Industry | Chemical |
---|---|
Founded | 1876 |
Founder | Charles Dreyfus |
Fate | Acquired |
Headquarters | Clayton, Manchester, England |
Products | Dyestuffs |
The Clayton Aniline Company Ltd. was a British manufacturer of dyestuffs, founded in 1876 by Charles Dreyfus in Clayton, Manchester. [1]
Charles Dreyfus was a French emigrant chemist and entrepreneur, who founded the Clayton Aniline Company on 29 May 1876. The company obtained a lease on a parcel of land in Clayton, Manchester, sandwiched between the Manchester and Ashton Canal and Chatham Street (later known as Clipstone Street). With an initial share capital of £40,000 [lower-alpha 1] the company began production of aniline and aniline salt. [3]
In 1894, a brilliant young organic chemist Arthur George Green joined the company. Green had discovered the dye primuline in 1887 and under his guidance the company rapidly expanded its range of dyes. Green left the company in 1901.
In 1897, the company was placed into voluntary liquidation and then reformed under the same name with an issued share capital of £140,000. Max Baerlein was appointed as company chairman with Charles Dreyfus as managing director. On 31 January 1900 a yooung worker, Thomas Musgrave, became caught in machinery and was killed instantly. [4]
Chaim Weizmann joined the company in 1905 as a part-time research consultant, leaving in 1908 to pursue an academic career. Weizmann would later achieve fame through his work on bacterial fermentation and go on to become the first president of Israel.
On 1 May 1911, the Society of Chemical Industry in Basle (later known as CIBA), took control of the company and in 1913 Charles Dreyfus resigned. [3]
The outbreak of war with Germany in 1914 led to lucrative contracts for the company including the production of 1,500 tons of TNT. The sites facilities were expanded considerably during the war including the construction of a new azo dyes plant (building 183) in 1918. TNT manufacture at the plant ceased following a series of accidents at other explosives factories such as those at Silvertown and Ashton-under-Lyne. Sylvain Dreyfus, a nephew of Charles Dreyfus, perished in the Ashton-under-Lyne disaster when the Hooley Hill Rubber and Chemical Works exploded. These and other accidents prompted the Government to concentrate explosives manufacture at factories sited well away from built up areas.
The construction of a new railway line was begun in 1916, that linked the works via a bridge across Ashton New Road to the existing Stuart Street Power Station branch line. [5]
In September 1918, the Basle Community of Interests was formed from an alliance between Society of Chemical Industry in Basle, the Sandoz Chemical Company Ltd and J.R. Geigy SA. The agreement between the three companies allowed the sharing of research and technical resources whilst each company retained its own autonomy. Later that same year, Sandoz and Geigy each acquired a financial interest in the Clayton Aniline Company.
During the inter war period the company continued to invest in new plant and products. The Dyestuffs (Import Regulation) Act 1920 had given British dye producers much needed protection from cheap imports and provided an impetus to increasing the range of dyes and intermediates produced at Clayton. In 1930, an additional azo dyes plant (building 187) was completed followed in 1938 by the construction of a new vat dyes complex (buildings 188, 189 and 190). The completion of the vat dyes project was held up by the outbreak of war in 1939.
In 1940, a new Ministry of Supply factory (building 300) was constructed adjacent to the site for the manufacture of explosives additive Centralite I. The company also gained an important contract to manufacture monomethylaniline used as an antiknock agent in high octane aviation fuel. In 1941, a new aniline plant was built with an output of around 100 tons per week.
On 5 October 1942, a near catastrophe befell the site when an ethylation autoclave caught fire, which threatened the adjacent phosgenation unit. Department manager Eric Shaw risked his life to disconnect and remove to safety gas cylinders filled with phosgene, that were in danger of exploding. Shaw was awarded an MBE in 1943 for his actions. [6] Also commended for their bravery were J.T. Read, J. Wood and R. Dean. [3]
The Second World War ended in 1945 and the company began its post war reconstruction. The Centralite plant (building 300) was acquired from the Government and re-equipped as an intermediates plant and plans were drawn up for a new intermediates plant (building 151) which was completed in 1951. Other projects undertaken in the early 1950s included a new PAK-ice plant, a new power plant and a new waste gas tunnel and chimney. The company also began the removal of a chemical spoil heap nicknamed the “mucky mountain”, which was left behind by a soda ash manufacturer that previously occupied the site. [3]
In 1957, a plan was drawn up to re-build virtually the whole of the site. The project involved the construction of a new triphenylmethane dyes plant (building 75), a new laboratories block (building 80), a milling and blending plant (building 81), an intermediates plant (building 74) and a new azo dyes plant (building 48). An additional azo dyes plant (building 46) was added to the scheme in 1965 to replace (building 187). Extra warehousing was also added to the site including a new intermediates warehouse (building 71) and a new raw materials warehouse (building 50).
1964 marked the end of an era for the company with the decision to cease aniline production at Clayton. The aniline plant was demolished the following year. [3]
In 1971, CIBA and Geigy merged to form CIBA-GEIGY. The combined group retained a majority shareholding in the Clayton Aniline Company with Sandoz holding the remaining 25% of the equity. CAC was allowed to continue as a separate subsidiary under the chairmanship of Sir Arthur Vere Harvey.
At its peak in the 1970s, the site occupied over 57 acres and employed over 2,000 people. However, due to the gradual demise of the British textile industry, most textile production shifted to countries such as China and India with the textile dye industry following.
CIBA merged their life science businesses with Sandoz in 1997, forming Novartis and Syngenta, and spinning off their respective industrial chemicals' businesses separately to form Ciba Speciality Chemicals and Clariant respectively. This left Clayton as a manufacturing site for direct dyes for cotton, disperse dyes for polyester and metal complex dyes for wool and nylon; and pigments used for carbonless copying and thermal printer papers.
Initially the whole site was designated as part of the "Colors" business unit of Ciba Specialty Chemicals; but later the dyes manufacturing, logistics and site management became part of the Textile Effects division, while the carbonless copying paper business was made part of the Consumer Chemicals division and Clayton was designated the global centre for R&D, marketing and sales this type of product.
Manufacturing was gradually transferred to China, India, Thailand and Mexico in response to sustained price competition from emerging competitors in China and India and the workforce was reduced accordingly. In 2004 the announcement was made that the site would be closing with the loss of over 300 remaining jobs. A small number of staff were retained to assist in the decommissioning of the plant. The last workers left the site in 2007 and the remainder of the buildings were demolished shortly afterwards. [1]
Although initially expected to be re-used for housing, the site remained undeveloped for a number of years afterwards. Then in 2012, City Football Group (CFG) announced that they would be building a world-class training and academy complex for all Manchester City men's, women's and youth football teams; a new 7,000 capacity academy stadium; an institute of sport; a sixth form college and their new global operational HQ on the site and its surrounding area, which would accompany the City of Manchester Stadium which opened opposite the site in 2002. These new facilities opened in December 2014 after two years of land remediation and construction work. [7] [8] [9]
A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and may require a mordant to improve the fastness of the dye on the fiber.
Novartis AG is a Swiss multinational pharmaceutical corporation based in Basel, Switzerland. Consistently ranked in the global top five, Novartis is one of the largest pharmaceutical companies in the world and was the fourth largest by revenue in 2022.
BASF SE, an initialism and portmanteau of its original name Badische Anilin- und Sodafabrik, is a European multinational company and the largest chemical producer in the world. Its headquarters are located in Ludwigshafen, Germany.
Ciba was a chemical company based in and near Basel, Switzerland. "Ciba" stood for "Chemische Industrie Basel". It was formed when the non-pharmaceuticals elements of Novartis were spun out in 1997, following the merger in the previous year of Ciba-Geigy and Sandoz that created Novartis.
Azo compounds are organic compounds bearing the functional group diazenyl.
Allied Corp. was a major American company with operations in the chemical, aerospace, automotive, oil and gas industries. It was initially formed in 1920 as the Allied Chemical and Dye Corporation as an amalgamation of five chemical companies. In 1958, it was renamed Allied Chemical Corporation when it diversified into oil and gas exploration. Allied Chemical then became Allied Corporation in 1981. In 1985, Allied merged with the Signal Companies to become AlliedSignal. AlliedSignal would eventually acquire Honeywell in 1999 and then adopt its name.
Ilfochrome is a dye destruction positive-to-positive photographic process used for the reproduction of film transparencies on photographic paper. The prints are made on a dimensionally stable polyester base as opposed to traditional paper base. Since it uses 13 layers of azo dyes sealed in a polyester base, the print will not fade, discolour, or deteriorate for an extended time. Accelerated aging tests conducted by Henry Wilhelm rated the process as producing prints which, framed under glass, would last for 29 years before color shifts could be detected. Characteristics of Ilfochrome prints are image clarity, color purity, and being an archival process able to produce critical accuracy to the original transparency.
Azo dyes are organic compounds bearing the functional group R−N=N−R′, in which R and R′ are usually aryl and substituted aryl groups. They are a commercially important family of azo compounds, i.e. compounds containing the C-N=N-C linkage. Azo dyes are synthetic dyes and do not occur naturally. Most azo dyes contain only one azo group, but some dyes contain two or three azo groups, called "diazo dyes" and "triazo dyes" respectively. Azo dyes comprise 60-70% of all dyes used in food and textile industries. Azo dyes are widely used to treat textiles, leather articles, and some foods. Chemically related derivatives of azo dyes include azo pigments, which are insoluble in water and other solvents.
Clariant AG is a Swiss multinational speciality chemical company, formed in 1995 as a spin-off from Sandoz. Headquartered in Muttenz, Switzerland, the public company encompasses 74 subsidiaries in 36 countries (2022). Major manufacturing sites are located in Europe, North America, South America, China, and India. In 2022, sales from continuing operations were 5.198 billion CHF.
Harman Technology, trading as Ilford Photo, is a UK-based manufacturer of photographic materials known worldwide for its Ilford branded black-and-white film, papers and chemicals and other analog photography supplies. Historically it also published the Ilford Manual of Photography, a comprehensive manual of everything photographic, including the optics, physics and chemistry of photography, along with recipes for many developers.
Charles Dreyfus was President of the Manchester Zionist Society, a member of Manchester City Council and a leading figure in the East Manchester Conservative Association during the time that Arthur Balfour was Member of Parliament for the constituency and Prime Minister. At Dreyfus' suggestion Balfour and the Zionist leader Chaim Weizmann first met at a constituency meeting on 27 January 1905. Dreyfus had been introduced to Weizmann by the Zionist activist and writer Joseph Massel. Dreyfus was Weizmann's employer in Manchester and remained a friend until his death.
British Dyestuffs Corporation Ltd (BDC) was a British company formed in 1919 from the merger of British Dyes Ltd with Levinstein Ltd. The British Government was the company's largest shareholder, and had two directors on the board.
Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources—roots, berries, bark, leaves, and wood—and other biological sources such as fungi.
The Ashton-under-Lyne munitions explosion occurred on 13 June 1917 when the Hooley Hill Rubber and Chemical Works caught fire and exploded. The factory was engaged in the production of TNT for the war effort and was completely destroyed. Forty-three people were killed and most of the surrounding area was left devastated.
The pharmaceutical industry in Switzerland directly and indirectly employs about 135,000 people. It contributes to 5.7% of the gross domestic product of Switzerland and contributes to 30% of the country's exports. In 2017 about 30% of Swiss exports were chemical products. In the same year Switzerland was the second largest exporter of packaged medicine in the world, with about 11% of the global total, worth $36.5 billion.
Atul Ltd (Atul) is an integrated chemical company founded by Kasturbhai Lalbhai on September 5, 1947 in India. The company manufactures 900 products and 400 formulations and owns 140 retail brands. It serves 4,000 customers belonging to 30 diverse industries and has established subsidiary companies in the US, the UK, the UAE, China and Brazil to serve its customers.
Rudolf Hugo Nietzki was a German chemist who specialized in industrial dyes derived from coal tar. While a professor at the University of Basel in Switzerland he initiated the university's association with to the local chemical industry.
Azuline is a coal-tar blue dye that became popular for colouring silk in 1861. It was one of the first synthetic dyes. The name was a combination of "azure" and "aniline". A variant of the name was "Azurine". The word was introduced as a colour term about the same time as "mauve" and "magenta", but it has not survived in the English language.
Vinyl sulfone dyes are reactive dyes comprising a vinyl sulfone group as reactive group (a fiber-bonding site of the reactive dye, "reactive hook"). Due to the relatively high reactivity of the vinyl sulfone group with water (residual moisture, air humidity), it is present in many commercial products in a protected form. For protection, an ethylsulfonyl group is substituted with a leaving group. During the dyeing process under alkaline conditions, the vinyl sulfone group is released by an elimination reaction:
Formation of the vinyl sulfone group by alkaline elimination. R= alkyl or aryl radical, X=-OSO3H, -Cl
A colorant is any substance that changes the spectral transmittance or reflectance of a material. Synthetic colorants are those created in a laboratory or industrial setting. The production and improvement of colorants was a driver of the early synthetic chemical industry, in fact many of today's largest chemical producers started as dye-works in the late 19th or early 20th centuries, including Bayer AG(1863). Synthetics are extremely attractive for industrial and aesthetic purposes as they have they often achieve higher intensity and color fastness than comparable natural pigments and dyes used since ancient times. Market viable large scale production of dyes occurred nearly simultaneously in the early major producing countries Britain (1857), France (1858), Germany (1858), and Switzerland (1859), and expansion of associated chemical industries followed. The mid-nineteenth century through WWII saw an incredible expansion of the variety and scale of manufacture of synthetic colorants. Synthetic colorants quickly became ubiquitous in everyday life, from clothing to food. This stems from the invention of industrial research and development laboratories in the 1870s, and the new awareness of empirical chemical formulas as targets for synthesis by academic chemists. The dye industry became one of the first instances where directed scientific research lead to new products, and the first where this occurred regularly.
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