Related Research Articles
In electromagnetism, a dielectric is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the material as they do in an electrical conductor, because they have no loosely bound, or free, electrons that may drift through the material, but instead they shift, only slightly, from their average equilibrium positions, causing dielectric polarisation. Because of dielectric polarisation, positive charges are displaced in the direction of the field and negative charges shift in the direction opposite to the field. This creates an internal electric field that reduces the overall field within the dielectric itself. If a dielectric is composed of weakly bonded molecules, those molecules not only become polarised, but also reorient so that their symmetry axes align to the field.
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter ε (epsilon), is a measure of the electric polarizability of a dielectric. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy in the material. In electrostatics, the permittivity plays an important role in determining the capacitance of a capacitor.
Dynamic mechanical analysis is a technique used to study and characterize materials. It is most useful for studying the viscoelastic behavior of polymers. A sinusoidal stress is applied and the strain in the material is measured, allowing one to determine the complex modulus. The temperature of the sample or the frequency of the stress are often varied, leading to variations in the complex modulus; this approach can be used to locate the glass transition temperature of the material, as well as to identify transitions corresponding to other molecular motions.
In physics, the electric displacement field or electric induction is a vector field that appears in Maxwell's equations. It accounts for the electromagnetic effects of polarization and that of an electric field, combining the two in an auxiliary field. It plays a major role in topics such as the capacitance of a material, as well the response of dielectrics to electric field, and how shapes can change due to electric fields in piezoelectricity or flexoelectricity as well as the creation of voltages and charge transfer due to elastic strains.
Dielectrophoresis (DEP) is a phenomenon in which a force is exerted on a dielectric particle when it is subjected to a non-uniform electric field. This force does not require the particle to be charged. All particles exhibit dielectrophoretic activity in the presence of electric fields. However, the strength of the force depends strongly on the medium and particles' electrical properties, on the particles' shape and size, as well as on the frequency of the electric field. Consequently, fields of a particular frequency can manipulate particles with great selectivity. This has allowed, for example, the separation of cells or the orientation and manipulation of nanoparticles and nanowires. Furthermore, a study of the change in DEP force as a function of frequency can allow the electrical properties of the particle to be elucidated.
An electroactive polymer (EAP) is a polymer that exhibits a change in size or shape when stimulated by an electric field. The most common applications of this type of material are in actuators and sensors. A typical characteristic property of an EAP is that they will undergo a large amount of deformation while sustaining large forces.
Dielectric spectroscopy measures the dielectric properties of a medium as a function of frequency. It is based on the interaction of an external field with the electric dipole moment of the sample, often expressed by permittivity.
High resolution electron energy loss spectroscopy (HREELS) is a tool used in surface science. The inelastic scattering of electrons from surfaces is utilized to study electronic excitations or vibrational modes of the surface of a material or of molecules adsorbed to a surface. In contrast to other electron energy loss spectroscopies (EELS), HREELS deals with small energy losses in the range of 10−3 eV to 1 eV. It plays an important role in the investigation of surface structure, catalysis, dispersion of surface phonons and the monitoring of epitaxial growth.
A surface charge is an electric charge present on a two-dimensional surface. These electric charges are constrained on this 2-D surface, and surface charge density, measured in coulombs per square meter (C•m−2), is used to describe the charge distribution on the surface. The electric potential is continuous across a surface charge and the electric field is discontinuous, but not infinite; this is unless the surface charge consists of a dipole layer. In comparison, the potential and electric field both diverge at any point charge or linear charge.
A capacitor is an electronic device that stores electrical energy in an electric field by accumulating electric charges on two closely spaced surfaces that are insulated from each other. It is a passive electronic component with two terminals.
Characterization, when used in materials science, refers to the broad and general process by which a material's structure and properties are probed and measured. It is a fundamental process in the field of materials science, without which no scientific understanding of engineering materials could be ascertained. The scope of the term often differs; some definitions limit the term's use to techniques which study the microscopic structure and properties of materials, while others use the term to refer to any materials analysis process including macroscopic techniques such as mechanical testing, thermal analysis and density calculation. The scale of the structures observed in materials characterization ranges from angstroms, such as in the imaging of individual atoms and chemical bonds, up to centimeters, such as in the imaging of coarse grain structures in metals.
In electrical engineering, dielectric loss quantifies a dielectric material's inherent dissipation of electromagnetic energy. It can be parameterized in terms of either the loss angleδ or the corresponding loss tangenttan(δ). Both refer to the phasor in the complex plane whose real and imaginary parts are the resistive (lossy) component of an electromagnetic field and its reactive (lossless) counterpart.
Dielectric elastomers (DEs) are smart material systems that produce large strains and are promising for Soft robotics, Artificial muscle, etc. They belong to the group of electroactive polymers (EAP). DE actuators (DEA) transform electric energy into mechanical work and vice versa. Thus, they can be used as both actuators, sensors, and energy-harvesting devices. They have high elastic energy density and fast response due to being lightweight, highly stretchable, and operating under the electrostatic principle. They have been investigated since the late 1990s. Many prototype applications exist. Every year, conferences are held in the US and Europe.
Sedimentation potential occurs when dispersed particles move under the influence of either gravity or centrifugation or electricity in a medium. This motion disrupts the equilibrium symmetry of the particle's double layer. While the particle moves, the ions in the electric double layer lag behind due to the liquid flow. This causes a slight displacement between the surface charge and the electric charge of the diffuse layer. As a result, the moving particle creates a dipole moment. The sum of all of the dipoles generates an electric field which is called sedimentation potential. It can be measured with an open electrical circuit, which is also called sedimentation current.
Polymer characterization is the analytical branch of polymer science.
A biotransducer is the recognition-transduction component of a biosensor system. It consists of two intimately coupled parts; a bio-recognition layer and a physicochemical transducer, which acting together converts a biochemical signal to an electronic or optical signal. The bio-recognition layer typically contains an enzyme or another binding protein such as antibody. However, oligonucleotide sequences, sub-cellular fragments such as organelles and receptor carrying fragments, single whole cells, small numbers of cells on synthetic scaffolds, or thin slices of animal or plant tissues, may also comprise the bio-recognition layer. It gives the biosensor selectivity and specificity. The physicochemical transducer is typically in intimate and controlled contact with the recognition layer. As a result of the presence and biochemical action of the analyte, a physico-chemical change is produced within the biorecognition layer that is measured by the physicochemical transducer producing a signal that is proportionate to the concentration of the analyte. The physicochemical transducer may be electrochemical, optical, electronic, gravimetric, pyroelectric or piezoelectric. Based on the type of biotransducer, biosensors can be classified as shown to the right.
Double-layer capacitance is the important characteristic of the electrical double layer which appears at the interface between a surface and a fluid. At this boundary two layers of electric charge with opposing polarity form, one at the surface of the electrode, and one in the electrolyte. These two layers, electrons on the electrode and ions in the electrolyte, are typically separated by a single layer of solvent molecules that adhere to the surface of the electrode and act like a dielectric in a conventional capacitor. The amount of charge stored in double-layer capacitor depends on the applied voltage.
In electrochemistry, faradaic impedance is the resistance and capacitance acting jointly at the surface of an electrode of an electrochemical cell. The cell may be operating as either a galvanic cell generating an electric current or inversely as an electrolytic cell using an electric current to drive a chemical reaction. In the simplest nontrivial case faradaic impedance is modeled as a single resistor and single capacitor connected in parallel, as opposed say to in series or as a transmission line with multiple resistors and capacitors.
Thermally stimulated depolarization current (TSDC) is a scientific technique used to measure dielectric properties of materials. It can be used to measure the thermally stimulated depolarization of molecules within a material. One method of doing so is to place the material between two electrodes, cool the material in the presence of an external electric field, remove the field once a desired temperature has been reached, and measure the current between the electrodes as the material warms. The external electric field must be applied at a sufficiently high temperature to allow the molecular dipoles time to align with the field. Because the dielectric relaxation time increases exponentially on cooling, the polarization caused by their alignment with the field gets "frozen-in". So when the field is removed and the material begins to warm the dipoles begin to "thaw" whereby losing their net alignment and thus the material become depolarized. This depolarization can be measured if the material is sandwiched between two ohmic electrodes and the current is measured on warming. As the material depolarizes, charges are pulled to (or pushed away from) the electrodes which causes a current through the measuring device.
Radio-frequency welding, also known as dielectric welding and high-frequency welding, is a plastic welding process that utilizes high-frequency electric fields to induce heating and melting of thermoplastic base materials. The electric field is applied by a pair of electrodes after the parts being joined are clamped together. The clamping force is maintained until the joint solidifies. Advantages of this process are fast cycle times, automation, repeatability, and good weld appearance. Only plastics which have dipoles can be heated using radio waves and therefore not all plastics are able to be welded using this process. Also, this process is not well suited for thick or overly complex joints. The most common use of this process is lap joints or seals on thin plastic sheets or parts.
References
- ↑ Haines, Peter J. (2002). Thermal Analysis and Calorimetry. Royal Society of Chemistry. ISBN 9780854046102.
- 1 2 Brown, M. E. (2001-12-31). Introduction to Thermal Analysis: Techniques and Applications. Springer. ISBN 9781402004728.
 | This article about materials science is a stub. You can help Wikipedia by expanding it. |