A sintered glass filter connected to an Erlenmeyer flaskFritted glass funnels
Fritted glass is finely porous glass through which gas or liquid may pass, made by sintering together glass particles into a solid but porous body.[1] This porous glass body can also be called a frit. Applications in laboratory glassware include use in fritted glass filter items, scrubbers, or spargers. Other laboratory applications of fritted glass include packing in chromatography columns and resin beds for special chemical synthesis.
In a fritted glass filter, a disc or pane of fritted glass is used to filter out solid particles, precipitate, or residue from a fluid, similar to a piece of filter paper. The fluid can go through the pores in the fritted glass, but the frit will often stop a solid from going through. A fritted filter is often part of a glassware item, so fritted glass funnels and fritted glass crucibles are available.[2]
Laboratory scale spargers (also known as gas diffusing stones or diffusors) as well as scrubbers, and gas-washing bottles (or Drechsel bottles[3]) are similar glassware items which may use a fritted glass piece fused to the tip of a gas-inlet tube. This fritted glass tip is placed inside the vessel with liquid inside during use such that the fritted tip is submerged in the liquid. To maximize surface area contact of the gas to the liquid, a stream of gaseous particles is slowly blown into the vessel through the fritted glass tip so that it breaks up the gas into many tiny bubbles. The purpose of sparging is to saturate the enclosed liquid with the gas, often to displace another gaseous component. The purpose of a scrubber or gas-washing bottle is to scrub the gas such that the liquid absorbs one (or more) of the gaseous components to remove it from the gas stream, effectively purifying the gas stream.
Because frits are made up of particles of glass that are bonded together by small contact areas, they are not normally used in strongly alkaline conditions, as these can dissolve the glass to some extent. This is not normally a problem, as the amount dissolved is usually minute, but the equally minute bonds in a frit can be dissolved away by strong alkalis, causing the frit to fall apart over time.[citation needed]
Filtration is a physical separation process that separates solid matter and fluid from a mixture using a filter medium that has a complex structure through which only the fluid can pass. Solid particles that cannot pass through the filter medium are described as oversize and the fluid that passes through is called the filtrate. Oversize particles may form a filter cake on top of the filter and may also block the filter lattice, preventing the fluid phase from crossing the filter, known as blinding. The size of the largest particles that can successfully pass through a filter is called the effective pore size of that filter. The separation of solid and fluid is imperfect; solids will be contaminated with some fluid and filtrate will contain fine particles. Filtration occurs both in nature and in engineered systems; there are biological, geological, and industrial forms.
Laboratory glassware refers to a variety of equipment used in scientific work, and traditionally made of glass. Glass can be blown, bent, cut, molded, and formed into many sizes and shapes, and is therefore common in chemistry, biology, and analytical laboratories. Many laboratories have training programs to demonstrate how glassware is used and to alert first–time users to the safety hazards involved with using glassware.
Filter paper is a semi-permeable paper barrier placed perpendicular to a liquid or air flow. It is used to separate fine solid particles from liquids or gases.
A funnel is a tube or pipe that is wide at the top and narrow at the bottom, used for guiding liquid or powder into a small opening.
A Büchner funnel is a piece of laboratory equipment used in filtration. It is traditionally made of porcelain, but glass and plastic funnels are also available. On top of the funnel-shaped part there is a cylinder with a fritted glass disc/perforated plate separating it from the funnel. The Hirsch funnel has a similar design; it is used similarly, but for smaller quantities of material. The main difference is that the plate of a Hirsch funnel is much smaller, and the walls of the funnel angle outward instead of being vertical.
A watch glass is a circular concave piece of glass used in chemistry as a surface to evaporate a liquid, to hold solids while being weighed, for heating a small amount of substance, and as a cover for a beaker. When used to cover beakers, the purpose is generally to prevent dust or other particles from entering the beaker; the watch glass does not completely seal the beaker, so gas exchanges still occur. When used as an evaporation surface, a watch glass allows closer observation of precipitates or crystallization. It can be placed on a surface of contrasting colors to improve the visibility overall. Watch glasses are also sometimes used to cover a glass of whisky, to concentrate the aromas in the glass, and to prevent spills when the whisky is swirled. Watch glasses are named so because they are similar to the glass used for the front of old-fashioned pocket watches. These large watch glasses are occasionally known as clock glasses.
An ampoule is a small sealed vial which is used to contain and preserve a sample, usually a solid or liquid. Ampoules are usually made of glass.
A dust collector is a system used to enhance the quality of air released from industrial and commercial processes by collecting dust and other impurities from air or gas. Designed to handle high-volume dust loads, a dust collector system consists of a blower, dust filter, a filter-cleaning system, and a dust receptacle or dust removal system. It is distinguished from air purifiers, which use disposable filters to remove dust.
Aeration is the process by which air is circulated through, mixed with or dissolved in a liquid or other substances that act as a fluid. Aeration processes create additional surface area in the mixture, allowing greater chemical or suspension reactions.
A policeman is a hand-held flexible natural-rubber or plastic scraper. The common type of it is attached to a glass rod and used in chemical laboratories to transfer residues of precipitate or solid on glass surfaces when performing gravimetric analysis. This equipment works well under gentle, delicate and precise requirement. A policeman also comes in various sizes, shapes, and types. Some of them come in one-piece flexible plastic version and some in stainless. The origin of the policeman and its name cannot be identified for sure but some clues led back to the 19th century from German chemist Carl Remigius Fresenius.
A venturi scrubber is designed to effectively use the energy from a high-velocity inlet gas stream to atomize the liquid being used to scrub the gas stream. This type of technology is a part of the group of air pollution controls collectively referred to as wet scrubbers.
The term wet scrubber describes a variety of devices that remove pollutants from a furnace flue gas or from other gas streams. In a wet scrubber, the polluted gas stream is brought into contact with the scrubbing liquid, by spraying it with the liquid, by forcing it through a pool of liquid, or by some other contact method, so as to remove the pollutants.
Diffusivity, mass diffusivity or diffusion coefficient is usually written as the proportionality constant between the molar flux due to molecular diffusion and the negative value of the gradient in the concentration of the species. More accurately, the diffusion coefficient times the local concentration is the proportionality constant between the negative value of the mole fraction gradient and the molar flux. This distinction is especially significant in gaseous systems with strong temperature gradients. Diffusivity derives its definition from Fick's law and plays a role in numerous other equations of physical chemistry.
Particle collection in wet scrubbers capture relatively small dust particles with the wet scrubber's large liquid droplets. In most wet scrubbing systems, droplets produced are generally larger than 50 micrometres. As a point of reference, human hair ranges in diameter from 50 to 100 micrometres. The size distribution of particles to be collected is source specific. For example, particles produced by mechanical means tend to be large ; whereas, particles produced from combustion or a chemical reaction will have a substantial portion of small and submicrometre particles.
Cannula transfer or cannulation is a set of air-free techniques used with a Schlenk line, in transferring liquid or solution samples between reaction vessels via cannulae, avoiding atmospheric contamination. While the syringes are not the same as cannulae, the techniques remain relevant.
In chemistry, recrystallization is a technique used to purify chemicals. By dissolving a mixture of a compound and impurities in an appropriate solvent, either the desired compound or impurities can be removed from the solution, leaving the other behind. It is named for the crystals often formed when the compound precipitates out. Alternatively, recrystallization can refer to the natural growth of larger ice crystals at the expense of smaller ones.
Laboratory funnels are funnels that have been made for use in the chemical laboratory. There are many different kinds of funnels that have been adapted for these specialized applications. Filter funnels, thistle funnels, and dropping funnels have stopcocks which allow the fluids to be added to a flask slowly. For solids, a powder funnel with a short and wide neck/stem is more appropriate as it prevents clogging.
The circulating fluidized bed (CFB) is a type of Fluidized bed combustion that utilizes a recirculating loop for even greater efficiency of combustion. while achieving lower emission of pollutants. Reports suggest that up to 95% of pollutants can be absorbed before being emitted into the atmosphere. The technology is limited in scale however, due to its extensive use of limestone, and the fact that it produces waste byproducts.
A Schlenk-frit is a laboratory filtration device operating under inert gas conditions. It separates air- and water-sensitive suspensions into liquid and solid parts. A Schlenk-frit is made of a glass tube with a ground glass joint at both ends, a fused filter and valves at both sides.
Gravity filtration is a method of filtering impurities from solutions by using gravity to pull liquid through a filter. The two main kinds of filtration used in laboratories are gravity and vacuum/suction. Gravity filtration is often used in chemical laboratories to filter precipitates from precipitation reactions as well as drying agents, inadmissible side items, or remaining reactants. While it can also be used to separate out strong products, vacuum filtration is more commonly used for this purpose.
This page is based on this Wikipedia article Text is available under the CC BY-SA 4.0 license; additional terms may apply. Images, videos and audio are available under their respective licenses.
