An electrochromic device (ECD) controls optical properties such as optical transmission, absorption, reflectance and/or emittance in a continual but reversible manner on application of voltage (electrochromism). This property enables an ECD to be used for applications like smart glass, electrochromic mirrors, and electrochromic display devices.
The history of electro-coloration goes back to 1704 when Diesbach discovered Prussian blue (hexacyanoferrate), which changes color from transparent to blue under oxidation of iron. In the 1930s, Kobosew and Nekrassow first noted electrochemical coloration in bulk tungsten oxide. While working at Balzers in Lichtenstein, T. Kraus provided a detailed description of the electrochemical coloration in a thin film of tungsten trioxide (WO3) on 30 July 1953. In 1969, S. K. Deb demonstrated electrochromic coloration in WO3 thin films. [1] Deb observed electrochromic color by applying an electric field on the order of 104 Vcm−1 across WO3 thin film. In fact, the real birth of the EC technology is usually attributed to S. K. Deb’s seminal paper of 1973, wherein he described the coloration mechanism in WO3. [2] The electrochromism occurs due to the electrochemical redox reactions that take place in electrochromic materials. Various types of materials and structures can be used to construct electrochromic devices, depending on the specific applications.
Electrochromic (sometimes called electrochromatic) devices are one kind of electrochromic cells. [3] The basic structure of ECD consists of two EC layers separated by an electrolytic layer. The ECD works on an external voltage, for which the conducting electrodes are used on the either side of both EC layers. Electrochromic devices can be categorized in two types depending upon the kind of electrolyte used viz. Laminated ECD are the one in which liquid gel is used while in solid electrolyte EC devices solid inorganic or organic material is used. The basic structure of electrochromic device embodies five superimposed layers on one substrate or positioned between two substrates in a laminated configuration. In this structure there are three principally different kinds of layered materials in the ECD: The EC layer and ion-storage layer conduct ions and electrons and belong to the class of mixed conductors. The electrolyte is a pure ion conductor and separates the two EC layers. The transparent conductors are pure electron conductors. Optical absorption occurs when electrons move into the EC layers from the transparent conductors along with charge balancing ions entering from the electrolyte.
In solid-state electrochromic devices, a solid inorganic or organic material is used as the electrolyte. Ta2O5 and ZrO2 are the most extensively studied inorganic solid electrolytes.
Laminated electrochromic devices contain a liquid gel which is used as the electrolyte.
Typically, ECD are of two types depending on the modes of device operation, namely the transmission mode and reflectance mode. In the transmission mode, the conducting electrodes are transparent and control the light intensity passing through them; this mode is used in smart-window applications. In the reflectance mode, one of the transparent conducting electrodes (TCE) is replaced with a reflective surface like aluminum, gold or silver, which controls the reflective light intensity; this mode is useful in rear-view mirrors of cars and EC display devices.
Windows have both direct and indirect impacts on building energy consumption. Electrochromic windows, or the application of electrochromic switchable glazes deposited on to windows, also known as smart windows, are a technology for energy efficiency used in buildings by controlling the amount of sunlight passing through. [4] The solar-optical properties of electrochromic coatings vary over a wide range in response to an applied electrical signal that can be applied via execution of laboratory processes, such as Cyclic Voltammetry (CV). Specifically, these smart windows are made of Tungsten Oxide (WO3). Tungsten Oxide is known to be a standard material used for electrochromic devices because of its wide optical window, ranging from 400-630 nm, and prolonged cyclic stability on the order of thousands of cycles. To enhance the electrochromic performance of Tungsten Oxide coatings, electro chromic coatings are prepared by introducing a small amount of dopamine (DA) into a peroxo tungstic acid (PTA) precursor sol to form tungsten complexes on the surface of nanoparticles. This processing method shows promising cyclic stability as it will last up to thirty five thousand cycles which is greater than that of regular WO3 since new ligand formation promotes plasmonic tuning in nanoparticle electrochemistry. [5] They can also produce less glare than fritted glass. [6] The efficiency of electrochromic windows is dependent on the intrinsic properties of the coating, the placement of the coating within a window system, and parameters related to the building they are used for. In addition to this, electrochromic coating efficiency is directly dependent on the growth kinetics of such thin-film layers since thinner films, and non-even coatings, have a lower optical signal compared to the thicker films with more uniformity having more control and experience a greater optical signal. [7]
These windows usually contain layers for tinting in response to increases in incoming sunlight and to protect from UV radiation. For example the glass developed by Gesimat, has a tungsten oxide layer, a polyvinyl butyral layer and a Prussian Blue layer sandwiched by two dual layers of glass and fluorine-doped glass coated with tin oxide. [8] The tungsten oxide and Prussian Blue layers form the positive and negative ends of a battery using the incoming light energy. [9] The polyvinyl butyral (PVB) forms the central layer and serves as a polymer electrolyte. This allows for the flow of ions which, in turn, generates a current.
Electrochromic mirrors use a combination of optoelectronic sensors and complex electronics that monitor both ambient light and the intensity of the light shining on the surface. As soon as glare makes contact with the surface, these mirrors automatically dim reflections of flashing light from following vehicles at night so that a driver can see them without discomfort. These mirrors, however, only dim relative to the amount of light that shines on them. [10]
Electrochromic displays can operate in one of two modes: reflecting light mode, where light or other radiation strikes a surface and is redirected, or transmitting light mode, which is transmitted through a substrate; the majority of displays operates in a reflective mode. Even though electrochromic devices are considered to be more “passive” since they do not emit light and need external illumination to function, electrochromic coatings on devices have been proposed for flat panel displays and visual-display units (VDUs). For example, an electrochromic coating was featured on an iPod in the early 2000s, and the Nanochromic screen surpassed that of the original iPod in terms of its fidelity in display quality and screen brightness. Electrochromics have been used for other display applications as well; however, the technology is still somewhat nascent and competes with Liquid-crystal displays (LCDs) and their presence in the market. Electrochromic devices do have advantages over materials synthesized to produce LCD based optoelectronics, such as consuming little to no power in producing images and the same amount of power is needed to keep present displays, and there is no restriction to the size of such a device since it is dependent on manufacturing capability and number of electrodes. But they are not regularly used because of their quick response times, 𝜏, estimated by the equation l=(Dt)0.5. For type I-electrochromics (solution-phase) species, the diffusion coefficient is on the order of 10–7 cm2/s. In comparison, for type III-electrochromic species, the diffusion coefficient is on the order of 10–12 cm2/s, which allows for a longer response time on the order of ten seconds compared to almost a millisecond when using type I devices. Such electrochromic displays, to be used commercially, need to be optimized at the materials processing and synthesis level to compete with LCDs in advanced display technologies beyond the iPod. [11]
Other applications include dynamically tinting goggles and motorcycle helmet visors, and special paper for drawing on with a stylus.
Indium tin oxide (ITO) is a ternary composition of indium, tin and oxygen in varying proportions. Depending on the oxygen content, it can be described as either a ceramic or an alloy. Indium tin oxide is typically encountered as an oxygen-saturated composition with a formulation of 74% In, 8% Sn, and 18% O by weight. Oxygen-saturated compositions are so typical that unsaturated compositions are termed oxygen-deficient ITO. It is transparent and colorless in thin layers, while in bulk form it is yellowish to gray. In the infrared region of the spectrum it acts as a metal-like mirror,
The vertical-cavity surface-emitting laser is a type of semiconductor laser diode with laser beam emission perpendicular from the top surface, contrary to conventional edge-emitting semiconductor lasers which emit from surfaces formed by cleaving the individual chip out of a wafer. VCSELs are used in various laser products, including computer mice, fiber optic communications, laser printers, Face ID, and smartglasses.
An optical coating is one or more thin layers of material deposited on an optical component such as a lens, prism or mirror, which alters the way in which the optic reflects and transmits light. These coatings have become a key technology in the field of optics. One type of optical coating is an anti-reflective coating, which reduces unwanted reflections from surfaces, and is commonly used on spectacle and camera lenses. Another type is the high-reflector coating, which can be used to produce mirrors that reflect greater than 99.99% of the light that falls on them. More complex optical coatings exhibit high reflection over some range of wavelengths, and anti-reflection over another range, allowing the production of dichroic thin-film filters.
Smart glass, also known as switchable glass, dynamic glass, and smart-tinting glass, is a type of glass that can change its reflective properties to prevent sunlight and heat from entering a building and to also provide privacy. Smart glass for building aims to provide more energy-efficient buildings by reducing the amount of solar heat that passes through glass windows.
In chemistry, chromism is a process that induces a change, often reversible, in the colors of compounds. In most cases, chromism is based on a change in the electron states of molecules, especially the π- or d-electron state, so this phenomenon is induced by various external stimuli which can alter the electron density of substances. It is known that there are many natural compounds that have chromism, and many artificial compounds with specific chromism have been synthesized to date. It is usually synonymous with chromotropism, the (reversible) change in color of a substance due to the physical and chemical properties of its ambient surrounding medium, such as temperature and pressure, light, solvent, and presence of ions and electrons.
Tungsten(VI) oxide, also known as tungsten trioxide is a chemical compound of oxygen and the transition metal tungsten, with formula WO3. The compound is also called tungstic anhydride, reflecting its relation to tungstic acid H2WO4. It is a light yellow crystalline solid.
Electrochromism is a phenomenon in which a material displays changes in color or opacity in response to an electrical stimulus. In this way, a smart window made of an electrochromic material can block specific wavelengths of ultraviolet, visible or (near) infrared light. The ability to control the transmittance of near-infrared light can increase the energy efficiency of a building, reducing the amount of energy needed to cool during summer and heat during winter.
An antireflective, antiglare or anti-reflection (AR) coating is a type of optical coating applied to the surface of lenses, other optical elements, and photovoltaic cells to reduce reflection. In typical imaging systems, this improves the efficiency since less light is lost due to reflection. In complex systems such as cameras, binoculars, telescopes, and microscopes the reduction in reflections also improves the contrast of the image by elimination of stray light. This is especially important in planetary astronomy. In other applications, the primary benefit is the elimination of the reflection itself, such as a coating on eyeglass lenses that makes the eyes of the wearer more visible to others, or a coating to reduce the glint from a covert viewer's binoculars or telescopic sight.
Chalcogenide glass is a glass containing one or more chalcogens. Up until recently, chalcogenide glasses (ChGs) were believed to be predominantly covalently bonded materials and classified as covalent network solids. A most recent and extremely comprehensive university study of more than 265 different ChG elemental compositions, representing 40 different elemental families now shows that the vast majority of chalcogenide glasses are more accurately defined as being predominantly bonded by the weaker van der Waals forces of atomic physics and more accurately classified as van der Waals network solids. They are not exclusively bonded by these weaker vdW forces, and do exhibit varying percentages of covalency, based upon their specific chemical makeup. Polonium is also a chalcogen but is not used because of its strong radioactivity. Chalcogenide materials behave rather differently from oxides, in particular their lower band gaps contribute to very dissimilar optical and electrical properties.
Silvering is the chemical process of coating a non-conductive substrate such as glass with a reflective substance, to produce a mirror. While the metal is often silver, the term is used for the application of any reflective metal.
Gentex Corporation is an American electronics and technology company that develops, designs and manufactures automatic-dimming rear-view mirrors, camera-based driver assistance systems, and other equipment for the global automotive industry. They produce dimmable aircraft windows for the commercial, business and general aviation markets. In addition, the company produces photoelectric smoke detectors, signaling devices, and the HomeLink Wireless Control System for the North American fire protection market.
An optical fiber, or optical fibre in Commonwealth English, is a flexible glass or plastic fiber that can transmit light from one end to the other. Such fibers find wide usage in fiber-optic communications, where they permit transmission over longer distances and at higher bandwidths than electrical cables. Fibers are used instead of metal wires because signals travel along them with less loss; in addition, fibers are immune to electromagnetic interference, a problem from which metal wires suffer. Fibers are also used for illumination and imaging, and are often wrapped in bundles so they may be used to carry light into, or images out of confined spaces, as in the case of a fiberscope. Specially designed fibers are also used for a variety of other applications, such as fiber optic sensors and fiber lasers.
Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO2. It is a dark blue solid. Vanadium(IV) dioxide is amphoteric, dissolving in non-oxidising acids to give the blue vanadyl ion, [VO]2+ and in alkali to give the brown [V4O9]2− ion, or at high pH [VO4]4−. VO2 has a phase transition very close to room temperature (~68 °C (341 K)). Electrical resistivity, opacity, etc, can change up several orders. Owing to these properties, it has been used in surface coating, sensors, and imaging. Potential applications include use in memory devices, phase-change switches, passive radiative cooling applications, such as smart windows and roofs, that cool or warm depending on temperature, aerospace communication systems and neuromorphic computing.
Vacuum deposition is a group of processes used to deposit layers of material atom-by-atom or molecule-by-molecule on a solid surface. These processes operate at pressures well below atmospheric pressure. The deposited layers can range from a thickness of one atom up to millimeters, forming freestanding structures. Multiple layers of different materials can be used, for example to form optical coatings. The process can be qualified based on the vapor source; physical vapor deposition uses a liquid or solid source and chemical vapor deposition uses a chemical vapor.
Physical vapor deposition (PVD), sometimes called physical vapor transport (PVT), describes a variety of vacuum deposition methods which can be used to produce thin films and coatings on substrates including metals, ceramics, glass, and polymers. PVD is characterized by a process in which the material transitions from a condensed phase to a vapor phase and then back to a thin film condensed phase. The most common PVD processes are sputtering and evaporation. PVD is used in the manufacturing of items which require thin films for optical, mechanical, electrical, acoustic or chemical functions. Examples include semiconductor devices such as thin-film solar cells, microelectromechanical devices such as thin film bulk acoustic resonator, aluminized PET film for food packaging and balloons, and titanium nitride coated cutting tools for metalworking. Besides PVD tools for fabrication, special smaller tools used mainly for scientific purposes have been developed.
Solid-state ionics is the study of ionic-electronic mixed conductor and fully ionic conductors and their uses. Some materials that fall into this category include inorganic crystalline and polycrystalline solids, ceramics, glasses, polymers, and composites. Solid-state ionic devices, such as solid oxide fuel cells, can be much more reliable and long-lasting, especially under harsh conditions, than comparable devices with fluid electrolytes.
Gasochromism is closely related to electrochromism. The process involves the interaction of an electrochrome, usually a metal oxide, such as tungsten oxide, with an oxidizing or reducing gas, commonly oxygen and hydrogen, producing reversible color changes. The gasochromic technology is used commercially in reversible smart windows and gas sensing of oxygen, hydrogen, nitric oxide, hydrogen sulphide and carbon monoxide.
SAGE Electrochromics, Inc., a wholly owned subsidiary of Saint-Gobain, is a specialized window glass developer based in Faribault, Minnesota.
Claes-Göran Sture Granqvist is a materials physicist and Professor of Solid State Physics at Uppsala University in Sweden. Granqvist is considered a pioneer and expert in photochromic materials and energy-efficient building materials such as glass, paint, and wood.
Smart inorganic polymers (SIPs) are hybrid or fully inorganic polymers with tunable (smart) properties such as stimuli responsive physical properties (shape, conductivity, rheology, bioactivity, self-repair, sensing etc.). While organic polymers are often petrol-based, the backbones of SIPs are made from elements other than carbon which can lessen the burden on scarce non-renewable resources and provide more sustainable alternatives. Common backbones utilized in SIPs include polysiloxanes, polyphosphates, and polyphosphazenes, to name a few.
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