Disclination

Last updated

In crystallography, a disclination is a line defect in which there is compensation of an angular gap, equivalent to a violation of rotational symmetry. [1] In analogy with dislocations in crystals, the term, disinclination, for liquid crystals first used by Frederick Charles Frank and since then has been modified to its current usage, disclination. [2] It is a defect in the orientation of director whereas a dislocation is a defect in positional order. [3]

Contents

Example in two dimensions

Formation of two disclinations (right) out of a dislocation (left) on an otherwise hexagonal background Disklination Dissoziation.svg
Formation of two disclinations (right) out of a dislocation (left) on an otherwise hexagonal background

In 2D, disclinations and dislocations are point defects instead of line defects as in 3D. They are topological defects and play a central role in melting of 2D crystals within the KTHNY theory, based on two Kosterlitz–Thouless transitions.

Equally sized discs (spheres, particles, atoms) form a hexagonal crystal as dense packing in two dimensions. In such a crystal, each particle has six nearest neighbors. Local strain and twist (for example induced by thermal motion) can cause configurations where discs (or particles) have a coordination number different of six, typically five or seven. Disclinations are topological defects, therefore (starting from a hexagonal array) they can only be created in pairs. Ignoring surface/border effects, this implies that there are always as many 5-folded as 7-folded disclinations present in a perfectly plane 2D crystal. A "bound" pair of 5-7-folded disclinations is a dislocation. If myriad dislocations are thermally dissociated into isolated disclinations, then the monolayer of particles becomes an isotropic fluid in two dimensions. A 2D crystal is free of disclinations.

To transform a section of a hexagonal array into a 5-folded disclination (colored green in the figure), a triangular wedge of hexagonal elements (blue triangle) has to be removed; to create a 7-folded disclination (orange), an identical wedge must be inserted. The figure illustrates how disclinations destroy orientational order, while dislocations only destroy translational order in the far field (portions of the crystal far from the center of the disclination).

Disclinations are topological defects because they cannot be created locally by an affine transformation without cutting the hexagonal array outwards to infinity (or the border of a finite crystal). The undisturbed hexagonal crystal has a  60° symmetry, but when a wedge is removed to create a 5-folded disclination, the crystal symmetry is stretched to  72° – for a 7-folded disclination, it is compressed to about  51,4°. Thus, disclinations store elastic energy by disturbing the director field.

See also

Related Research Articles

<span class="mw-page-title-main">Crystallographic defect</span> Disruption of the periodicity of a crystal lattice

A crystallographic defect is an interruption of the regular patterns of arrangement of atoms or molecules in crystalline solids. The positions and orientations of particles, which are repeating at fixed distances determined by the unit cell parameters in crystals, exhibit a periodic crystal structure, but this is usually imperfect. Several types of defects are often characterized: point defects, line defects, planar defects, bulk defects. Topological homotopy establishes a mathematical method of characterization.

<span class="mw-page-title-main">Phase transition</span> Physical process of transition between basic states of matter

In chemistry, thermodynamics, and other related fields, a phase transition is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point.

<span class="mw-page-title-main">Crystal structure</span> Ordered arrangement of atoms, ions, or molecules in a crystalline material

In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter.

Topological defects or solitons are irregularities or disruptions that occur within continuous fields or ordered states of matter. These defects, which can take various forms such as points, lines, or surfaces, are characterized by their stability and the fact that they cannot be 'smoothed out' or removed through continuous transformations of the field or material. They play a significant role in various areas of physics, including condensed matter physics, cosmology, and quantum field theory, and can have profound effects on the properties and behavior of the systems in which they occur.

<span class="mw-page-title-main">Dislocation</span> Linear crystallographic defect or irregularity

In materials science, a dislocation or Taylor's dislocation is a linear crystallographic defect or irregularity within a crystal structure that contains an abrupt change in the arrangement of atoms. The movement of dislocations allow atoms to slide over each other at low stress levels and is known as glide or slip. The crystalline order is restored on either side of a glide dislocation but the atoms on one side have moved by one position. The crystalline order is not fully restored with a partial dislocation. A dislocation defines the boundary between slipped and unslipped regions of material and as a result, must either form a complete loop, intersect other dislocations or defects, or extend to the edges of the crystal. A dislocation can be characterised by the distance and direction of movement it causes to atoms which is defined by the Burgers vector. Plastic deformation of a material occurs by the creation and movement of many dislocations. The number and arrangement of dislocations influences many of the properties of materials.

In physics, the terms order and disorder designate the presence or absence of some symmetry or correlation in a many-particle system.

The Berezinskii–Kosterlitz–Thouless (BKT) transition is a phase transition of the two-dimensional (2-D) XY model in statistical physics. It is a transition from bound vortex-antivortex pairs at low temperatures to unpaired vortices and anti-vortices at some critical temperature. The transition is named for condensed matter physicists Vadim Berezinskii, John M. Kosterlitz and David J. Thouless. BKT transitions can be found in several 2-D systems in condensed matter physics that are approximated by the XY model, including Josephson junction arrays and thin disordered superconducting granular films. More recently, the term has been applied by the 2-D superconductor insulator transition community to the pinning of Cooper pairs in the insulating regime, due to similarities with the original vortex BKT transition.

<span class="mw-page-title-main">Crystal twinning</span> Two separate crystals sharing some of the same crystal lattice points in a symmetrical manner

Crystal twinning occurs when two or more adjacent crystals of the same mineral are oriented so that they share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals that are tightly bonded to each other. The surface along which the lattice points are shared in twinned crystals is called a composition surface or twin plane.

The λ (lambda) universality class is a group in condensed matter physics. It regroups several systems possessing strong analogies, namely, superfluids, superconductors and smectics. All these systems are expected to belong to the same universality class for the thermodynamic critical properties of the phase transition. While these systems are quite different at the first glance, they all are described by similar formalisms and their typical phase diagrams are identical.

<span class="mw-page-title-main">Topological order</span> Type of order at absolute zero

In physics, topological order is a kind of order in the zero-temperature phase of matter. Macroscopically, topological order is defined and described by robust ground state degeneracy and quantized non-Abelian geometric phases of degenerate ground states. Microscopically, topological orders correspond to patterns of long-range quantum entanglement. States with different topological orders cannot change into each other without a phase transition.

The superconductor–insulator transition is an example of a quantum phase transition, whereupon tuning some parameter in the Hamiltonian, a dramatic change in the behavior of the electrons occurs. The nature of how this transition occurs is disputed, and many studies seek to understand how the order parameter, , changes. Here is the amplitude of the order parameter, and is the phase. Most theories involve either the destruction of the amplitude of the order parameter - by a reduction in the density of states at the Fermi surface, or by destruction of the phase coherence; which results from the proliferation of vortices.

<span class="mw-page-title-main">David J. Thouless</span> British physicist (1934–2019)

David James Thouless was a British condensed-matter physicist. He was the winner of the 1990 Wolf Prize and a laureate of the 2016 Nobel Prize for physics along with F. Duncan M. Haldane and J. Michael Kosterlitz for theoretical discoveries of topological phase transitions and topological phases of matter.

The hexatic phase is a state of matter that is between the solid and the isotropic liquid phases in two dimensional systems of particles. It is characterized by two order parameters: a short-range positional and a quasi-long-range orientational (sixfold) order. More generally, a hexatic is any phase that contains sixfold orientational order, in analogy with the nematic phase.

<span class="mw-page-title-main">Xiao-Gang Wen</span> Chinese-American physicist

Xiao-Gang Wen is a Chinese-American physicist. He is a Cecil and Ida Green Professor of Physics at the Massachusetts Institute of Technology and Distinguished Visiting Research Chair at the Perimeter Institute for Theoretical Physics. His expertise is in condensed matter theory in strongly correlated electronic systems. In Oct. 2016, he was awarded the Oliver E. Buckley Condensed Matter Prize.

<span class="mw-page-title-main">David Robert Nelson</span> American physicist (born 1951)

David R. Nelson is an American physicist, and Arthur K. Solomon Professor of Biophysics, at Harvard University.

In quantum many-body physics, topological degeneracy is a phenomenon in which the ground state of a gapped many-body Hamiltonian becomes degenerate in the limit of large system size such that the degeneracy cannot be lifted by any local perturbations.

Symmetry-protected topological (SPT) order is a kind of order in zero-temperature quantum-mechanical states of matter that have a symmetry and a finite energy gap.

The Kibble–Zurek mechanism (KZM) describes the non-equilibrium dynamics and the formation of topological defects in a system which is driven through a continuous phase transition at finite rate. It is named after Tom W. B. Kibble, who pioneered the study of domain structure formation through cosmological phase transitions in the early universe, and Wojciech H. Zurek, who related the number of defects it creates to the critical exponents of the transition and to its rate—to how quickly the critical point is traversed.

<span class="mw-page-title-main">Jorge V. José</span>

Jorge V. José is a Mexican/American physicist born in Mexico City. Currently the James H. Rudy Distinguished Professor of Physics at Indiana University. He has made seminal contributions to research in a variety of disciplines, including condensed matter physics, nonlinear dynamics, quantum chaos, biological physics, computational neuroscience and lately precision psychiatry. His pioneering work on the two-dimensional x-y model has been exceedingly influential in many areas of physics and has garnered many citations. He edited the book on the “40 Years of Berezinskii-Kosterlitz-Thouless Theory”, on two-dimensional topological phase transitions in 2013. Three years later KT were awarded the 2016 Nobel Physics Prize.

The KTHNY-theory describes the melting of crystals in two dimensions (2D). The name is derived from the initials of the surnames of John Michael Kosterlitz, David J. Thouless, Bertrand Halperin, David R. Nelson, and A. Peter Young, who developed the theory in the 1970s. It is, beside the Ising model in 2D and the XY model in 2D, one of the few theories, which can be solved analytically and which predicts a phase transition at a temperature .

References

  1. Murayama, M.; Howe, J. M.; Hidaka, H.; Takaki, S. (2002-03-29). "Atomic-Level Observation of Disclination Dipoles in Mechanically Milled, Nanocrystalline Fe". Science. 295 (5564): 2433–2435. Bibcode:2002Sci...295.2433M. doi:10.1126/science.1067430. PMID   11923534. S2CID   46024551.
  2. Chandrasekhar, S. (1977) Liquid Crystals, Cambridge University Press, p. 123, ISBN   0-521-21149-2
  3. Barón, Máximo (2001). "Definitions of basic terms relating to low-molar-mass and polymer liquid crystals (IUPAC Recommendations 2001)". Pure and Applied Chemistry. 73 (5): 845–895. doi: 10.1351/pac200173050845 . S2CID   95656853.

Further reading