Charge exchange (or charge exchange collision) is a process in which a neutral atom or molecule collides with an ion, resulting in the neutral atom acquiring the charge of the ion. [1] The reaction is typically expressed as
This reaction has various diagnostic applications, such as in plasma physics and mass spectrometry. [2]
When a neutral atom collides with an ion in a gas or a plasma, the ion can acquire an electron from the neutral atom as both electron shells overlap in the course of the collision. This can be used in various applications.
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Charge-exchange spectroscopy (abbreviated CES or CXS) is a technique commonly used in plasma diagnostics to analyze high-temperature controlled fusion plasmas. In fusion plasmas, the light elements tend to become fully ionized during operation, which makes it challenging to diagnose their properties using conventional optical diagnostics. To address this, a method was developed in the 1970s which involves the injection of a beam of neutral atoms, such as hydrogen or deuterium, into the plasma. [3] This process results in the ionization of hydrogenic atoms the excitation of ions through charge exchange, as represented by the reaction:
where represents the various possible charged states of the ions in the plasma.
Optical fibers are then strategically positioned to create "chords", lines of sight along which the measurements are taken. These chords pass through regions both with and without the neutral beam. By subtracting the signals from these two chords, emissions not generated by the neutral beam can be inferred. This allows for the determination of ion properties, such as its temperature and density.
The technique can also be extended to include multiple chords to build spatial profiles of the plasma, such as its toroidal and poloidal rotation. This provides insights into how ions conduct heat and transport momentum within the plasma. [3]
Charge-exchange spectroscopy is often referred to as charge-exchange recombination spectroscopy, which is acronymized as CXRS [4] or CER. [5]
An ion source is a device that creates atomic and molecular ions. Ion sources are used to form ions for mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters and ion engines.
Plasma diagnostics are a pool of methods, instruments, and experimental techniques used to measure properties of a plasma, such as plasma components' density, distribution function over energy (temperature), their spatial profiles and dynamics, which enable to derive plasma parameters.
Electron cyclotron resonance (ECR) is a phenomenon observed in plasma physics, condensed matter physics, and accelerator physics. It happens when the frequency of incident radiation coincides with the natural frequency of rotation of electrons in magnetic fields. A free electron in a static and uniform magnetic field will move in a circle due to the Lorentz force. The circular motion may be superimposed with a uniform axial motion, resulting in a helix, or with a uniform motion perpendicular to the field resulting in a cycloid. The angular frequency of this cyclotron motion for a given magnetic field strength B is given by
Tandem mass spectrometry, also known as MS/MS or MS2, is a technique in instrumental analysis where two or more stages of analysis using one or more mass analyzer are performed with an additional reaction step in between these analyses to increase their abilities to analyse chemical samples. A common use of tandem MS is the analysis of biomolecules, such as proteins and peptides.
A glow discharge is a plasma formed by the passage of electric current through a gas. It is often created by applying a voltage between two electrodes in a glass tube containing a low-pressure gas. When the voltage exceeds a value called the striking voltage, the gas ionization becomes self-sustaining, and the tube glows with a colored light. The color depends on the gas used.
The Madison Symmetric Torus (MST) is a reversed field pinch (RFP) physics experiment with applications to both fusion energy research and astrophysical plasmas.
Neutral-beam injection (NBI) is one method used to heat plasma inside a fusion device consisting in a beam of high-energy neutral particles that can enter the magnetic confinement field. When these neutral particles are ionized by collision with the plasma particles, they are kept in the plasma by the confining magnetic field and can transfer most of their energy by further collisions with the plasma. By tangential injection in the torus, neutral beams also provide momentum to the plasma and current drive, one essential feature for long pulses of burning plasmas. Neutral-beam injection is a flexible and reliable technique, which has been the main heating system on a large variety of fusion devices. To date, all NBI systems were based on positive precursor ion beams. In the 1990s there has been impressive progress in negative ion sources and accelerators with the construction of multi-megawatt negative-ion-based NBI systems at LHD (H0, 180 keV) and JT-60U (D0, 500 keV). The NBI designed for ITER is a substantial challenge (D0, 1 MeV, 40 A) and a prototype is being constructed to optimize its performance in view of the ITER future operations. Other ways to heat plasma for nuclear fusion include RF heating, electron cyclotron resonance heating (ECRH), ion cyclotron resonance heating (ICRH), and lower hybrid resonance heating (LH).
The tokamak à configuration variable is an experimental tokamak located at the École Polytechnique Fédérale de Lausanne (EPFL) Swiss Plasma Center (SPC) in Lausanne, Switzerland. As the largest experimental facility of the Swiss Plasma Center, the TCV tokamak explores the physics of magnetic confinement fusion. It distinguishes itself from other tokamaks with its specialized plasma shaping capability, which can produce diverse plasma shapes without requiring hardware modifications.
In mass spectrometry, direct analysis in real time (DART) is an ion source that produces electronically or vibronically excited-state species from gases such as helium, argon, or nitrogen that ionize atmospheric molecules or dopant molecules. The ions generated from atmospheric or dopant molecules undergo ion-molecule reactions with the sample molecules to produce analyte ions. Analytes with low ionization energy may be ionized directly. The DART ionization process can produce positive or negative ions depending on the potential applied to the exit electrode.
Penning ionization is a form of chemi-ionization, an ionization process involving reactions between neutral atoms or molecules. The Penning effect is put to practical use in applications such as gas-discharge neon lamps and fluorescent lamps, where the lamp is filled with a Penning mixture to improve the electrical characteristics of the lamps.
High-harmonic generation (HHG) is a non-linear process during which a target is illuminated by an intense laser pulse. Under such conditions, the sample will emit the high harmonics of the generation beam. Due to the coherent nature of the process, high-harmonics generation is a prerequisite of attosecond physics.
Electron beam ion trap (EBIT) is an electromagnetic bottle that produces and confines highly charged ions. An EBIT uses an electron beam focused with a powerful magnetic field to ionize atoms to high charge states by successive electron impact.
Rydberg matter is an exotic phase of matter formed by Rydberg atoms; it was predicted around 1980 by É. A. Manykin, M. I. Ozhovan and P. P. Poluéktov. It has been formed from various elements like caesium, potassium, hydrogen and nitrogen; studies have been conducted on theoretical possibilities like sodium, beryllium, magnesium and calcium. It has been suggested to be a material that diffuse interstellar bands may arise from. Circular Rydberg states, where the outermost electron is found in a planar circular orbit, are the most long-lived, with lifetimes of up to several hours, and are the most common.
A ball-pen probe is a modified Langmuir probe used to measure the plasma potential in magnetized plasmas. The ball-pen probe balances the electron and ion saturation currents, so that its floating potential is equal to the plasma potential. Because electrons have a much smaller gyroradius than ions, a moving ceramic shield can be used to screen off an adjustable part of the electron current from the probe collector.
The Gas Dynamic Trap is a magnetic mirror machine being operated at the Budker Institute of Nuclear Physics in Akademgorodok, Russia.
The magnesium argide ion, MgAr+ is an ion composed of one ionised magnesium atom, Mg+ and an argon atom. It is important in inductively coupled plasma mass spectrometry and in the study of the field around the magnesium ion. The ionization potential of magnesium is lower than the first excitation state of argon, so the positive charge in MgAr+ will reside on the magnesium atom. Neutral MgAr molecules can also exist in an excited state.
Dmitri Dmitriyevich Ryutov is a Russian theoretical plasma physicist.
Keith Howard Burrell is an American plasma physicist.
Jürgen Meyer-ter-Vehn is a German theoretical physicist who specializes in laser-plasma interactions at the Max Planck Institute for Quantum Optics. He published under the name Meyer until 1973.
