Equilibrium moisture content

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Equilibrium moisture content of wood versus humidity and temperature, according to the Hailwood-Horrobin equation. Hailwood-Horrobin EMC graph.svg
Equilibrium moisture content of wood versus humidity and temperature, according to the Hailwood-Horrobin equation.

The equilibrium moisture content (EMC) of a hygroscopic material surrounded at least partially by air is the moisture content at which the material is neither gaining nor losing moisture. The value of the EMC depends on the material and the relative humidity and temperature of the air with which it is in contact. The speed with which it is approached depends on the properties of the material, the surface-area-to-volume ratio of its shape, and the speed with which humidity is carried away or towards the material (e.g. diffusion in stagnant air or convection in moving air).

Contents

Equilibrium moisture content of grains

The moisture content of grains is an essential property in food storage. The moisture content that is safe for long-term storage is 12% for corn, sorghum, rice and wheat and 11% for soybean [1]

At a constant relative humidity of air, the EMC will drop by about 0.5% for every increase of 10 °C air temperature. [2]

The following table shows the equilibriums for a number of grains (data from [1] ). These values are only approximations since the exact values depend on the specific variety of a grain. [2]

Corn kernelsSoybeanSorghumLong Grain RiceDurum Wheat
°C 1.710.021.137.81.710.021.137.81.710.021.137.81.710.021.137.81.710.021.137.8
RH °F 355070100355070100355070100355070100355070100
259.38.67.97.15.95.75.55.211.510.910.29.39.28.68.07.38.38.07.77.2
3010.39.58.77.86.56.36.15.712.111.510.89.910.19.58.88.08.98.78.37.7
3511.210.49.58.57.16.96.66.212.712.111.410.510.910.39.58.79.69.38.98.3
4012.111.210.39.27.87.67.36.913.312.712.011.111.711.010.39.410.29.99.58.8
4513.012.011.09.98.68.38.07.513.813.312.611.712.511.811.010.010.910.510.19.4
5013.912.911.810.69.49.18.88.314.413.813.212.313.312.511.710.711.511.210.710.0
5514.813.712.611.310.310.09.79.115.014.413.812.914.113.312.411.312.211.911.410.6
6015.714.513.412.011.511.110.710.115.615.114.413.614.914.013.112.013.012.612.111.3
6516.615.414.212.812.812.411.911.316.315.715.114.315.714.813.812.713.813.412.812.0
7017.616.315.013.614.414.013.512.717.016.515.815.016.615.714.613.414.714.313.712.8
7518.717.316.014.516.416.015.414.517.817.316.715.917.616.515.514.215.815.414.713.8
8019.818.517.015.419.118.617.917.018.818.217.616.918.617.516.415.117.116.616.015.0
8521.219.818.216.522.922.321.620.519.919.418.818.019.818.717.516.118.818.317.616.5
9022.921.419.817.928.928.227.326.121.420.920.319.621.320.118.917.421.320.720.018.8

Equilibrium moisture content of wood

The moisture content of wood below the fiber saturation point is a function of both relative humidity and temperature of surrounding air. The moisture content (M) of wood is defined as:

where m is the mass of the wood (with moisture) and is the oven-dry mass of wood (i.e. no moisture). [3] If the wood is placed in an environment at a particular temperature and relative humidity, its moisture content will generally begin to change in time, until it is finally in equilibrium with its surroundings, and the moisture content no longer changes in time. This moisture content is the EMC of the wood for that temperature and relative humidity.

The Hailwood-Horrobin equation for two hydrates is often used to approximate the relationship between EMC, temperature (T), and relative humidity (h): [4] [5] [6]

where Meq is the equilibrium moisture content (percent), T is the temperature (degrees Fahrenheit), h is the relative humidity (fractional) and:

This equation does not account for the slight variations with wood species, state of mechanical stress, and/or hysteresis. It is an empirical fit to tabulated data provided in the same reference, and closely agrees with the tabulated data. For example, at T=140 deg F, h=0.55, EMC=8.4% from the above equation, while EMC=8.0% from the tabulated data.

Equilibrium moisture content of sands, soils and building materials

Materials such as stones, sand and ceramics are considered 'dry' and have much lower equilibrium moisture content than organic material like wood and leather. [7] typically a fraction of a percent by weight when in equilibrium of air of Relative humidity 10% to 90%. This affects the rate that buildings need to dry out after construction, typical cements starting with 40-60% water content. This is also important for construction materials such as render reinforced with organic materials, as modest changes in content of different types of straw and wood shavings have a significant influence on the overall moisture content [8]

Related Research Articles

Vapor pressure Pressure exterted by a vapor in thermodynamic equilibrium

Vapor pressure or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's evaporation rate. It relates to the tendency of particles to escape from the liquid. A substance with a high vapor pressure at normal temperatures is often referred to as volatile. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the kinetic energy of its molecules also increases. As the kinetic energy of the molecules increases, the number of molecules transitioning into a vapor also increases, thereby increasing the vapor pressure.

Humidity Concentration of water vapour present in the air

Humidity is the concentration of water vapour present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation, dew, or fog to be present.

Dew point Temperature at which air becomes saturated with water vapour

The dew point is the temperature to which air must be cooled to become saturated with water vapor. When cooled further, the airborne water vapor will condense to form liquid water (dew). When air cools to its dew point through contact with a surface that is colder than the air, water will condense on the surface.

Hygrometer Instrument used for measuring the moisture content in the atmosphere

A hygrometer is an instrument used to measure the amount of water vapor in air, in soil, or in confined spaces. Humidity measurement instruments usually rely on measurements of some other quantities such as temperature, pressure, mass, a mechanical or electrical change in a substance as moisture is absorbed. By calibration and calculation, these measured quantities can lead to a measurement of humidity. Modern electronic devices use temperature of condensation, or changes in electrical capacitance or resistance to measure humidity differences. A crude hygrometer was invented by Leonardo da Vinci in 1480. Major leaps came forward during the 1600s; Francesco Folli invented a more practical version of the device, while Robert Hooke improved a number of meteorological devices including the hygrometer. A more modern version was created by Swiss polymath Johann Heinrich Lambert in 1755. Later, in the year 1783, Swiss physicist and Geologist Horace Bénédict de Saussure invented the first hygrometer using human hair to measure humidity.

The density of air or atmospheric density, denoted ρ, is the mass per unit volume of Earth's atmosphere. Air density, like air pressure, decreases with increasing altitude. It also changes with variation in atmospheric pressure, temperature and humidity. At 101.325 kPa (abs) and 15 °C, air has a density of approximately 1.225 kg/m3, about 1/1000 that of water according to ISA.

Evaporative cooler Device that cools air through the evaporation of water

An evaporative cooler is a device that cools air through the evaporation of water. Evaporative cooling differs from other air conditioning systems, which use vapor-compression or absorption refrigeration cycles. Evaporative cooling uses the fact that water will absorb a relatively large amount of heat in order to evaporate. The temperature of dry air can be dropped significantly through the phase transition of liquid water to water vapor (evaporation). This can cool air using much less energy than refrigeration. In extremely dry climates, evaporative cooling of air has the added benefit of conditioning the air with more moisture for the comfort of building occupants.

Psychrometrics

Psychrometrics, psychrometry, and hygrometry are names for the field of engineering concerned with the physical and thermodynamic properties of gas-vapor mixtures. The term comes from the Greek psuchron (ψυχρόν) meaning "cold" and metron (μέτρον) meaning "means of measurement".

Craquelure

Craquelure is a fine pattern of dense cracking formed on the surface of materials. It can be a result of drying, aging, intentional patterning, or a combination of all three. The term is most often used to refer to tempera or oil paintings, but it can also develop in old ivory carvings or painted miniatures on an ivory backing. Recently, analysis of craquelure has been proposed as a way to authenticate art.

In the physical sciences, relaxation usually means the return of a perturbed system into equilibrium. Each relaxation process can be categorized by a relaxation time τ. The simplest theoretical description of relaxation as function of time t is an exponential law exp(-t/τ).

Water content

Water content or moisture content is the quantity of water contained in a material, such as soil, rock, ceramics, crops, or wood. Water content is used in a wide range of scientific and technical areas, and is expressed as a ratio, which can range from 0 to the value of the materials' porosity at saturation. It can be given on a volumetric or mass (gravimetric) basis.

Drying is a mass transfer process consisting of the removal of water or another solvent by evaporation from a solid, semi-solid or liquid. This process is often used as a final production step before selling or packaging products. To be considered "dried", the final product must be solid, in the form of a continuous sheet, long pieces, particles or powder. A source of heat and an agent to remove the vapor produced by the process are often involved. In bioproducts like food, grains, and pharmaceuticals like vaccines, the solvent to be removed is almost invariably water. Desiccation may be synonymous with drying or considered an extreme form of drying.

Wet-bulb temperature Temperature read by a thermometer covered in water-soaked cloth

The wet-bulb temperature (WBT) is the temperature read by a thermometer covered in water-soaked cloth over which air is passed. At 100% relative humidity, the wet-bulb temperature is equal to the air temperature ; at lower humidity the wet-bulb temperature is lower than dry-bulb temperature because of evaporative cooling.

Wood drying Also known as seasoning, which is the reduction of the moisture content of wood prior to its use

Wood drying reduces the moisture content of wood before its use. When the drying is done in a kiln, the product is known as kiln-dried timber or lumber, whereas air drying is the more traditional method.

Lifted condensation level

The lifted condensation level or lifting condensation level (LCL) is formally defined as the height at which the relative humidity (RH) of an air parcel will reach 100% with respect to liquid water when it is cooled by dry adiabatic lifting. The RH of air increases when it is cooled, since the amount of water vapor in the air remains constant, while the saturation vapor pressure decreases almost exponentially with decreasing temperature. If the air parcel is lifting further beyond the LCL, water vapor in the air parcel will begin condensing, forming cloud droplets. The LCL is a good approximation of the height of the cloud base which will be observed on days when air is lifted mechanically from the surface to the cloud base.

Like the Penman equation, the Penman–Monteith equation approximates net evapotranspiration (ET), requiring as input daily mean temperature, wind speed, relative humidity and solar radiation. Other than radiation, these parameter are implicit in the derivation of , , and , if not conductances below.

Volume (thermodynamics)

In thermodynamics, the volume of a system is an important extensive parameter for describing its thermodynamic state. The specific volume, an intensive property, is the system's volume per unit of mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature. For example, volume is related to the pressure and temperature of an ideal gas by the ideal gas law.

Moisture meter

Moisture meters are used to measure the percentage of water in a given substance. This information can be used to determine if the material is ready for use, unexpectedly wet or dry, or otherwise in need of further inspection. Wood and paper products are very sensitive to their moisture content. Physical properties are strongly affected by moisture content and high moisture content for a period of time may progressively degrade a material.

Dynamic vapor sorption (DVS) is a gravimetric technique that measures how quickly and how much of a solvent is absorbed by a sample: such as a dry powder absorbing water. It does this by varying the vapor concentration surrounding the sample and measuring the change in mass which this produces. Water vapor is most commonly used, but it is also possible to use a wide range of organic solvents.

Water activity One of the main factor limiting microbial activity

Water activity (aw) is the partial vapor pressure of water in a solution divided by the standard state partial vapor pressure of water. In the field of food science, the standard state is most often defined as the partial vapor pressure of pure water at the same temperature. Using this particular definition, pure distilled water has a water activity of exactly one. As temperature increases, aw typically increases, except in some products with crystalline salt or sugar.

Grain drying is process of drying grain to prevent spoilage during storage. The grain drying described in this article is that which uses fuel- or electric-powered processes supplementary to natural ones, including swathing/windrowing for drying by ambient air and sunshine.

References

  1. 1 2 Sadakam, Samy Grain Drying Tools: Equilibrium Moisture Content Tables and Psychrometric Charts. Univ. Arkansas, FSA1074
  2. 1 2 FAO. 2011. Rural structures in the tropics. Design and development. Chapter 16: Grain crop drying, handling, and storage. Rome. http://www.fao.org/docrep/015/i2433e/i2433e10.pdf
  3. What is Equilibrium Moisture Content? http://www.wagnermeters.com/wood-moisture-meter/moisture-content-and-equilibrium-determined-by-relative-humidity/
  4. Hailwood, A.J.; S. Horrobin (1946). "Absorption of water by polymers: analysis in terms of a simple model". Trans. Faraday Soc. 42B: 84–102.
  5. Rasmussen, E.F. (1988). Forest Products Laboratory, U.S. Department of Agriculture. (ed.). Dry Kiln Operators Manual. Hardwood Research Council.
  6. Eleotério, Jackson Roberto; Clóvis Roberto Haselein; Nestor Pedro Giacomini. "A Program to Estimate the Equilibrium Moisture Content of Wood" (PDF). Ciência Florestal. 8 (1): 13–22. ISSN   0103-9954 . Retrieved 2008-11-14.
  7. Leivo, Virpi & Rantala, Jukka. (2003). Moisture Behavior of Slab-On-Ground Structures
  8. An experimental investigation on equilibrium moisture content of earth plasters with natural reinforcement fibres for straw bale buildings Taha Ashour, Heiko Georg, Wei Wu

Bibliography