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Rayleigh scattering, named after the 19th-century British physicist Lord Rayleigh, is the predominantly elastic scattering of light, or other electromagnetic radiation, by particles with a size much smaller than the wavelength of the radiation. For light frequencies well below the resonance frequency of the scattering medium, the amount of scattering is inversely proportional to the fourth power of the wavelength, e.g., a blue color is scattered much more than a red color as light propagates through air.
Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum.
A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The radiation emitted by a black body in thermal equilibrium with its environment is called black-body radiation. The name "black body" is given because it absorbs all colors of light. In contrast, a white body is one with a "rough surface that reflects all incident rays completely and uniformly in all directions."
Atomic, molecular, and optical physics (AMO) is the study of matter–matter and light–matter interactions, at the scale of one or a few atoms and energy scales around several electron volts. The three areas are closely interrelated. AMO theory includes classical, semi-classical and quantum treatments. Typically, the theory and applications of emission, absorption, scattering of electromagnetic radiation (light) from excited atoms and molecules, analysis of spectroscopy, generation of lasers and masers, and the optical properties of matter in general, fall into these categories.
A femtosecond is a unit of time in the International System of Units (SI) equal to 10−15 or 1⁄1 000 000 000 000 000 of a second; that is, one quadrillionth, or one millionth of one billionth, of a second. For context, a femtosecond is to a second as a second is to about 31.71 million years; a ray of light travels approximately 0.3 μm (micrometers) in 1 femtosecond, a distance comparable to the diameter of a virus. The first to make femtosecond measurements was the Egyptian Nobel Laureate Ahmed Zewail, for which he was awarded the Nobel Prize in Chemistry in 1999. Professor Zewail used lasers to measure the movement of particles at the femtosecond scale, thereby allowing chemical reactions to be observed for the first time.
Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of reflected radiation from the angle predicted by the law of reflection. Reflections of radiation that undergo scattering are often called diffuse reflections and unscattered reflections are called specular (mirror-like) reflections. Originally, the term was confined to light scattering. As more "ray"-like phenomena were discovered, the idea of scattering was extended to them, so that William Herschel could refer to the scattering of "heat rays" in 1800. John Tyndall, a pioneer in light scattering research, noted the connection between light scattering and acoustic scattering in the 1870s. Near the end of the 19th century, the scattering of cathode rays and X-rays was observed and discussed. With the discovery of subatomic particles and the development of quantum theory in the 20th century, the sense of the term became broader as it was recognized that the same mathematical frameworks used in light scattering could be applied to many other phenomena.
Diffuse sky radiation is solar radiation reaching the Earth's surface after having been scattered from the direct solar beam by molecules or particulates in the atmosphere. It is also called sky radiation, the determinative process for changing the colors of the sky. Approximately 23% of direct incident radiation of total sunlight is removed from the direct solar beam by scattering into the atmosphere; of this amount about two-thirds ultimately reaches the earth as photon diffused skylight radiation.
Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.
Black-body radiation is the thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body. It has a specific, continuous spectrum of wavelengths, inversely related to intensity, that depend only on the body's temperature, which is assumed, for the sake of calculations and theory, to be uniform and constant.
The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that most commonly includes both visible radiation (light) and infrared radiation, which is not visible to human eyes. A portion of the thermal radiation from very hot objects is easily visible to the eye.
Radiative transfer is the physical phenomenon of energy transfer in the form of electromagnetic radiation. The propagation of radiation through a medium is affected by absorption, emission, and scattering processes. The equation of radiative transfer describes these interactions mathematically. Equations of radiative transfer have application in a wide variety of subjects including optics, astrophysics, atmospheric science, and remote sensing. Analytic solutions to the radiative transfer equation (RTE) exist for simple cases but for more realistic media, with complex multiple scattering effects, numerical methods are required. The present article is largely focused on the condition of radiative equilibrium.
An atmospheric radiative transfer model, code, or simulator calculates radiative transfer of electromagnetic radiation through a planetary atmosphere.
Light scattering by particles is the process by which small particles scatter light causing optical phenomena such as the blue color of the sky, and halos.
In spectroscopy, spectral flux density is the quantity that describes the rate at which energy is transferred by electromagnetic radiation through a real or virtual surface, per unit surface area and per unit wavelength. It is a radiometric rather than a photometric measure. In SI units it is measured in W m−3, although it can be more practical to use W m−2 nm−1 or W m−2 μm−1, and respectively by W·m−2·Hz−1, Jansky or solar flux units. The terms irradiance, radiant exitance, radiant emittance, and radiosity are closely related to spectral flux density.
In models of radiative transfer, the two-stream approximation is a discrete ordinate approximation in which radiation propagating along only two discrete directions is considered. In other words, the two-stream approximation assumes the intensity is constant with angle in the upward hemisphere, with a different constant value in the downward hemisphere. It was first used by Arthur Schuster in 1905. The two ordinates are chosen such that the model captures the essence of radiative transport in light scattering atmospheres. A practical benefit of the approach is that it reduces the computational cost of integrating the radiative transfer equation. The two-stream approximation is commonly used in parameterizations of radiative transport in global circulation models and in weather forecasting models, such as the WRF. There are a large number of applications of the two-stream approximation, including variants such as the Kubelka-Munk approximation. It is the simplest approximation that can be used to explain common observations inexplicable by single-scattering arguments, such as the brightness and color of the clear sky, the brightness of clouds, the whiteness of a glass of milk, and the darkening of sand upon wetting. The two-stream approximation comes in many variants, such as the Quadrature, and Hemispheric constant models. Mathematical descriptions of the two-stream approximation are given in several books. The two-stream approximation is separate from the Eddington approximation, which instead assumes that the intensity is linear in the cosine of the incidence angle, with no discontinuity at the horizon.
Codes for electromagnetic scattering by spheres - this article list codes for electromagnetic scattering by a homogeneous sphere, layered sphere, and cluster of spheres.
Codes for electromagnetic scattering by cylinders – this article list codes for electromagnetic scattering by a cylinder.
In radiometry, spectral radiance or specific intensity is the radiance of a surface per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. The SI unit of spectral radiance in frequency is the watt per steradian per square metre per hertz and that of spectral radiance in wavelength is the watt per steradian per square metre per metre —commonly the watt per steradian per square metre per nanometre. The microflick is also used to measure spectral radiance in some fields.
Atmospheric optics is "the study of the optical characteristics of the atmosphere or products of atmospheric processes .... [including] temporal and spatial resolutions beyond those discernible with the naked eye". Meteorological optics is "that part of atmospheric optics concerned with the study of patterns observable with the naked eye". Nevertheless, the two terms are sometimes used interchangeably.
References
- ↑ Bohren, Craig (2006). Fundamentals of Atmospheric Radiation: an Introduction with 400 Problems. Chichester: John Wiley & Sons. ISBN 978-3-527-40503-9.
- ↑ Bohren, Craig (1998). Absorption and Scattering of Light by Small Particles. New York: Wiley. ISBN 978-0-471-29340-8.
- ↑ Bohren, Craig (1998). Atmospheric Thermodynamics. Oxford Oxfordshire: Oxford University Press. ISBN 978-0-19-509904-1.
- ↑ Bohren, Craig (2001). Clouds in a Glass of Beer. New York: Dover Publications. ISBN 978-0-486-41738-7.
- ↑ Bohren, Craig (1991). What Light through Yonder Window Breaks? . London: J. Wiley. ISBN 978-0-471-52915-6.
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