same site other ammine-containing minerals were later found:

<span class="mw-page-title-main">Joanneumite</span>

Joanneumite, confirmed as a new mineral in 2012, is the first recognized isocyanurate mineral, with the formula Cu(C3N3O3H2)2(NH3)2. It is also an ammine-containing mineral, a feature shared with ammineite, chanabayaite and shilovite. All the minerals are very rare and were found in a guano deposit in Pabellón de Pica, Chile.

Feodosiyite is a very rare chloride mineral, just recently approved, with the formula Cu11Mg2Cl18(OH)8•16H2O. Its structure is unique. Feodosiyite comes from the Tolbachik volcano, famous for many rare fumarolic minerals. Chemically similar minerals, chlorides containing both copper and magnesium, include haydeeite, paratacamite-(Mg) and tondiite.

Genplesite is a very rare tin mineral coming from the Oktyabr'skoe deposit in the Noril'sk area, Russia, which is known for nickel and platinum group elements minerals. Its chemical formula is Ca3Sn(SO4)2(OH)6•3H2O. Genplesite is a member of the fleischerite group, and it is a calcium and tin-analogue of fleischerite. It is hexagonal, with space group P63/mmc.

Chrysothallite is a rare thallium-bearing chloride mineral with the formula K6Cu6Tl3+Cl17(OH)4•H2O. Chrysothallite is unique in being only the second mineral with essential trivalent thallium, a feature shared with natural thallium(III) oxide, avicennite. Another examples of natural thallium chlorides are steropesite, Tl3BiCl6, and lafossaite, TlCl. Chrysothallite is one of numerous fumarolic minerals discovered among fumarolic sites of the Tolbachik volcano, Kamchatka, Russia The mineral is named in allusion to its colour and thallium content.

Kainotropite is a rare vanadate mineral with the formula Cu4FeO2(V2O7)(VO4). It contains trivalent iron. It is one of many fumarolic minerals discovered on the Tolbachik volcano. The name of its parental fumarole is "Yadovitaya", which means poisonous.

<span class="mw-page-title-main">Sturmanite</span>

Sturmanite is a rare sulfate mineral with the chemical formula Ca6Fe3+2(SO4)2.5(B(OH)4)(OH)12 · 25 H2O. It crystallises in the tetragonal system and it has a Moh's hardness of 2.5. Sturmanite has a bright yellow to amber colour and falls in the ettringite group. It was named after Bozidar Darko Sturman (born 1937), Croatian-Canadian mineralogist and Curator Emeritus of Mineralogy, Royal Ontario Museum.

<span class="mw-page-title-main">Triazolite</span>

Triazolite is an organic mineral with the chemical structure of NaCu2(N3C2H2)2(NH3)2Cl3·4H2O, and is formed in conjunction with chanabayite, another natural triazolate. Triazolite has only been found in Pabellón de Pica, Chanabaya, Iquique Province, Tarapacá Region, Chile, due to its specific requirements for formation. The first specimens of triazolite were found in what is suspected to be the guano of the Guanay cormorant. The guano reacted to chalcopyrite-bearing gabbro, allowing the formation for triazolite to take place. Triazolite was initially grouped together with chanabayite in 2015, and wasn't identified as a separate mineral until 2017.

Lemanskiite is a mineral that was first discovered in a mine at Abundancia mine, El Guanaco mining district, Chile, with the ideal formula of NaCaCu5(AsO4)4Cl•3H2O. Originally, this mineral was discovered as being dimorphus with lavendulan, but in 2018 it was revised to only have 3 water molecules. Lemanskiite typically occurs as rosette-shaped aggregates of thin lamellar or needle-shaped aggregates, such as lammerite. Lemanskiite is dark sky blue with a light blue streak, it is brittle with an excellent cleavage plane. It was found on a dumping site in the abandoned Abundancia mine, El Guanaco mining district, Region II, Antofagasta Province, Chile The new mineral has been named after Chester S. Lemanski, Jr. This mineral and name were then approved by the Commission on New Minerals and Mineral Names of the International Mineralogical Association.

The carbonate chlorides are double salts containing both carbonate and chloride anions. Quite a few minerals are known. Several artificial compounds have been made. Some complexes have both carbonate and chloride ligands. They are part of the family of halocarbonates. In turn these halocarbonates are a part of mixed anion materials.

Wulffite is an alkali copper sulfate mineral with the chemical formula K3NaCu4O2(SO4)4, in the sulfate category of minerals. It was recently discovered in Kamchatka, Russia at the Tolbachik volcano in 2012. It was named for Russian crystallographer Georgiy Viktorovich Wulff, a renowned expert who furthered X-ray diffraction and interference. Wullfite shares many properties with parawulffite, which was found in the same area just with slightly different chemical composition.

Euchlorine (KNaCu3(SO4)3O) is a rare emerald-green colored sulfate mineral found naturally occurring as a sublimate in fumaroles around volcanic eruptions. It was first discovered in fumaroles of the 1868 eruption at Mount Vesuvius in Campania, Italy by Arcangelo Scacchi. The name 'euchlorine' comes from the Greek word εΰχλωρος meaning "pale green" in reference to the mineral's color, other reported spellings include euclorina, euchlorin, and euchlorite.

The sulfate chlorides are double salts containing both sulfate (SO42–) and chloride (Cl) anions. They are distinct from the chlorosulfates, which have a chlorine atom attached to the sulfur as the ClSO3 anion.

The sulfate nitrates are a family of double salts that contain both sulfate and nitrate ions (NO3, SO42−). They are in the class of mixed anion compounds. A few rare minerals are in this class. Two sulfate nitrates are in the class of anthropogenic compounds, accidentally made as a result of human activities in fertilizers that are a mix of ammonium nitrate and ammonium sulfate, and also in the atmosphere as polluting ammonia, nitrogen dioxide, and sulfur dioxide react with the oxygen and water there to form solid particles. The nitro group (NO3) can act as a ligand, and complexes containing it can form salts with sulfate.

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

<span class="mw-page-title-main">Fumarole mineral</span> Minerals which are deposited by fumarole exhalations

Fumarole minerals are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes following deposition from volcanic gas during an eruption or discharge from a volcanic vent or fumarole, but have been encountered on burning coal deposits as well. They can be black or multicoloured and are often unstable upon exposure to the atmosphere.

Balliranoite ((Na,K)6Ca2(Si6Al6O24)Cl2(CO)3) is a mineral that was discovered at Monte Somma – Vesuvio volcanic complex, Campania, Italy. This mineral is named in honor of Paolo Ballirano (b. 1964), Italian crystallographer and professor in the Department of Earth Sciences, University of Rome ‘‘La Sapienza’’, who has made important contributions to the crystal chemistry of cancrinite-group minerals.

Potassium trichloridocuprate(II) is a salt with chemical formula KCuCl3, more properly [K+]2[Cu2Cl2−4].

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mineralienatlas
  3. 1 2 3 4 5 Chukanov, N.V., Zubkova, N.V., Möhn, G., Pekov, I.V., Pushcharovsky, D.Yu., and Zadov, A.E., 2015. Chanabayaite, Cu2(N3C2H2Cl(NH3,Cl,H2O,[])4, a new mineral containing triazolate anion. Geology of Ore Deposits 57(8), 712-720.
  4. 1 2 "Chanabayaite: Chanabayaite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  5. "Ammineite: Ammineite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  6. "Joanneumite: Joanneumite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  7. "Shilovite: Shilovite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  8. Zubkova, N.V., Chukanov, N.V., Pekov, I., and Pushcharovsky, D., 2016. The crystal structure of the natural 1,2,4-triazolate compound NaCu
    2
    Cl
    3
    [N
    3
    C
    2
    H
    2
    ]
    2
    [NH
    3
    ]
    2
    •4H
    2
    O
    . Zeitschrift für Kristallographie - Crystalline Materials 231(1), 47–53.