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Flexoelectricity is a property of a dielectric material where there is coupling between electrical polarization and a strain gradient. Flexoelectricity is closely related to piezoelectricity, but while piezoelectricity refers to polarization due to uniform strain, flexoelectricity refers specifically to polarization due to strain that changes from point to point in the material. This nonuniform strain breaks centrosymmetry, meaning that unlike in piezoelectricity, flexoelectric effects occur in both centrosymmetric and asymmetric crystal structures. [1] Flexoelectricity is not the same as Ferroelasticity. Flexoelectricity plays a critical role in explaining many interesting electromechanical behaviors in hard crystalline materials and core mechanoelectric transduction phenomena in soft biomaterials. [2] Most excitingly, flexoelectricity is a size-dependent effect that becomes more significant in nanoscale systems, such as crack tips. [3]
In common useage flexoelectricity is the generation of polarization due to a strain gradient; inverse flexoectricity is when polarization, often due to an applied electric field, generates a strain gradient. Converse flexoelectricity is where a polarization gradient induces strain in a material. [4]
The electric polarization due to mechanical strain of in a dielectric is given by
where the first term corresponds to the direct piezoelectric effect and the second term corresponds to the flexoelectric polarization induced by the strain gradient.
Here, the flexoelectric coefficient, , is a fourth-rank polar tensor and is the coefficient corresponding to the direct piezoelectric effect.
The Fresnel equations describe the reflection and transmission of light when incident on an interface between different optical media. They were deduced by French engineer and physicist Augustin-Jean Fresnel who was the first to understand that light is a transverse wave, when no one realized that the waves were electric and magnetic fields. For the first time, polarization could be understood quantitatively, as Fresnel's equations correctly predicted the differing behaviour of waves of the s and p polarizations incident upon a material interface.
Piezoelectricity is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure and latent heat. It is derived from Ancient Greek πιέζω (piézō) 'to squeeze or press' and ἤλεκτρον (ḗlektron) 'amber'. The German form of the word (Piezoelektricität) was coined in 1881 by the German physicist Wilhelm Gottlieb Hankel; the English word was coined in 1883.
Capacitance is the capacity of a material object or device to store electric charge. It is measured by the charge in response to a difference in electric potential, expressed as the ratio of those quantities. Commonly recognized are two closely related notions of capacitance: self capacitance and mutual capacitance. An object that can be electrically charged exhibits self capacitance, for which the electric potential is measured between the object and ground. Mutual capacitance is measured between two components, and is particularly important in the operation of the capacitor, an elementary linear electronic component designed to add capacitance to an electric circuit.
Linear elasticity is a mathematical model of how solid objects deform and become internally stressed by prescribed loading conditions. It is a simplification of the more general nonlinear theory of elasticity and a branch of continuum mechanics.
A Newtonian fluid is a fluid in which the viscous stresses arising from its flow are at every point linearly correlated to the local strain rate — the rate of change of its deformation over time. Stresses are proportional to the rate of change of the fluid's velocity vector.
In electromagnetism, displacement current density is the quantity ∂D/∂t appearing in Maxwell's equations that is defined in terms of the rate of change of D, the electric displacement field. Displacement current density has the same units as electric current density, and it is a source of the magnetic field just as actual current is. However it is not an electric current of moving charges, but a time-varying electric field. In physical materials, there is also a contribution from the slight motion of charges bound in atoms, called dielectric polarization.
A metamaterial is a type of material engineered to have a property, typically rarely observed in naturally occurring materials, that is derived not from the properties of the base materials but from their newly designed structures. Metamaterials are usually fashioned from multiple materials, such as metals and plastics, and are usually arranged in repeating patterns, at scales that are smaller than the wavelengths of the phenomena they influence. Their precise shape, geometry, size, orientation, and arrangement give them their "smart" properties of manipulating electromagnetic, acoustic, or even seismic waves: by blocking, absorbing, enhancing, or bending waves, to achieve benefits that go beyond what is possible with conventional materials.
In physics and engineering, a constitutive equation or constitutive relation is a relation between two or more physical quantities that is specific to a material or substance or field, and approximates its response to external stimuli, usually as applied fields or forces. They are combined with other equations governing physical laws to solve physical problems; for example in fluid mechanics the flow of a fluid in a pipe, in solid state physics the response of a crystal to an electric field, or in structural analysis, the connection between applied stresses or loads to strains or deformations.
In physics, the electric displacement field or electric induction is a vector field that appears in Maxwell's equations. It accounts for the electromagnetic effects of polarization and that of an electric field, combining the two in an auxiliary field. It plays a major role in topics such as the capacitance of a material, as well as the response of dielectrics to an electric field, and how shapes can change due to electric fields in piezoelectricity or flexoelectricity as well as the creation of voltages and charge transfer due to elastic strains.
In electromagnetism, electrostriction is a property of all electrical non-conductor or dielectrics. Electrostriction causes these materials to change their shape under the application of an electric field. It is the dual property to magnetostriction.
In optics, negative refraction is the electromagnetic phenomenon where light rays become refracted at an interface that is opposite to their more commonly observed positive refractive properties. Negative refraction can be obtained by using a metamaterial which has been designed to achieve a negative value for electric permittivity and magnetic permeability ; in such cases the material can be assigned a negative refractive index. Such materials are sometimes called "double negative" materials.
Elastic energy is the mechanical potential energy stored in the configuration of a material or physical system as it is subjected to elastic deformation by work performed upon it. Elastic energy occurs when objects are impermanently compressed, stretched or generally deformed in any manner. Elasticity theory primarily develops formalisms for the mechanics of solid bodies and materials. The elastic potential energy equation is used in calculations of positions of mechanical equilibrium. The energy is potential as it will be converted into other forms of energy, such as kinetic energy and sound energy, when the object is allowed to return to its original shape (reformation) by its elasticity.
The Franz–Keldysh effect is a change in optical absorption by a semiconductor when an electric field is applied. The effect is named after the German physicist Walter Franz and Russian physicist Leonid Keldysh.
Volume viscosity is a material property relevant for characterizing fluid flow. Common symbols are or . It has dimensions, and the corresponding SI unit is the pascal-second (Pa·s).
In continuum mechanics, a compatible deformation tensor field in a body is that unique tensor field that is obtained when the body is subjected to a continuous, single-valued, displacement field. Compatibility is the study of the conditions under which such a displacement field can be guaranteed. Compatibility conditions are particular cases of integrability conditions and were first derived for linear elasticity by Barré de Saint-Venant in 1864 and proved rigorously by Beltrami in 1886.
In its most general form, the magnetoelectric effect (ME) denotes any coupling between the magnetic and the electric properties of a material. The first example of such an effect was described by Wilhelm Röntgen in 1888, who found that a dielectric material moving through an electric field would become magnetized. A material where such a coupling is intrinsically present is called a magnetoelectric.
The spin angular momentum of light (SAM) is the component of angular momentum of light that is associated with the quantum spin and the rotation between the polarization degrees of freedom of the photon.
The acoustoelastic effect is how the sound velocities of an elastic material change if subjected to an initial static stress field. This is a non-linear effect of the constitutive relation between mechanical stress and finite strain in a material of continuous mass. In classical linear elasticity theory small deformations of most elastic materials can be described by a linear relation between the applied stress and the resulting strain. This relationship is commonly known as the generalised Hooke's law. The linear elastic theory involves second order elastic constants and yields constant longitudinal and shear sound velocities in an elastic material, not affected by an applied stress. The acoustoelastic effect on the other hand include higher order expansion of the constitutive relation between the applied stress and resulting strain, which yields longitudinal and shear sound velocities dependent of the stress state of the material. In the limit of an unstressed material the sound velocities of the linear elastic theory are reproduced.
In continuum mechanics an eigenstrain is any mechanical deformation in a material that is not caused by an external mechanical stress, with thermal expansion often given as a familiar example. The term was coined in the 1970s by Toshio Mura, who worked extensively on generalizing their mathematical treatment. A non-uniform distribution of eigenstrains in a material leads to corresponding eigenstresses, which affect the mechanical properties of the material.
JCMsuite is a finite element analysis software package for the simulation and analysis of electromagnetic waves, elasticity and heat conduction. It also allows a mutual coupling between its optical, heat conduction and continuum mechanics solvers. The software is mainly applied for the analysis and optimization of nanooptical and microoptical systems. Its applications in research and development projects include dimensional metrology systems, photolithographic systems, photonic crystal fibers, VCSELs, Quantum-Dot emitters, light trapping in solar cells, and plasmonic systems. The design tasks can be embedded into the high-level scripting languages MATLAB and Python, enabling a scripting of design setups in order to define parameter dependent problems or to run parameter scans.
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