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H3 is a pyrotechnic composition which is used mostly as a burst charge for small diameter shells. It is friction and shock sensitive, as are most compositions containing chlorates. For this reason, H3 should be mixed using the "diaper method" and not with a ball mill. The composition consists of:
Due to the potassium chlorate, H3 should not be mixed with sulfur or compositions containing sulfur, as sulfur increases the sensitivity of the mixture.
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2,4,6-Trinitrophenylmethylnitramine commonly referred to as tetryl (C7H5N5O8) is an explosive compound used to make detonators and explosive booster charges.
A match is a tool for starting a fire. Typically, matches are made of small wooden sticks or stiff paper. One end is coated with a material that can be ignited by frictional heat generated by striking the match against a suitable surface. Wooden matches are packaged in matchboxes, and paper matches are partially cut into rows and stapled into matchbooks. The coated end of a match, known as the match "head", consists of a bead of active ingredients and binder; often colored for easier inspection. There are two main types of matches: safety matches, which can be struck only against a specially prepared surface, and strike-anywhere matches, for which any suitably frictional surface can be used.
Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. It is the most common chlorate in industrial use. It is used,
Manganese(IV) oxide is the inorganic compound with the formula MnO
2. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO
2 is for dry-cell batteries, such as the alkaline battery and the zinc-carbon battery. MnO
2 is also used as a pigment and as a precursor to other manganese compounds, such as KMnO
4. It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. MnO
2 in the α polymorph can incorporate a variety of atoms in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in α-MnO
2 as a possible cathode for lithium ion batteries.
The chlorate anion has the formula ClO−
3. In this case, the chlorine atom is in the +5 oxidation state. "Chlorate" can also refer to chemical compounds containing this anion; chlorates are the salts of chloric acid. "Chlorate", when followed by a Roman numeral in parentheses, e.g. chlorate (VII), refers to a particular oxyanion of chlorine.
Potassium perchlorate is the inorganic salt with the chemical formula KClO4. Like other perchlorates, this salt is a strong oxidizer although it usually reacts very slowly with organic substances. This, usually obtained as a colorless, crystalline solid, is a common oxidizer used in fireworks, ammunition percussion caps, explosive primers, and is used variously in propellants, flash compositions, stars, and sparklers. It has been used as a solid rocket propellant, although in that application it has mostly been replaced by the higher performance ammonium perchlorate. KClO4 has the lowest solubility of the alkali metal perchlorates (1.5 g in 100 mL of water at 25 °C).
Silver fulminate (AgCNO) is the highly explosive silver salt of fulminic acid.
Flash powder is a pyrotechnic composition, a mixture of oxidizer and metallic fuel, which burns quickly and if confined produces a loud noise. It is widely used in theatrical pyrotechnics and fireworks and was once used for flashes in photography.
Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leave sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching pulp to produce high brightness paper.
Armstrong's mixture is a highly sensitive primary explosive. Its primary ingredients are red phosphorus and strong oxidizer, such as potassium chlorate and potassium perchlorate. Sulfur is used to substitute for some or all of the phosphorus to slightly decrease sensitivity and lower costs; calcium carbonate may also be present in small proportions. Commercially, Armstrong's mixture is used in milligram quantities on the paper caps in toy cap guns and in party poppers. An improvised version can be made with match-heads, ground up into a fine powder, and mixed with another fine powder, this time made of the striker strip found on the side of match boxes.
Ammonium chlorate is an inorganic compound with the formula NH4ClO3.
The iodine clock reaction is a classical chemical clock demonstration experiment to display chemical kinetics in action; it was discovered by Hans Heinrich Landolt in 1886. The iodine clock reaction exists in several variations, which each involve iodine species and redox reagents in the presence of starch. Two colourless solutions are mixed and at first there is no visible reaction. After a short time delay, the liquid suddenly turns to a shade of dark blue due to the formation of a triiodide-starch complex. In some variations, the solution will repeatedly cycle from colorless to blue and back to colorless, until the reagents are depleted.
In chemical nomenclature, the IUPAC nomenclature of inorganic chemistry is a systematic method of naming inorganic chemical compounds, as recommended by the International Union of Pure and Applied Chemistry (IUPAC). It is published in Nomenclature of Inorganic Chemistry. Ideally, every inorganic compound should have a name from which an unambiguous formula can be determined. There is also an IUPAC nomenclature of organic chemistry.
Phosphorus sesquisulfide is the inorganic compound with the formula P4S3. It was developed by Henri Sevene and Emile David Cahen in 1898 as part of their invention of friction matches that did not pose the health hazards of white phosphorus. This yellow solid is one of two commercially produced phosphorus sulfides. It is a component of "strike anywhere" matches.
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction.
Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO3)2. Like other chlorates, it is a strong oxidizer.
Oxygen balance is an expression that is used to indicate the degree to which an explosive can be oxidized. If an explosive molecule contains just enough oxygen to form carbon dioxide from carbon, water from hydrogen atoms, all of its sulfur dioxide from sulfur, and all metal oxides from metals with no excess, the molecule is said to have a zero oxygen balance. The molecule is said to have a positive oxygen balance if it contains more oxygen than is needed and a negative oxygen balance if it contains less oxygen than is needed; the combustion will then be incomplete, and large amount of toxic gases like carbon monoxide will be present. The sensitivity, strength, and brisance of an explosive are all somewhat dependent upon oxygen balance and tend to approach their maxima as oxygen balance approaches zero.
Barium chlorate, Ba(ClO3)2, is a white crystalline solid, the barium salt of chloric acid. It is an irritant and toxic, as are all soluble barium compounds. It is sometimes used in pyrotechnics to produce a green color. It also finds use in the production of chloric acid.
Lithium chlorate is the inorganic chemical compound with the formula LiClO3. Like all chlorates, it is an oxidizer and may become unstable and possibly explosive if mixed with organic materials, reactive metal powders, or sulfur.
Barium perchlorate is a powerful oxidizing agent, with the formula Ba(ClO4)2. It is used in the pyrotechnic industry.