Electropolishing

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Electropolishing principle: 1. Electrolyte 2. Cathode 3. Workpiece to polish (Anode) 4. Particle moving from the work-piece to the cathode 5. Surface before polishing 6. Surface after polishing Electropolishing principle.png
Electropolishing principle: 1. Electrolyte 2. Cathode 3. Workpiece to polish (Anode) 4. Particle moving from the work-piece to the cathode 5. Surface before polishing 6. Surface after polishing

Electropolishing, also known as electrochemical polishing, anodic polishing, or electrolytic polishing (especially in the metallography field), is an electrochemical process that removes material from a metallic workpiece, reducing the surface roughness by levelling micro-peaks and valleys, improving the surface finish. [1] Electropolishing is often compared to, but distinctly different from, electrochemical machining. It is used to polish, passivate, and deburr metal parts. It is often described as the reverse of electroplating.[ citation needed ]

Contents

It may be used in lieu of abrasive fine polishing in microstructural preparation. [2]

Mechanism

Typically, the workpiece is immersed in a temperature-controlled bath of electrolyte and serves as the cathode. At the cathode, a reduction reaction occurs, which normally produces hydrogen. The tiny hydrogen bubbles forming on the surface of the workpiece exert a scrubbing action which can be used to clean and polish the part. Electrolytes used for electropolishing are most often concentrated acid solutions such as mixtures of sulfuric acid and phosphoric acid. Other electropolishing electrolytes reported in the literature include mixtures of perchloric acid with acetic anhydride (which has caused fatal explosions), and methanolic solutions of sulfuric acid. [3]

To electropolish a rough surface, the protruding parts of a surface profile must dissolve faster than the recesses. This process, referred to as anodic leveling, can be subject to incorrect analysis when measuring the surface topography. [4] Anodic dissolution under electropolishing conditions deburrs metal objects due to increased current density on corners and burrs. Most importantly, successful electropolishing should operate under diffusion limited constant current plateau, achieved by following current dependence on voltage (polarisation curve), under constant temperature and stirring conditions.

Benefits

Applications

Due to its ease of operation and its usefulness in polishing irregularly-shaped objects, electropolishing has become a common process in the production of semiconductors.

As electropolishing can also be used to sterilize workpieces, the process plays an essential role in the food, medical, and pharmaceutical industries. [5]

It is commonly used in the post-production of large metal pieces such as those used in drums of washing machines, bodies of ocean vessels and aircraft, and automobiles.

While nearly any metal may be electropolished, the most-commonly polished metals are 300- and 400-series stainless steel, aluminum, copper, titanium, and nickel- and copper-alloys.

Ultra-high vacuum (UHV) components are typically electropolished in order to have a smoother surface for improved vacuum pressures, out-gassing rates, and pumping speed.

Electropolishing is commonly used to prepare thin metal samples for transmission electron microscopy and atom probe tomography [6] because the process does not mechanically deform surface layers like mechanical polishing does.

Standards

See also

References

  1. "Electropolishing | Britannica". www.britannica.com. Retrieved 2024-10-31.
  2. Vander Voort, G.F. ed. (2004) "Chemical and Electrolytic Polishing," ASM Handbook, Vol. 9: Metallography and Microstructures, ASM International, pp. 281-293, ISBN   978-0-87170-706-2.
  3. "The "Then & Now" of Electropolishing" (PDF). Anopol Limited/Surface World. Archived from the original on November 7, 2014. Retrieved 20 March 2017.
  4. "Surface Texture: Electroplishing and Ra" (PDF). Anopol Limited/British Stainless Steel Association. Retrieved 20 March 2017.
  5. Cutchin, Johnson H. Sr. (October 27, 2015). "Electropolishing applications and techniques". The Fabricator.
  6. F. Kelly, Thomas; K. Miller, Michael (2007). "Atom probe tomography". Review of Scientific Instruments. 78 (3): 031101. doi: 10.1063/1.2709758 . PMID   17411171.