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An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ACID, for "anode current into device". The direction of conventional current in a circuit is opposite to the direction of electron flow, so electrons flow out the anode of a galvanic cell, into an outside or external circuit connected to the cell. For example, the end of a household battery marked with a "-" (minus) is the anode.
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outcome of a particular chemical change, or vice versa. These reactions involve electrons moving via an electronically-conducting phase between electrodes separated by an ionically conducting and electronically insulating electrolyte.
Galvanization or galvanizing is the process of applying a protective zinc coating to steel or iron, to prevent rusting. The most common method is hot-dip galvanizing, in which the parts are coated by submerging them in a bath of hot, molten zinc.
Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO(OH), Fe(OH)3), and is typically associated with the corrosion of refined iron.
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be coated acts as the cathode of an electrolytic cell; the electrolyte is a solution of a salt of the metal to be coated; and the anode is usually either a block of that metal, or of some inert conductive material. The current is provided by an external power supply.
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.
A galvanic anode, or sacrificial anode, is the main component of a galvanic cathodic protection system used to protect buried or submerged metal structures from corrosion.
Cathodic protection is a technique used to control the corrosion of a metal surface by making it the cathode of an electrochemical cell. A simple method of protection connects the metal to be protected to a more easily corroded "sacrificial metal" to act as the anode. The sacrificial metal then corrodes instead of the protected metal. For structures such as long pipelines, where passive galvanic cathodic protection is not adequate, an external DC electrical power source is used to provide sufficient current.
Electrophoretic deposition (EPD), is a term for a broad range of industrial processes which includes electrocoating, cathodic electrodeposition, anodic electrodeposition, and electrophoretic coating, or electrophoretic painting. A characteristic feature of this process is that colloidal particles suspended in a liquid medium migrate under the influence of an electric field (electrophoresis) and are deposited onto an electrode. All colloidal particles that can be used to form stable suspensions and that can carry a charge can be used in electrophoretic deposition. This includes materials such as polymers, pigments, dyes, ceramics and metals.
Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic while an unknown but potentially vast area becomes cathodic, leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions.
In chemistry, a corrosion inhibitor or anti-corrosive is a chemical compound that, when added to a liquid or gas, decreases the corrosion rate of a material, typically a metal or an alloy, that comes into contact with the fluid. The effectiveness of a corrosion inhibitor depends on fluid composition, quantity of water, and flow regime. Corrosion inhibitors are common in industry, and also found in over-the-counter products, typically in spray form in combination with a lubricant and sometimes a penetrating oil. They may be added to water to prevent leaching of lead or copper from pipes.
A ballast tank is a compartment within a boat, ship or other floating structure that holds water, which is used as ballast to provide hydrostatic stability for a vessel, to reduce or control buoyancy, as in a submarine, to correct trim or list, to provide a more even load distribution along the hull to reduce structural hogging or sagging stresses, or to increase draft, as in a semi-submersible vessel or platform, or a SWATH, to improve seakeeping. Using water in a tank provides easier weight adjustment than the stone or iron ballast used in older vessels, and makes it easy for the crew to reduce a vessel's draft when it enters shallower water, by temporarily pumping out ballast. Airships use ballast tanks mainly to control buoyancy and correct trim.
Rustproofing is the prevention or delay of rusting of iron and steel objects, or the permanent protection against corrosion. Typically, the protection is achieved by a process of surface finishing or treatment. Depending on mechanical wear or environmental conditions, the degradation may not be stopped completely, unless the process is periodically repeated. The term is particularly used in the automobile industry.
Corrosion engineering is an engineering specialty that applies scientific, technical, engineering skills, and knowledge of natural laws and physical resources to design and implement materials, structures, devices, systems, and procedures to manage corrosion. From a holistic perspective, corrosion is the phenomenon of metals returning to the state they are found in nature. The driving force that causes metals to corrode is a consequence of their temporary existence in metallic form. To produce metals starting from naturally occurring minerals and ores, it is necessary to provide a certain amount of energy, e.g. Iron ore in a blast furnace. It is therefore thermodynamically inevitable that these metals when exposed to various environments would revert to their state found in nature. Corrosion and corrosion engineering thus involves a study of chemical kinetics, thermodynamics, electrochemistry and materials science.
Oil tankers generally have from 8 to 12 tanks. Each tank is split into two or three independent compartments by fore-and-aft bulkheads. The tanks are numbered with tank one being the forwardmost. Individual compartments are referred to by the tank number and the athwartships position, such as "one port", "three starboard", or "six center."
Anodic protection (AP) otherwise referred to as Anodic Control is a technique to control the corrosion of a metal surface by making it the anode of an electrochemical cell and controlling the electrode potential in a zone where the metal is passive.
Bipolar electrochemistry is a phenomenon in electrochemistry based on the polarization of conducting objects in electric fields. Indeed, this polarization generates a potential difference between the two extremities of the substrate that is equal to the electric field value multiplied by the size of the object. If this potential difference is important enough, then redox reactions can be generated at the extremities of the object, oxidations will occur at one extremity coupled simultaneously to reductions at the other extremity. In a simple experimental setup consisting of a platinum wire in a weighing boat containing a pH indicator solution, a 30 V voltage across two electrodes will cause water reduction at one end of the wire and a pH increase and water oxidation at the anodic end and a pH decrease. The poles of the bipolar electrode also align themselves with the applied electric field.
A sacrificial metal is a metal used as a sacrificial anode in cathodic protection that corrodes to prevent a primary metal from corrosion or rusting. It may also be used for galvanization.
DCVG is a survey technique used for assessing the effectiveness of corrosion protection on buried steel structures. In particular, oil and natural gas pipelines are routinely monitored using this technique to help locate coating faults and highlight deficiencies in their cathodic protection (CP) strategies.
Galvanic corrosion is an electrochemical process in which one metal corrodes preferentially when it is in electrical contact with another, in the presence of an electrolyte. A similar galvanic reaction is exploited in primary cells to generate a useful electrical voltage to power portable devices. This phenomenon is named after Italian physician Luigi Galvani (1737-1798).
References
- ↑ "Ballast Space Protection Is Key to Ship's Lifespan". The Motor Ship. October 1993.
- ↑ "A Guide To Ballast Tanks On Ships". Marine Insight. 2021-05-16. Retrieved 2022-03-11.
- 1 2 Anderson, Colin. "Protection of Ships Against Corrosion" (PDF). Protection of Ships Lecture Series. Newcastle University (UK). Archived from the original (PDF) on 1 February 2006. Retrieved 12 December 2012.
- ↑ "Corrosion Protection Systems for Ballast Tanks and Void Spaces". Amtec Consultants (UK). Archived from the original on 6 February 2007. Retrieved 12 December 2012.
- 1 2 "About Corrosion and Ballast Water Treatment Systems" (PDF). OceanSaver Ballast and Corrosion Control. Retrieved 12 December 2012.
- ↑ "Ballast Tank Protection – Black Magic or Black Hole?". Amtec Consultants. Archived from the original on 17 October 2010. Retrieved 12 December 2012.
- ↑ Madkour, Professor Dr Loutfy H. INDUSTRIAL CORROSION AND CORROSION CONTROL TECHNOLOGY. pp. 289–329.
The Original Ballast Tank Rust Inhibitor "Float Coat" (Military Specification: MIL-R-21006) - Rust & Corrosion Inhibitor