Environmental stress fracture

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In materials science, environmental stress fracture or environment assisted fracture is the generic name given to premature failure under the influence of tensile stresses and harmful environments of materials such as metals and alloys, composites, plastics and ceramics.

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Metals and alloys exhibit phenomena such as stress corrosion cracking, hydrogen embrittlement, liquid metal embrittlement and corrosion fatigue all coming under this category. Environments such as moist air, sea water and corrosive liquids and gases cause environmental stress fracture. Metal matrix composites are also susceptible to many of these processes.

Plastics and plastic-based composites may suffer swelling, debonding and loss of strength when exposed to organic fluids and other corrosive environments, such as acids and alkalies. Under the influence of stress and environment, many structural materials, particularly the high-specific strength ones become brittle and lose their resistance to fracture. While their fracture toughness remains unaltered, their threshold stress intensity factor for crack propagation may be considerably lowered. Consequently, they become prone to premature fracture because of sub-critical crack growth. This article aims to give a brief overview of the various degradation processes mentioned above.

Stress corrosion cracking

A .35 Remington brass cartridge that has experienced season cracking. 35remsplitneck.jpg
A .35 Remington brass cartridge that has experienced season cracking.

Stress corrosion cracking is a phenomenon where a synergistic action of corrosion and tensile stress leads to brittle fracture of normally ductile materials at generally lower stress levels. During stress corrosion cracking, the material is relatively unattacked by the corrosive agent (no general corrosion, only localized corrosion), but fine cracks form within it. This process has serious implications on the utilisation of the material because the applicable safe stress levels are drastically reduced in the corrosive medium. Season cracking and caustic embrittlement are two stress corrosion cracking processes which affected the serviceability of brass cartridge cases and riveted steel boilers respectively.

Hydrogen embrittlement

Small quantities of hydrogen present inside certain metallic materials make the latter brittle and susceptible to sub-critical crack growth under stress. Hydrogen embrittlement may occur as a side effect of electroplating processes.

Delayed failure is the fracture of a component under stress after an elapsed time, is a characteristic feature of hydrogen embrittlement (2). Hydrogen entry into the material may be effected during plating, pickling, phosphating, melting, casting or welding. Corrosion during service in moist environments generates hydrogen, part of which may enter the metal as atomic hydrogen (H) and cause embrittlement. Presence of a tensile stress, either inherent or externally applied, is necessary for metals to be damaged. As in the case of stress corrosion cracking, hydrogen embrittlement may also lead to a decrease in the threshold stress intensity factor for crack propagation or an increase in the sub-critical crack growth velocity of the material. The most visible effect of hydrogen in materials is a drastic reduction in ductility during tensile tests. It may increase, decrease or leave unaffected the yield strength of the material.

Hydrogen may also cause serrated yielding in certain metals such as niobium, nickel and some steels (3).

Case studies

The collapsed Silver Bridge, as seen from the Ohio side Silver Bridge collapsed, Ohio side.jpg
The collapsed Silver Bridge, as seen from the Ohio side

One of the worst disasters caused by stress corrosion cracking was the fall of the Silver Bridge, WV in 1967, when a single brittle crack formed by rusting grew to criticality. The crack was on one of the tie bar links of one of the suspension chains, and the whole joint failed quickly by overload. The event escalated and the whole bridge disappeared in less than a minute, killing 46 drivers or passengers on the bridge at the time.

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Ductility Degree to which a material under stress irreversibly deforms before failure

Ductility is a mechanical property commonly described as a material's amenability to drawing. In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stress before failure. Ductility is an important consideration in engineering and manufacturing, defining a material's suitability for certain manufacturing operations and its capacity to absorb mechanical overload. Some metals that are generally described as ductile include gold and copper. However, not all metals experience ductile failure as some can be characterized with brittle failure like cast iron. Polymers generally can be viewed as ductile materials as they typically allow for plastic deformation.

Fracture Split of materials or structures under stress

Fracture is the separation of an object or material into two or more pieces under the action of stress. The fracture of a solid usually occurs due to the development of certain displacement discontinuity surfaces within the solid. If a displacement develops perpendicular to the surface, it is called a normal tensile crack or simply a crack; if a displacement develops tangentially, it is called a shear crack, slip band or dislocation.

Fatigue (material) Initiation and propagation of cracks in a material due to cyclic loading

In materials science, fatigue is the initiation and propagation of cracks in a material due to cyclic loading. Once a fatigue crack has initiated, it grows a small amount with each loading cycle, typically producing striations on some parts of the fracture surface. The crack will continue to grow until it reaches a critical size, which occurs when the stress intensity factor of the crack exceeds the fracture toughness of the material, producing rapid propagation and typically complete fracture of the structure.

Fracture mechanics Field of mechanics which studies the propagation of cracks in materials

Fracture mechanics is the field of mechanics concerned with the study of the propagation of cracks in materials. It uses methods of analytical solid mechanics to calculate the driving force on a crack and those of experimental solid mechanics to characterize the material's resistance to fracture.

Hydrogen embrittlement Embrittlement of a metal exposed to hydrogen

Hydrogen embrittlement (HE) also known as hydrogen assisted cracking or hydrogen-induced cracking, describes the embrittlement of a metal by hydrogen. The essential facts about the nature of the hydrogen embrittlement of steels have now been known for 140 years. It is atomic hydrogen that is harmful to the toughness of iron and steel. It is a low temperature effect: most metals are relatively immune to hydrogen embrittlement above approximately 150°C.

Stress corrosion cracking Growth of cracks in a corrosive environment

Stress corrosion cracking (SCC) is the growth of crack formation in a corrosive environment. It can lead to unexpected and sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. SCC is highly chemically specific in that certain alloys are likely to undergo SCC only when exposed to a small number of chemical environments. The chemical environment that causes SCC for a given alloy is often one which is only mildly corrosive to the metal. Hence, metal parts with severe SCC can appear bright and shiny, while being filled with microscopic cracks. This factor makes it common for SCC to go undetected prior to failure. SCC often progresses rapidly, and is more common among alloys than pure metals. The specific environment is of crucial importance, and only very small concentrations of certain highly active chemicals are needed to produce catastrophic cracking, often leading to devastating and unexpected failure.

Intergranular fracture

Intergranular fracture, intergranular cracking or intergranular embrittlement occurs when a crack propagates along the grain boundaries of a material, usually when these grain boundaries are weakened. The more commonly seen transgranular fracture, occurs when the crack grows through the material grains. As an analogy, in a wall of bricks, intergranular fracture would correspond to a fracture that takes place in the mortar that keeps the bricks together.

Hydrogen damage is the generic name given to a large number of metal degradation processes due to interaction with hydrogen atoms. Note that molecular gaseous hydrogen does not have the same effect as atoms or ions released into solid solution in the metal.

Liquid metal embrittlement (LME), also known as liquid metal induced embrittlement, is a phenomenon of practical importance, where certain ductile metals experience drastic loss in tensile ductility or undergo brittle fracture when exposed to specific liquid metals. Generally, a tensile stress, either externally applied or internally present, is needed to induce embrittlement. Exceptions to this rule have been observed, as in the case of aluminium in the presence of liquid gallium. This phenomenon has been studied since the beginning of the 20th century. Many of its phenomenological characteristics are known and several mechanisms have been proposed to explain it. The practical significance of liquid metal embrittlement is revealed by the observation that several steels experience ductility losses and cracking during hot-dip galvanizing or during subsequent fabrication. Cracking can occur catastrophically and very high crack growth rates have been measured.

Corrosion fatigue is fatigue in a corrosive environment. It is the mechanical degradation of a material under the joint action of corrosion and cyclic loading. Nearly all engineering structures experience some form of alternating stress, and are exposed to harmful environments during their service life. The environment plays a significant role in the fatigue of high-strength structural materials like steel, aluminum alloys and titanium alloys. Materials with high specific strength are being developed to meet the requirements of advancing technology. However, their usefulness depends to a large extent on the degree to which they resist corrosion fatigue.

Embrittlement Loss of ductility of a material, making it brittle

Embrittlement is a significant decrease of ductility of a material, which makes the material brittle. Embrittlement is used to describe any phenomena where the environment compromises a stressed material's mechanical performance, such as temperature or environmental composition. This is oftentimes undesirable as brittle fracture occurs quicker and can much more easily propagate than ductile fracture, leading to complete failure of the equipment. Various materials have different mechanisms of embrittlement, therefore it can manifest in a variety of ways, from slow crack growth to a reduction of tensile ductility and toughness.

Fracture (geology) Geologic discontinuity feature, often a joint or fault

A fracture is any separation in a geologic formation, such as a joint or a fault that divides the rock into two or more pieces. A fracture will sometimes form a deep fissure or crevice in the rock. Fractures are commonly caused by stress exceeding the rock strength, causing the rock to lose cohesion along its weakest plane. Fractures can provide permeability for fluid movement, such as water or hydrocarbons. Highly fractured rocks can make good aquifers or hydrocarbon reservoirs, since they may possess both significant permeability and fracture porosity.

Environmental stress cracking Brittle failure of thermoplastic polymers

Environmental Stress Cracking (ESC) is one of the most common causes of unexpected brittle failure of thermoplastic polymers known at present. According to ASTM D883, stress cracking is defined as "an external or internal crack in a plastic caused by tensile stresses less than its short-term mechanical strength". This type of cracking typically involves brittle cracking, with little or no ductile drawing of the material from its adjacent failure surfaces. Environmental stress cracking may account for around 15-30% of all plastic component failures in service. This behavior is especially prevalent in glassy, amorphous thermoplastics. Amorphous polymers exhibit ESC because of their loose structure which makes it easier for the fluid to permeate into the polymer. Amorphous polymers are more prone to ESC at temperature higher than their glass transition temperature (Tg) due to the increased free volume. When Tg is approached, more fluid can permeate into the polymer chains.

Material failure theory is an interdisciplinary field of materials science and solid mechanics which attempts to predict the conditions under which solid materials fail under the action of external loads. The failure of a material is usually classified into brittle failure (fracture) or ductile failure (yield). Depending on the conditions most materials can fail in a brittle or ductile manner or both. However, for most practical situations, a material may be classified as either brittle or ductile.

Metallurgical failure analysis is the process to determine the mechanism that has caused a metal component to fail. It can identify the cause of failure, providing insight into the root cause and potential solutions to prevent similar failures in the future, as well as culpability, which is important in legal cases. Resolving the source of metallurgical failures can be of financial interest to companies. The annual cost of corrosion in the United States was estimated by NACE International in 2012 to be $450 billion a year, a 67% increase compared to estimates for 2001. These failures can be analyzed to determine their root cause, which if corrected, would save reduce the cost of failures to companies.

Polymer fracture is the study of the fracture surface of an already failed material to determine the method of crack formation and extension in polymers both fiber reinforced and otherwise. Failure in polymer components can occur at relatively low stress levels, far below the tensile strength because of four major reasons: long term stress or creep rupture, cyclic stresses or fatigue, the presence of structural flaws and stress-cracking agents. Formations of submicroscopic cracks in polymers under load have been studied by x ray scattering techniques and the main regularities of crack formation under different loading conditions have been analyzed. The low strength of polymers compared to theoretically predicted values are mainly due to the many microscopic imperfections found in the material. These defects namely dislocations, crystalline boundaries, amorphous interlayers and block structure can all lead to the non-uniform distribution of mechanical stress.


Concrete is widely used construction material all over the world. It is composed of aggregate, cement and water. Composition of concrete varies to suit for different applications desired. Even size of the aggregate can influence mechanical properties of concrete to a great extent.

Static fatigue describes the fracture that happens at a stress level that is less than that required to cause an ordinary tensile fracture. It is a manifestation of the possible adverse effects of the environment on the behaviour of materials. This term highlights the contribution of the environment to the crack propagation in materials that are under applied or residual stress, which leads to stress concentration and thus stress fatigue. It is also called “delayed fracture”, referring to the long period of time the crack takes to grow large enough to cause spontaneous failure. It is a form of material embrittlement, and occurs in various materials and diverse environments.

Metal-induced embrittlement (MIE) is the embrittlement caused by diffusion of metal, either solid or liquid, into the base material. Metal induced embrittlement occurs when metals are in contact with low-melting point metals while under tensile stress. The embrittler can be either solid (SMIE) or liquid. Under sufficient tensile stress, MIE failure occurs instantaneously at temperatures just above melting point. For temperatures below the melting temperature of the embrittler, solid-state diffusion is the main transport mechanism. This occurs in the following ways:

Striation (fatigue)

Striations are marks produced on the fracture surface that show the incremental growth of a fatigue crack. A striation marks the position of the crack tip at the time it was made. The term striation generally refers to ductile striations which are rounded bands on the fracture surface separated by depressions or fissures and can have the same appearance on both sides of the mating surfaces of the fatigue crack. Although some research has suggested that many loading cycles are required to form a single striation, it is now generally thought that each striation is the result of a single loading cycle.

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