Eskolaite

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Eskolaite
Eskolaite.jpg
Eskolaite from Russia
General
Category Oxide mineral
Formula
(repeating unit)
Cr2O3
IMA symbol Esk [1]
Strunz classification 4.CB.05
Crystal system Trigonal
Crystal class Hexagonal scalenohedral (3 m)
H-M symbol: (3 2/m)
Space group R3c, No. 167
Unit cell a = 4.95, c = 13.58 [Å]; Z = 6
Identification
ColorBlack to dark green
Crystal habit Hexagonal prisms and plates
Cleavage None
Tenacity Brittle
Mohs scale hardness8 – 8.5
Luster Vitreous or metallic
Streak Pale green
Diaphaneity Opaque, translucent in thin edges
Specific gravity 5.18
Density Measured: 5.18 g/cm3, Calculated: 5.20 g/cm3
Optical propertiesUniaxial
Pleochroism Noted; emerald-green to olive-green
References [2] [3] [4]

Eskolaite is a rare chromium oxide mineral (chromium(III) oxide Cr2O3).

Contents

Discovery and occurrence

It was first described in 1958 for an occurrence in the Outokumpu ore deposit of eastern Finland. [3] It occurs in chromium bearing tremolite skarns, metamorphosed quartzites and chlorite bearing veins in Finland; in glacial boulder clays in Ireland and in stream pebbles in the Merume River of Guyana. [2] It has also been recognized as a rare component in chondrite meteorites. [2]

The mineral is named after the Finnish geologist Pentti Eskola (1883–1964).

Structure and physical properties

Molar volume vs. pressure at room temperature. Eskolaite-pV.svg
Molar volume vs. pressure at room temperature.

Eskolaite crystallizes with trigonal symmetry in the space group R3c and has the lattice parameters a = 4.95 Å and c = 13.58 Å at standard conditions. The unit cell contains six formula units. The lattice is analogous to that of corundum, with Cr3+ replacing Al3+.

See also

Related Research Articles

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Corundum is a crystalline form of aluminium oxide typically containing traces of iron, titanium, vanadium, and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. Corundum has two primary gem varieties: ruby and sapphire. Rubies are red due to the presence of chromium, and sapphires exhibit a range of colors depending on what transition metal is present. A rare type of sapphire, padparadscha sapphire, is pink-orange.

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<span class="mw-page-title-main">Chromite</span> Crystalline mineral

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<span class="mw-page-title-main">Uvarovite</span> Chromium-bearing garnet group

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<span class="mw-page-title-main">Torbernite</span> Copper uranyl phosphate mineral

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1-x
(Mn,Mg,Al)
6
O
12
·3-4H
2
O
. It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 – 3.82. It is a component of deep ocean basin manganese nodules.

<span class="mw-page-title-main">Chromium(III) oxide</span> Chemical compound

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2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

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<span class="mw-page-title-main">Johannite</span>

Johannite is a rare uranium sulfate mineral. It crystallizes in the triclinic crystal system with the chemical composition Cu[UO2(OH)SO4]2·8H2O. It crystallizes in the triclinic system and develops only small prism or thin to thick tabular crystals, usually occurs as flaky or spheroidal aggregates and efflorescent coatings. Its color is emerald-green to apple-green and its streak is pale green.

<span class="mw-page-title-main">Plumbogummite</span> Alunite supergroup, phosphate mineral

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<span class="mw-page-title-main">Tsumebite</span>

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References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Eskolaite in the Handbook of Mineralogy
  3. 1 2 Eskolaite on Mindat.org
  4. Eskolaite data on Webmineral.com