Garronite-Ca

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Garronite-Ca
3 Garronita-Ca 1.tif
Garronite-Ca. Group of crystals in oriented growth. Quarry of Barranc Salat, Calpe (Alicante) Spain. Group height 11 mm.
General
Category silicate mineralsZeolite group
Formula
(repeating unit)
Na2Ca5Al12Si20O64·27H2O
IMA symbol Grn-Ca [1]
Crystal system Tetragonal
Crystal class 32m
Identification
ColorWhite
Crystal habit Typically rhombohedral crystals saddle-shaped, twisted
Cleavage ]
Mohs scale hardness4-5
Luster Vitreous
Streak White
Diaphaneity Translucent
Specific gravity 2,2
References [2] [3]

Garronite-Ca is a fairly rare silicate mineral, from the zeolite, which has been found in a few dozen locations in the world. It was first found in the Glenariff Valley, Garron Plateau, County Antrim, Northern Ireland, and in some locations in Iceland. The name comes from the town of Garron, in Northern Ireland, which is consequently considered its type locality. [4] The name initially used was that of Garronite, without subfixes, but the discovery in 2015 of a garronite with dominant sodium instead of calcium in the position of interchangeable cations made it necessary to use subfixes, remaining as Garronite-Ca, to distinguish it from the new species, Garronite-Na. [5]

Contents

Physical and chemical properties

Garronite-Ca is generally found as masses and nodules with a finely fibrous internal structure, white in color, usually showing a concentric growth structure. This causes the nodules to present with a conchoidal fracture. It is very rare as defined crystals. When crystals appear, they usually show the faces corresponding to {101} and {011}. [6]

Localities

Garronite-Ca is formed under hydrothermal conditions at low temperature. It is a rare zeolite, and very rare in the form of defined crystals. As fibrous masses, filling vacuoles in basalts, it has been found in the county of Antrim, in Northern Ireland (United Kingdom), and in the area of Fáskrúðsfjörður (Iceland). [4] It is usually associated with phillipsite, which is located in the outer area of the nodules. As crystals, associated with calcite and analcime, it has been found in San Giorgio di Perlena, Fara Vicentino, Vicenza (Italy) [7] and in Barranc Salat, Calpe, Alicante (Spain). [8]

Related Research Articles

<span class="mw-page-title-main">Analcime</span> Tectosilicate mineral

Analcime (; from Ancient Greek ἀνάλκιμος (análkimos) 'not strong') or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is NaAlSi2O6 · H2O. Minor amounts of potassium and calcium substitute for sodium. A silver-bearing synthetic variety also exists (Ag-analcite). Analcime is usually classified as a zeolite mineral, but structurally and chemically it is more similar to the feldspathoids. Analcime is not classified as an isometric crystal, as although the crystal structure appears to be isometric, it is usually off only by a fraction of an angle. However, there are truly isometric samples of the mineral, which makes its classification even more difficult. Due to the differences between the samples being too slight, there's no merit from having multiple species names, so as a result analcime is a common example for minerals occurring in multiple crystal systems and space groups. It was first described by French geologist Déodat de Dolomieu, who called it zéolithe dure, meaning hard zeolite. It was found in lava in Cyclops, Italy. The mineral is IMA approved, and had been grandfathered, meaning the name analcime is believed to refer to a valid species til this day.

<span class="mw-page-title-main">Chabazite</span> Tectosilicate mineral of the zeolite group

Chabazite is a tectosilicate mineral of the zeolite group, closely related to gmelinite, with the chemical formula (Ca,K
2
,Na
2
,Mg)Al
2
Si
4
O
12
•6H
2
O
. Recognized varieties include Chabazite-Ca, Chabazite-K, Chabazite-Na, and Chabazite-Sr, depending on the prominence of the indicated cation.

<span class="mw-page-title-main">Wardite</span>

Wardite is a hydrous sodium aluminium phosphate hydroxide mineral with formula: NaAl3(PO4)2(OH)4·2(H2O). Wardite is of interest for its rare crystallography. It crystallizes in the tetragonal trapezohedral class and is one of only a few minerals in that class. Wardite forms vitreous green to bluish green to white to colorless crystals, with pyramidal {102} or {114} faces and with {001} usually present masses. Also appera as fibrous encrustations. It has a Mohs hardness of 5 and a specific gravity of 2.81–2.87.

<span class="mw-page-title-main">Natrolite</span> Zeolite mineral

Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula Na2Al2Si3O10·2H2O. The type locality is Hohentwiel, Hegau, Germany.

<span class="mw-page-title-main">Datolite</span> Nesosilicate mineral

Datolite is a calcium boron hydroxide nesosilicate, CaBSiO4(OH). It was first observed by Jens Esmark in 1806, and named by him from δατεῖσθαι, "to divide," and λίθος, "stone," in allusion to the granular structure of the massive mineral.

<span class="mw-page-title-main">Pectolite</span> Silicate mineral

Pectolite is a white to gray mineral, NaCa2Si3O8(OH), sodium calcium hydroxide inosilicate. It crystallizes in the triclinic system typically occurring in radiated or fibrous crystalline masses. It has a Mohs hardness of 4.5 to 5 and a specific gravity of 2.7 to 2.9. The gemstone variety, larimar, is a pale to sky blue. There is also a whitish form of the mineral from Alaska that is sometimes marketed as 'Alaska jade'.

<span class="mw-page-title-main">Heulandite</span>

Heulandite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, heulandite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:

<span class="mw-page-title-main">Mordenite</span>

Mordenite is a zeolite mineral with the chemical formula, (Ca, Na2, K2)Al2Si10O24·7H2O. and it is one of the six most abundant zeolites and is used commercially.

<span class="mw-page-title-main">Gmelinite</span> Zeolite mineral

Gmelinite-Na is one of the rarer zeolites but the most common member of the gmelinite series, gmelinite-Ca, gmelinite-K and gmelinite-Na. It is closely related to the very similar mineral chabazite. Gmelinite was named as a single species in 1825 after Christian Gottlob Gmelin (1792–1860) professor of chemistry and mineralogist from Tübingen, Germany, and in 1997 it was raised to the status of a series.
Gmelinite-Na has been synthesised from Na-bearing aluminosilicate gels. The naturally occurring mineral forms striking crystals, shallow, six sided double pyramids, which can be colorless, white, pale yellow, greenish, orange, pink, and red. They have been compared to an angular flying saucer.

<span class="mw-page-title-main">Cavansite</span> Phyllosilicate mineral

Cavansite, named for its chemical composition of calcium vanadium silicate, is a deep blue hydrous calcium vanadium phyllosilicate mineral, occurring as a secondary mineral in basaltic and andesitic rocks along with a variety of zeolite minerals. Its blue coloring comes from vanadium, a metal ion. Discovered in 1967 in Malheur County, Oregon, cavansite is a relatively rare mineral. It is polymorphic with the even rarer mineral, pentagonite. It is most frequently found in Pune, India, and in the Deccan Traps, a large igneous province.

<span class="mw-page-title-main">Celadonite</span>

Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula K(Mg,Fe2+
)(Fe3+
,Al)[Si
4
O
10
](OH)
2
.

<span class="mw-page-title-main">Thomsonite</span> Thomsonite series of the zeolite group

Thomsonite is the name of a series of tecto-silicate minerals of the zeolite group. Prior to 1997, thomsonite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named thomsonite-Ca and thomsonite-Sr. Thomsonite-Ca, by far the more common of the two, is a hydrous sodium, calcium and aluminium silicate, NaCa2Al5Si5O20·6H2O. Strontium can substitute for the calcium and the appropriate species name depends on the dominant element. The species are visually indistinguishable and the series name thomsonite is used whenever testing has not been performed. Globally, thomsonite is one of the rarer zeolites.

<span class="mw-page-title-main">Mesolite</span> Zeolite mineral

Mesolite is a tectosilicate mineral with formula Na2Ca2(Al2Si3O10)3·8H2O. It is a member of the zeolite group and is closely related to natrolite which it also resembles in appearance.

<span class="mw-page-title-main">Pollucite</span> Zeolite mineral

Pollucite is a zeolite mineral with the formula (Cs,Na)2Al2Si4O12·2H2O with iron, calcium, rubidium and potassium as common substituting elements. It is important as a significant ore of caesium and sometimes rubidium. It forms a solid solution series with analcime. It crystallizes in the isometric-hexoctahedral crystal system as colorless, white, gray, or rarely pink and blue masses. Well-formed crystals are rare. It has a Mohs hardness of 6.5 and a specific gravity of 2.9. It has a brittle fracture and no cleavage.

<span class="mw-page-title-main">Brewsterite</span> Series of tectosilicate minerals

Brewsterite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, brewsterite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named brewsterite-Sr and brewsterite-Ba. Brewsterite-Sr, the more common of these, is a hydrous strontium and aluminium silicate, (Sr,Ba)2Al4Si12O32·10H2O. Small amounts of barium is usually present replacing part of the strontium. The appropriate species name depends on the dominant element. The species are visually indistinguishable, and the series name brewsterite is still used whenever testing has not been performed.

<span class="mw-page-title-main">Portlandite</span> Calcium hydroxide mineral

Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).

<span class="mw-page-title-main">Thaumasite</span> Complex calcium silicate hydrate mineral

Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3Si(OH)6(CO3)(SO4)·12H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O.

Paulingite or paulingite-K is a rare zeolite mineral that is found in vesicles in the basaltic rocks from the Columbia River near Rock Island Dam, Washington.

<span class="mw-page-title-main">Okenite</span>

Okenite (CaSi2O5·2H2O) is a silicate mineral that is usually associated with zeolites. It most commonly is found as small white "cotton ball" formations within basalt geodes. These formations are clusters of straight, radiating, fibrous crystals that are both bendable and fragile. It also belongs to the family of the calcium silicate hydrates (C-S-H) commonly found in hardened cement paste. In cement chemist notation (CCN) it is noted as CaO·2SiO2·2H2O and abbreviated as CS2H2.

Zeolites are found in several locations in southern and central Idaho.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. https://www.mindat.org/min-1653.html Mindat
  3. http://webmineral.com/Alphabetical_Listing.shtml#.XXPC20dS9zk Webmineral
  4. 1 2 Walker, G. P. L (1962). "Garronite, a new zeolite, from Ireland and Iceland". Mineralogical Magazine. 33 (258): 173–186. Bibcode:1962MinM...33..173W. doi:10.1180/minmag.1962.033.258.01.
  5. Grice, J.D., Rowe, R. y Poirier, G. (2016). "Garronite-Na, a new zeolite species from Mont Saint-Hilaire, Quebec". The Canadian Mineralogist. 54 (6): 1549–1562. doi:10.3749/canmin.1600018.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  6. Tschernich, Rudy W. (1992). Zeolites of the World. Arizona, USA: Geoscience Press Inc. pp. 181–187.
  7. Howard, D.G. "Crystal habit and twinning of garronite from Fara Vicentina, Vicenza (Italy)". Neues Jahrbuch für Mineralogie - Monatshefte. 2: 91–96.
  8. Calvo, Miguel (2019). "Garronite-Ca, analcime, and phillipsite-ca in the Barranc Salat ophite quarry, Calpe, Alicante, Spain". Mineral up. 5 (3): 70–71.