Edith Marie Flanigen | |
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Born | Edith Marie Flanigen January 28, 1929 Buffalo, New York, U.S. |
Alma mater | D'Youville College Syracuse University (M.S.) |
Known for | |
Awards |
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Scientific career | |
Fields | Chemistry |
Institutions | Union Carbide, UOP |
Edith Marie Flanigen (born January 28, 1929) [1] [2] is a noted American chemist, known for her work on synthesis of emeralds, and later zeolites for molecular sieves at Union Carbide.
Edith Marie Flanigen was born January 28, 1929, in Buffalo, New York. She and her two sisters, Joan and Jane, were introduced to chemistry by their high school teacher. The three sisters all went on to study chemistry at D'Youville College. [3] Edith Flanigen graduated class president and valedictorian. [4] Joan and Edith both went on to receive master's degrees in chemistry in inorganic physical chemistry at Syracuse University in 1952. [3] [4] In 2008, Syracuse awarded her an honorary doctorate. [5]
In 1952, Edith Flanigen joined the Union Carbide company. [6] Her job at first was the identification, purification and extraction of different silicone polymers. In 1956, she moved to the molecular sieves group. [4] In 1973, she was the first woman at Union Carbide to be named corporate research fellow, and in 1986, senior corporate research fellow. She was moved to UOP (a joint venture between Union Carbide and Allied Signal) in 1988, where she was named senior research fellow. Flanigen was promoted to UOP Fellow in 1991. Edith Flanigen retired from UOP 1994. [6] Following her career at UOP, and through at least 2004, Edith Flanigen remained active professionally, including as a consultant with UOP. [7]
In her 42-year career associated with Union Carbide, Edith Flanigen invented more than 200 different synthetic substances, [4] authored or co-authored over 36 publications, and was awarded at least 109 patents. [8]
In 1956 Flanigen began working on molecular sieves. [4] Molecular sieves are crystal compounds with molecular sized pores that can filter or separate very complex substances. Edith Flanigen is best known as the inventor of zeolite Y, a specific molecular sieve. Zeolite Y was a certain type of molecular sieve that could refine petroleum. Zeolite Y surpassed Zeolite X before it. When refining "crude oil", or petroleum, it must be separated into all of its different parts, or fractions. Gasoline is one of the many fractions that come from refining petroleum. Flanigen's zeolites are used as catalysts, or a substance that enhances chemical reactions. Zeolite Y is a catalyst that enhances the amount of gasoline fractioned from petroleum, making refining petroleum safer and more productive. [10]
In addition to her work on molecular sieves, Flanigen also co-invented a synthetic emerald, [11] which Union Carbide produced and sold for many years. The emeralds were used mainly in masers (predecessors to lasers) and were even used in jewelry for a time, in a line marketed as the "Quintessa Collection." [12]
Wilson, Stephen T.; Lok, Brent M.; Messina, Celeste A.; Cannan, Thomas R.; & Flanigen, Edith M. (1982). Aluminophosphate molecular sieves: a new class of microporous crystalline inorganic solids. 104 (4), 1146-1147.
Flanigen has been the recipient of many awards and honors. She was, for example, the first female recipient of the Perkin Medal in 1992. She was also inducted into the National Inventors Hall of Fame in 2004. [2]
In 2014, the Edith Flanigen Award was created by the Collaborative Research Centre at Humboldt University of Berlin. The award is to be given annually to an outstanding female scientist at the early stage of her career. The first award was given to Natacha Krins for her work at the University of Paris. [13]
In 2012, Flanigen was named recipient of the National Medal of Technology and Innovation. [14] On November 20, 2014, President Barack Obama presented Flanigen with the National Medal of Technology and Innovation for her contributions to science. [15]
The Lemelson–MIT Program awards several prizes yearly to inventors in the United States. The largest is the Lemelson–MIT Prize which was endowed in 1994 by Jerome H. Lemelson, funded by the Lemelson Foundation, and is administered through the School of Engineering at the Massachusetts Institute of Technology. The winner receives $500,000, making it the largest cash prize for invention in the U.S.
Zeolite is a family of several microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula Mn+
1/n(AlO
2)−
(SiO
2)
x・yH
2O where Mn+
1/n is either a metal ion or H+.
In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon–carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of large hydrocarbons into smaller, more useful alkanes and alkenes. Simply put, hydrocarbon cracking is the process of breaking long-chain hydrocarbons into short ones. This process requires high temperatures.
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A molecular sieve is a material with pores of uniform size which link the interior of the solid to its exterior. These materials embody the molecular sieve effect: "With respect to porous solids, the surface associated with pores communicating with the outside space may be called the internal surface. Because the accessibility of pores may depend on the size of the fluid molecules, the extent of the internal surface may depend on the size of the molecules comprising the fluid, and may be different for the various components of a fluid mixture." The specification for the pores is that they not only communicate from the exterior to the interior, but the pores are uniform in size. Many kinds of materials exhibit some molecular sieves, but zeolites dominate the field. Zeolites are almost always aluminosilicates, or variants where some or all of the Si or Al centers are replaced by similarly charged elements.
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