Element collecting

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A set of periodic-table elements, lacking several highly radioactive elements which are impractical or impossible to collect. Wooden periodic table.jpg
A set of periodic-table elements, lacking several highly radioactive elements which are impractical or impossible to collect.
An assortment of precious metals Edelmetalle.jpg
An assortment of precious metals
Hafnium samples for collectors Hafnium pellets with a thin oxide layer.jpg
Hafnium samples for collectors

Element collecting is the hobby of collecting the chemical elements. Many element collectors simply enjoy finding peculiar uses of chemical elements. Others enjoy studying the properties of the elements, possibly engaging in amateur chemistry, and some simply collect elements for no practical reason. Some element collectors invest in elements, while some amateur chemists have amassed a large collection of elements—Oliver Sacks, for example. [1] In recent years, the hobby has gained popularity with media attention brought by element collectors like Theodore Gray. Sagar Jamane describes element collecting as “more a discipline than a hobby.” “It’s a reminder of the enormous effort of all the beautiful minds behind the periodic table and element discovery,” he says, adding that it’s thrilling to see the elements that make up the universe at such close quarters. [2]

Contents

Acquiring elements

Some collectors attempt to collect very high purity samples of each element. Others prefer to find the element in everyday use. Some are averse to collecting the element as a compound or alloy, while others find this acceptable. Collectors may isolate elements in their own homes. Hydrogen, for example, can be easily isolated via the electrolysis of water. [3]

In addition to the element samples, some element collectors also collect items connected with the element, such as manufactured goods containing the element, rocks and minerals with the element as a constituent or compounds of the element. Some manufacturers also sell coins made from pure elements, and density cubes made from the pure element can also be sourced on auction sites such as eBay.

Some commercial retailers now cater to the element collecting community, even selling large quantities in sets, [4] since purchasing elements from large chemical companies is frequently prohibited or uneconomical for individuals. There are a number of specialist element providers which retail to the public over the web, sell individual element samples in addition to full and partial element sets. Many also sell elements through auction sites, such as eBay. Established specialist providers include RGB Elements, Engineered Labs, [5] Nova Elements, [6] Smart Elements, [7] SMT Metalle Wimmer, [8] PEGUYS, [9] Metallium, [10] Collect the Periodic Table, Luciteria, [11] and Onyxmet. [12] [ citation needed ]

Practical issues

Collecting macroscopic samples of all the elements is problematic: some elements, such as mercury, beryllium, thallium, plutonium, and arsenic are toxic and so are difficult to find or their sale is restricted. Others are rare in commerce, and thus hard to buy or expensive: scandium, lutetium, and thulium. Some, such as caesium, white phosphorus, and fluorine, are too reactive and have restrictions on their shipping; others, such as gallium, react corrosively and very fast with aluminium, so cannot be shipped by air. [13] Some, such as phosphorus and iodine, are controlled due to use in clandestine chemistry. [14] Others, like radon and astatine, are radioactive and have half-lives too short for practical collection in addition to their radioactive hazards. Usually only the stable elements from hydrogen to bismuth (except the radioactive technetium and promethium) are collected, with the exceptions of the extremely long-lived thorium and uranium. It is possible to source other radioactive elements, such as radium (usually in the form of radium sulfate as part of luminescent paint on antique watch hands, [15] americium (in the form of radioactive buttons containing 0.29 micrograms of americium extracted from older smoke detectors), promethium (often in the form of luminous paint), [15] polonium from devices meant to eliminate static electricity, [16] and technetium with a half-life of six hours plated on foil. [17]

In What If?, Randall Munroe humorously explored the practicalities of building a periodic table consisting of bricks of each of the elements. He points out that many of the elements would immediately react with the air or with each other, sometimes with dramatic results. Astatine is so radioactive that it would quickly be "vaporized by its own heat". He concludes: [18]

While collecting things is certainly fun, when it comes to chemical elements, you do not want to collect them all.

Notable collectors

Several collectors have gained notoriety for their large element collections in addition to their other accomplishments, including: [5]

See also

Related Research Articles

Astatine is a chemical element; it has symbol At and atomic number 85. It is the rarest naturally occurring element in the Earth's crust, occurring only as the decay product of various heavier elements. All of astatine's isotopes are short-lived; the most stable is astatine-210, with a half-life of 8.1 hours. Consequently, a solid sample of the element has never been seen, because any macroscopic specimen would be immediately vaporized by the heat of its radioactivity.

A chemical element is a chemical substance whose atoms all have the same number of protons. The number of protons is called the atomic number of that element. For example, oxygen has an atomic number of 8, meaning each oxygen atom has 8 protons in its nucleus. Atoms of the same element can have different numbers of neutrons in their nuclei, known as isotopes of the element. Two or more atoms can combine to form molecules. Some elements are formed from molecules of identical atoms, e. g. atoms of hydrogen (H) form diatomic molecules (H2). Chemical compounds are substances made of atoms of different elements; they can have molecular or non-molecular structure. Mixtures are materials containing different chemical substances; that means (in case of molecular substances) that they contain different types of molecules. Atoms of one element can be transformed into atoms of a different element in nuclear reactions, which change an atom's atomic number.

<span class="mw-page-title-main">Chalcogen</span> Group of chemical elements

The chalcogens are the chemical elements in group 16 of the periodic table. This group is also known as the oxygen family. Group 16 consists of the elements oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and the radioactive elements polonium (Po) and livermorium (Lv). Often, oxygen is treated separately from the other chalcogens, sometimes even excluded from the scope of the term "chalcogen" altogether, due to its very different chemical behavior from sulfur, selenium, tellurium, and polonium. The word "chalcogen" is derived from a combination of the Greek word khalkos (χαλκός) principally meaning copper, and the Latinized Greek word genēs, meaning born or produced.

<span class="mw-page-title-main">Halogen</span> Group of chemical elements

The halogens are a group in the periodic table consisting of six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and the radioactive elements astatine (At) and tennessine (Ts), though some authors would exclude tennessine as its chemistry is unknown and is theoretically expected to be more like that of gallium. In the modern IUPAC nomenclature, this group is known as group 17.

<span class="mw-page-title-main">Promethium</span> Chemical element with atomic number 61 (Pm)

Promethium is a chemical element with symbol Pm and atomic number 61. All of its isotopes are radioactive; it is extremely rare, with only about 500–600 grams naturally occurring in the Earth's crust at any given time. Promethium is one of the only two radioactive elements that are both preceded and followed in the periodic table by elements with stable forms, the other being technetium. Chemically, promethium is a lanthanide. Promethium shows only one stable oxidation state of +3.

<span class="mw-page-title-main">Synthetic element</span> Chemical elements that do not occur naturally

A synthetic element is one of 24 known chemical elements that do not occur naturally on Earth: they have been created by human manipulation of fundamental particles in a nuclear reactor, a particle accelerator, or the explosion of an atomic bomb; thus, they are called "synthetic", "artificial", or "man-made". The synthetic elements are those with atomic numbers 95–118, as shown in purple on the accompanying periodic table: these 24 elements were first created between 1944 and 2010. The mechanism for the creation of a synthetic element is to force additional protons into the nucleus of an element with an atomic number lower than 95. All known synthetic elements are unstable, but they decay at widely varying rates; the half-lives of their longest-lived isotopes range from microseconds to millions of years.

<span class="mw-page-title-main">Technetium</span> Chemical element with atomic number 43 (Tc)

Technetium is a chemical element; it has symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. Technetium and promethium are the only radioactive elements whose neighbours in the sense of atomic number are both stable. All available technetium is produced as a synthetic element. Naturally occurring technetium is a spontaneous fission product in uranium ore and thorium ore, or the product of neutron capture in molybdenum ores. This silvery gray, crystalline transition metal lies between manganese and rhenium in group 7 of the periodic table, and its chemical properties are intermediate between those of both adjacent elements. The most common naturally occurring isotope is 99Tc, in traces only.

The transuraniumelements are the chemical elements with atomic number greater than 92, which is the atomic number of uranium. All of them are radioactively unstable and decay into other elements. Except for neptunium and plutonium which have been found in trace amounts in nature, none occur naturally on Earth and they are synthetic.

A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay. These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay. However, for a collection of atoms of a single nuclide the decay rate, and thus the half-life (t1/2) for that collection, can be calculated from their measured decay constants. The range of the half-lives of radioactive atoms has no known limits and spans a time range of over 55 orders of magnitude.

<span class="mw-page-title-main">Mendeleev's predicted elements</span> Elements predicted to exist but not yet found on the first periodic table

Dmitri Mendeleev published a periodic table of the chemical elements in 1869 based on properties that appeared with some regularity as he laid out the elements from lightest to heaviest. When Mendeleev proposed his periodic table, he noted gaps in the table and predicted that then-unknown elements existed with properties appropriate to fill those gaps. He named them eka-boron, eka-aluminium, eka-silicon, and eka-manganese, with respective atomic masses of 44, 68, 72, and 100.

<span class="mw-page-title-main">Period (periodic table)</span> Method of visualizing the relationship between elements

A period on the periodic table is a row of chemical elements. All elements in a row have the same number of electron shells. Each next element in a period has one more proton and is less metallic than its predecessor. Arranged this way, elements in the same group (column) have similar chemical and physical properties, reflecting the periodic law. For example, the halogens lie in the second-to-last group and share similar properties, such as high reactivity and the tendency to gain one electron to arrive at a noble-gas electronic configuration. As of 2022, a total of 118 elements have been discovered and confirmed.

<span class="mw-page-title-main">Carbon group</span> Periodic table group

The carbon group is a periodic table group consisting of carbon (C), silicon (Si), germanium (Ge), tin (Sn), lead (Pb), and flerovium (Fl). It lies within the p-block.

A period 5 element is one of the chemical elements in the fifth row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The fifth period contains 18 elements, beginning with rubidium and ending with xenon. As a rule, period 5 elements fill their 5s shells first, then their 4d, and 5p shells, in that order; however, there are exceptions, such as rhodium.

A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the chemical elements, including the lanthanides. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The sixth period contains 32 elements, tied for the most with period 7, beginning with caesium and ending with radon. Lead is currently the last stable element; all subsequent elements are radioactive. For bismuth, however, its only primordial isotope, 209Bi, has a half-life of more than 1019 years, over a billion times longer than the current age of the universe. As a rule, period 6 elements fill their 6s shells first, then their 4f, 5d, and 6p shells, in that order; however, there are exceptions, such as gold.

<span class="mw-page-title-main">Decay chain</span> Series of radioactive decays

In nuclear science a decay chain refers to the predictable series of radioactive disintegrations undergone by the nuclei of certain unstable chemical elements.

A period 7 element is one of the chemical elements in the seventh row of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behavior of the elements as their atomic number increases: a new row is begun when chemical behavior begins to repeat, meaning that elements with similar behavior fall into the same vertical columns. The seventh period contains 32 elements, tied for the most with period 6, beginning with francium and ending with oganesson, the heaviest element currently discovered. As a rule, period 7 elements fill their 7s shells first, then their 5f, 6d, and 7p shells in that order, but there are exceptions, such as uranium.

Chemical elements may be named from various sources: sometimes based on the person who discovered it, or the place it was discovered. Some have Latin or Greek roots deriving from something related to the element, for example some use to which it may have been put.

<span class="mw-page-title-main">Promethium compounds</span>

Promethium compounds are compounds containing the element promethium, which normally take the +3 oxidation state. Promethium belongs to the cerium group of lanthanides and is chemically very similar to the neighboring elements. Because of its instability, chemical studies of promethium are incomplete. Even though a few compounds have been synthesized, they are not fully studied; in general, they tend to be pink or red in color. Treatment of acidic solutions containing Pm3+ ions with ammonia results in a gelatinous light-brown sediment of hydroxide, Pm(OH)3, which is insoluble in water. When dissolved in hydrochloric acid, a water-soluble yellow salt, PmCl3, is produced; similarly, when dissolved in nitric acid, a nitrate results, Pm(NO3)3. The latter is also well-soluble; when dried, it forms pink crystals, similar to Nd(NO3)3. The electron configuration for Pm3+ is [Xe] 4f4, and the color of the ion is pink. The ground state term symbol is 5I4. The sulfate is slightly soluble, like the other cerium group sulfates. Cell parameters have been calculated for its octahydrate; they lead to conclusion that the density of Pm2(SO4)3·8 H2O is 2.86 g/cm3. The oxalate, Pm2(C2O4)3·10 H2O, has the lowest solubility of all lanthanide oxalates.

References

  1. Sacks, Oliver (2001). Uncle Tungsten: Memories of a Chemical Boyhood . Vintage Books. ISBN   978-0-375-40448-1.
  2. "It's Elementary! A Niche New Hobby Occupies India's Element Collectors". IndiaTimes. 2023-10-03. Retrieved 2024-03-29.
  3. Gray, Theodore. "The Wooden Periodic Table Table" . Retrieved 20 November 2010.
  4. Gray, Theodore. "How to Get Your Own Element Collection" . Retrieved 8 March 2015.
  5. 1 2 Halford, Bethany (June 29, 2019). "Element collecting: A niche hobby that connects people to chemistry". Chemical & Engineering News . Retrieved May 20, 2024.
  6. "Buy Periodic Table Elements". NovaElements ®. Retrieved 2024-10-08.
  7. "Shop". www.smart-elements.com. Retrieved 2024-11-24.
  8. "SMT Metalle Wimmer". SMT Metalle Wimmer. Retrieved 2024-11-24.
  9. "The Periodic Element Guys". The Periodic Element Guys. Retrieved 2024-10-08.
  10. "Metallium - ElementSales.com - Rare, Exotic Metals and Elements". elementsales.com. Retrieved 2024-11-24.
  11. "Luciteria Science". Luciteria. Retrieved 2024-10-08.
  12. "Onyxmet". onyxmet.com. Retrieved 2024-10-08.
  13. "Publication 52, Hazardous, Restricted, and Perishable Mail" (PDF). USPS. January 2008.
  14. "2007 - Changes in the Regulation of Iodine Crystals and Chemical Mixtures Containing Over 2.2 Percent Iodine". www.deadiversion.usdoj.gov. Archived from the original on 2022-03-08. Retrieved 2022-03-08.
  15. 1 2 "Radioluminescent Items". Museum of Radiation and Radioactivity. Retrieved 29 May 2024.
  16. "Backgrounder on Polonium-210". NRC Web. United States Nuclear Regulatory Commission.
  17. "Technetium". Departement Materiaalkunde (in Dutch). Retrieved 29 May 2024.
  18. Munroe, Randall (2014). What if? : serious scientific answers to absurd hypothetical questions. Houghton Mifflin Harcourt. pp. 35–42. ISBN   978-0-544-27299-6.
  19. Nikischer, Tony (November 30, 2021). "Rediscovery of the Elements". Mindat.org.