Constictic acid

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Constictic acid
Constictic acid.svg
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/C19H14O10/c1-6-3-9(26-2)7(4-20)14-10(6)17(23)28-15-8(5-21)13(22)11-12(16(15)27-14)19(25)29-18(11)24/h3-4,19,21-22,25H,5H2,1-2H3
    Key: FYPCEUKJORJHDL-UHFFFAOYSA-N
  • CC1=CC(=C(C2=C1C(=O)OC3=C(O2)C4=C(C(=C3CO)O)C(=O)OC4O)C=O)OC
Properties
C19H14O10
Molar mass 402.311 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Constictic acid is a chemical compound of the depsidone class. It was first isolated in 1968 from lichen of the genus Usnea . [1] It has since been found in many other lichen genera including Menegazzia , [2] Crespoa , [3] and Xanthoparmelia . [4]

Related Research Articles

<i>Xanthoparmelia</i> Genus of fungi

Xanthoparmelia is a genus of foliose lichens in the family Parmeliaceae. This genus of lichen is commonly found in the United States, South America, southern Africa, Europe, Australia, and New Zealand.

<i>Crespoa</i> Genus of fungi

Crespoa is a genus of five species of lichen in the family Parmeliaceae. Species in this genus are characterized by having an upper thallus surface that is wrinkled and reticulately ridged to coarsely foveolate.

<span class="mw-page-title-main">Constipatic acid</span> Chemical compound

Constipatic acid is a fatty acid found in several lichen species. It was isolated, identified, and named by Douglas Chester and John Alan Elix in a 1979 publication. The compound was extracted from the Australian leafy lichen called Xanthoparmelia constipata, which was collected on schist boulders west of Springton, South Australia. The related compounds protoconstipatic acid and dehydroconstipatic acid were also reported concurrently. Syo Kurokawa and Rex Filson had previously detected the compounds using thin-layer chromatography when they formally described the lichen as a new species in 1975, but had not characterised them chemically.

Xanthoparmelia isidiovagans is a species of foliose lichen in the family Parmeliaceae

Xanthoparmelia subverrucigera is a species of saxicolous (rock-dwelling), foliose lichen in the family Parmeliaceae. Found in Spain and Zimbabwe, it was formally described as a new species in 2005 by lichenologists Oscar Blanco, Ana Crespo, and John Elix. The type specimen was collected by the authors in Embid de la Ribera at an altitude of 510 m (1,670 ft); here, the lichen was found growing on siliceous rocks. It has also been collected from Rhodes Matopos National Park in Zimbabwe. The specific epithet subverrucigera alludes to its resemblance with X. verrucigera.

Xanthoparmelia bainskloofensis is a species of saxicolous (rock-dwelling), foliose lichen in the family Parmeliaceae. It was formally described as a new species in 2002 by lichenologists John Elix and Thomas Hawkes Nash III. The type specimen was collected by Nash from Bainskloof Pass at an altitude of 600 m (2,000 ft), where it was found growing on acidic rock. The species epithet refers to the type locality, the only place the lichen is known to occur. It contains usnic acid as a major lichen product, and minor amounts of echinocarpic acid, conechinocarpic acid, and hypothamnolic acid.

Xanthoparmelia boyeri is a species of foliose lichen in the family Parmeliaceae. Found in Kenya, it was formally described as a new species in 2002 by Australian lichenologist John Elix. The type specimen was collected from the Lewis Glacier on Mount Kenya, where it was found growing on volcanic rock. The species epithet refers to M. Boyer, one of the collectors of the type. The lichen contains salazinic acid as a major lichen product, minor amounts of usnic acid and norstictic acid, and trace amounts of consalazinic acid.

Xanthoparmelia kleinswartbergensis is a species of saxicolous (rock-dwelling), foliose lichen in the family Parmeliaceae. Found in South Africa, it was formally described as a new species in 2002 by Australian lichenologist John Elix. The type specimen was collected from Klein Swartberg, where it was found growing on large boulders in a gorge. It contains protocetraric acid as a major lichen product, minor amounts of usnic acid and anhydrofusarubin lactol, and trace amounts of anhydrofusarubin lactol methyl ketal. The species epithet refers to the type locality, the only place the lichen is known to occur.

Xanthoparmelia lobuliferella is a species of saxicolous (rock-dwelling), foliose lichen in the family Parmeliaceae. Found in South Africa, it was formally described as a new species in 2002 by Australian lichenologist John Elix. The type specimen was collected from the Jonaskop mountain at an altitude of 1,600 m (5,200 ft); there it was found growing on south-facing rocks. It contains several lichen products: major amounts of usnic acid and stictic acid, and minor amounts of constictic acid, norstictic acid, cryptostictic acid, lobaric acid, stenosporonic acid, lichesterinic acid, and protolichesterinic acid. The species epithet refers to its resemblance to Xanthoparmelia lobulifera.

Xanthoparmelia malawiensis is a species of saxicolous (rock-dwelling), foliose lichen in the family Parmeliaceae. Found in Malawi, it was formally described as a new species in 2002 by Australian lichenologist John Elix. The type specimen was collected in Nyika National Park at an altitude of 2,300 m (7,500 ft), where it was found growing on granite rocks. It is only known from the type locality. It contains usnic acid and stictic acid as major lichen products, and minor amounts of constictic acid, norstictic acid, cryptostictic acid, and lusitanic acid.

Xanthoparmelia micromaculata is a species of saxicolous (rock-dwelling), lichen in the family Parmeliaceae. Found in South Africa, it was formally described as a new species in 2002 by Australian lichenologist John Elix. The type specimen was collected from the summit of Waboomsberg mountain at an altitude of 1,220 m (4,000 ft). It is only known from the type locality. The lichen has a pale yellow-green, somewhat crustose thallus, reaching a diameter of up to 1 cm (0.4 in) wide. It contains several lichen products: stictic acid as a major metabolite, minor amounts of usnic acid, constictic acid, and hypostictic acid, and minor or trace amounts of norstictic acid, hyposalazinic acid, and cryptostictic acid. The species epithet refers to the prominent maculae on the thallus surface.

Xanthoparmelia waboomsbergensis is a species of foliose lichen in the family Parmeliaceae. It was formally described as a new species in 2002 by Australian lichenologist John Elix. The type specimen was collected from the summit of Waboomsberg mountain at an altitude of 1,220 m (4,000 ft). The species epithet refers to the type locality, the only place the lichen is known to occur.

Xanthoparmelia perezdepazii is a species of saxicolous (rock-dwelling), foliose lichen in the family Parmeliaceae. It is found in the Canary Islands.

Chrysothrix occidentalis is a species of saxicolous (rock-dwelling) dust lichen in the family Teloschistaceae. This yellow lichen occurs in Western Australia in open Eucalyptus forests.

<span class="mw-page-title-main">Connorstictic acid</span> Chemical compound found in some lichens

Connorstictic acid is an organic compound in the structural class of chemicals known as depsidones. It occurs as a secondary metabolite in many lichen species in several genera.

Xanthoparmelia cranfieldii is a species of foliose lichen in the family Parmeliaceae, first described by John Elix in 2003. It is known only from its type locality in Western Australia.

Xanthoparmelia elevata is a species of foliose lichen in the family Parmeliaceae, described by John Alan Elix in 2003. It is found exclusively in Western Australia, growing on granite outcrops in the region's southwest.

Xanthoparmelia kimberleyensis is a species of foliose lichen in the family Parmeliaceae, described by John Alan Elix in 2003. It is endemic to the Kimberley region of Western Australia.

Xanthoparmelia monadnockensis is a species of foliose lichen in the family Parmeliaceae, described by John Elix in 2003. It is native to Western Australia, particularly found in the Monadnocks Nature Reserve near Jarrahdale.

Xanthoparmelia nanoides is a species of saxicolous (rock-dwelling), foliose lichen in the family Parmeliaceae, described by John Elix in 2003. This species is endemic to Western Australia and known only from its type locality near Albany.

References

  1. Yosioka, Itiro; Morita, Yutaka; Ebihara, Kikuko (1970). "The Structure of Constictic Acid". Chemical and Pharmaceutical Bulletin. 18 (11): 2364–2366. doi: 10.1248/cpb.18.2364 .
  2. McCarthy, P.M.; Elix, John A. (2018). "New species and records of lichens from the Cook Islands" (PDF). Australian Lichenology. 82: 1.
  3. Hawksworth, David L. (2011). "Parmotrema subgen. Crespoa subgen. nov. for the Canoparmelia crozalsiana clade". Lichenologist. 43 (6): 647–648. doi:10.1017/S0024282911000399. S2CID   86356671.
  4. Blanco, Oscar; Crespo, Ana; Elix, John A. (2005). "Two new species of Xanthoparmelia (Ascomycota: Parmeliaceae) from Spain". Lichenologist. 37 (2): 97–100. doi:10.1017/S0024282905014829. S2CID   86778304.