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In fluid thermodynamics, a heat transfer fluid (HTF) is a gas or liquid that takes part in heat transfer by serving as an intermediary in cooling on one side of a process, transporting and storing thermal energy, and heating on another side of a process. Heat transfer fluids are used in countless applications and industrial processes requiring heating or cooling, typically in a closed circuit and in continuous cycles. Cooling water, for instance, cools an engine, while heating water in a hydronic heating system heats the radiator in a room.
Water is the most common heat transfer fluid because of its economy, high heat capacity and favorable transport properties. However, the useful temperature range is restricted by freezing below 0 °C and boiling at elevated temperatures depending on the system pressure. Antifreeze additives can alleviate the freezing problem to some extent. However, many other heat transfer fluids have been developed and used in a huge variety of applications. For higher temperatures, oil or synthetic hydrocarbon- or silicone-based fluids offer lower vapor pressure. Molten salts and molten metals can be used for transferring and storing heat at temperatures above 300 to 400 °C where organic fluids start to decompose. Gases such as water vapor, nitrogen, argon, helium and hydrogen have been used as heat transfer fluids where liquids are not suitable. For gases the pressure typically needs to be elevated to facilitate higher flow rates with low pumping power.
In order to prevent overheating, fluid flows inside a system or a device so as to transfer the heat outside that particular device or system.
They generally have a high boiling point and a high heat capacity. High boiling point prevents the heat transfer liquids from vaporising at high temperatures. High heat capacity enables a small amount of the refrigerant to transfer a large amount of heat very efficiently.
It must be ensured that the heat transfer liquids used should not have a low boiling point. This is because a low boiling point will result in vaporisation of the liquid at low temperatures when they are used to exchange heat with hot substances. This will produce vapors of the liquid in the machine itself where they are used.
Also, the heat transfer fluids should have high heat capacity. The heat capacity denotes the amount of heat the fluid can hold without changing its temperature. In case of liquids, it also shows the amount of heat the liquid can hold before its temperature reaches its boiling point and ultimately vaporises.
If the fluid has low heat capacity, then it will mean that a large amount of the fluid will be required to exchange a relatively small amount of heat. This will increase the cost of using heat transfer fluids and will reduce the efficiency of the process.
In case of liquid heat transfer fluids, usage of their small quantity will result in their vaporisation which can be dangerous for the equipment where they are used. The equipment will be designed for liquids but their vaporisation will include vapors in the flow channel. Also gases occupy larger volume than liquids at the same pressure. The production of vapors will increase the pressure on the walls of the pipe/channel where it will be flowing. This may cause the flow channel to rupture.
Heat transfer fluids have distinct thermal and chemical properties which determine their suitability for various industrial applications. Key characteristics include:
Heat transfer fluids are integral to various industrial applications, enabling precise temperature control in manufacturing processes. In the food industry, they are vital for processing meats and snacks. Chemical processes often rely on them for batch reactors and continuous operations. The plastics, rubber, and composites sectors use heat transfer fluids in molding and extrusion processes. They are also critical in petrochemical synthesis and distillation, oil and gas refining, and for converting materials in presses and laminating operations. [3]
In solar power plants, heat transfer fluids are used in concentrators like linear Fresnel and parabolic trough systems for efficient energy generation and thermal storage. Molten salts and synthetic heat transfer fluids are utilized based on their ability to function at various temperature ranges, contributing to the generation of electricity and the manufacturing of polysilicon for photovoltaic cells. These fluids assist in the purification and cooling steps of polysilicon production, essential for creating high-purity silicon for solar and electronic applications. [4] Technico-economic analyses are usually performed to select the appropriate heat transfer fluid. [5] Regarding the selection of a low-cost or cost-effective thermal oil, it is important to consider not only the acquisition or purchase cost, but also the operating and replacement costs. [5] An oil that is initially more expensive may prove to be more cost-effective in the long run if it offers higher thermal stability, thereby reducing the frequency of replacement. [5]
The choice of a heat transfer fluid is critical for system efficiency and longevity. Here are some commonly used fluids:
In physics, cryogenics is the production and behaviour of materials at very low temperatures.
Convection is single or multiphase fluid flow that occurs spontaneously through the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity. When the cause of the convection is unspecified, convection due to the effects of thermal expansion and buoyancy can be assumed. Convection may also take place in soft solids or mixtures where particles can flow.
A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contact. They are widely used in space heating, refrigeration, air conditioning, power stations, chemical plants, petrochemical plants, petroleum refineries, natural-gas processing, and sewage treatment. The classic example of a heat exchanger is found in an internal combustion engine in which a circulating fluid known as engine coolant flows through radiator coils and air flows past the coils, which cools the coolant and heats the incoming air. Another example is the heat sink, which is a passive heat exchanger that transfers the heat generated by an electronic or a mechanical device to a fluid medium, often air or a liquid coolant.
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species, either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system.
Solar thermal energy (STE) is a form of energy and a technology for harnessing solar energy to generate thermal energy for use in industry, and in the residential and commercial sectors. Solar thermal collectors are classified by the United States Energy Information Administration as low-, medium-, or high-temperature collectors. Low-temperature collectors are generally unglazed and used to heat swimming pools or to heat ventilation air. Medium-temperature collectors are also usually flat plates but are used for heating water or air for residential and commercial use.
A heat pipe is a heat-transfer device that employs phase transition to transfer heat between two solid interfaces.
An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, allowing higher coolant temperature. However, all common antifreeze additives also have lower heat capacities than water, and do reduce water's ability to act as a coolant when added to it.
Internal combustion engine cooling uses either air or liquid to remove the waste heat from an internal combustion engine. For small or special purpose engines, cooling using air from the atmosphere makes for a lightweight and relatively simple system. Watercraft can use water directly from the surrounding environment to cool their engines. For water-cooled engines on aircraft and surface vehicles, waste heat is transferred from a closed loop of water pumped through the engine to the surrounding atmosphere by a radiator.
A solar thermal collector collects heat by absorbing sunlight. The term "solar collector" commonly refers to a device for solar hot water heating, but may refer to large power generating installations such as solar parabolic troughs and solar towers or non-water heating devices such as solar cookers or solar air heaters.
Jatropha is a genus of flowering plants in the spurge family, Euphorbiaceae. The name is derived from the Greek words ἰατρός (iatros), meaning "physician", and τροφή (trophe), meaning "nutrition", hence the common name physic nut. Another common name is nettlespurge. It contains approximately 170 species of succulent plants, shrubs and trees. Most of these are native to the Americas, with 66 species found in the Old World. Plants produce separate male and female flowers. As with many members of the family Euphorbiaceae, Jatropha contains compounds that are highly toxic. Jatropha species have traditionally been used in basketmaking, tanning and dye production. In the 2000s, one species, Jatropha curcas, generated interest as an oil crop for biodiesel production and also medicinal importance when used as lamp oil; native Mexicans in the Veracruz area developed by selective breeding a Jatropha curcas variant lacking the toxic compounds, yielding a better income when used as source for biodiesel, because of its edible byproduct. Toxicity may return if edible Jatropha is pollinated by toxic types.
A phase-change material (PCM) is a substance which releases/absorbs sufficient energy at phase transition to provide useful heat or cooling. Generally the transition will be from one of the first two fundamental states of matter - solid and liquid - to the other. The phase transition may also be between non-classical states of matter, such as the conformity of crystals, where the material goes from conforming to one crystalline structure to conforming to another, which may be a higher or lower energy state.
A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosion of the cooling system. Some applications also require the coolant to be an electrical insulator.
A shell-and-tube heat exchanger is a class of heat exchanger designs. It is the most common type of heat exchanger in oil refineries and other large chemical processes, and is suited for higher-pressure applications. As its name implies, this type of heat exchanger consists of a shell with a bundle of tubes inside it. One fluid runs through the tubes, and another fluid flows over the tubes to transfer heat between the two fluids. The set of tubes is called a tube bundle, and may be composed of several types of tubes: plain, longitudinally finned, etc.
Thermal energy storage (TES) is the storage of thermal energy for later reuse. Employing widely different technologies, it allows surplus thermal energy to be stored for hours, days, or months. Scale both of storage and use vary from small to large – from individual processes to district, town, or region. Usage examples are the balancing of energy demand between daytime and nighttime, storing summer heat for winter heating, or winter cold for summer cooling. Storage media include water or ice-slush tanks, masses of native earth or bedrock accessed with heat exchangers by means of boreholes, deep aquifers contained between impermeable strata; shallow, lined pits filled with gravel and water and insulated at the top, as well as eutectic solutions and phase-change materials.
Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles. It is also used in domestic and commercial refrigerators, large-scale warehouses for chilled or frozen storage of foods and meats, refrigerated trucks and railroad cars, and a host of other commercial and industrial services. Oil refineries, petrochemical and chemical processing plants, and natural gas processing plants are among the many types of industrial plants that often utilize large vapor-compression refrigeration systems. Cascade refrigeration systems may also be implemented using two compressors.
In thermal engineering, the organic Rankine cycle (ORC) is a type of thermodynamic cycle. It is a variation of the Rankine cycle named for its use of an organic, high-molecular-mass fluid whose vaporization temperature is lower than that of water. The fluid allows heat recovery from lower-temperature sources such as biomass combustion, industrial waste heat, geothermal heat, solar ponds etc. The low-temperature heat is converted into useful work, that can itself be converted into electricity.
Photovoltaic thermal collectors, typically abbreviated as PVT collectors and also known as hybrid solar collectors, photovoltaic thermal solar collectors, PV/T collectors or solar cogeneration systems, are power generation technologies that convert solar radiation into usable thermal and electrical energy. PVT collectors combine photovoltaic solar cells, which convert sunlight into electricity, with a solar thermal collector, which transfers the otherwise unused waste heat from the PV module to a heat transfer fluid. By combining electricity and heat generation within the same component, these technologies can reach a higher overall efficiency than solar photovoltaic (PV) or solar thermal (T) alone.
The term subcooling refers to a liquid existing at a temperature below its normal boiling point. For example, water boils at 373 K; at room temperature (293 K) liquid water is termed "subcooled". Subcooled liquids are frequently used in refrigeration cycles, steam turbine cycles, and some rocket engines use subcooled propellants.
Nanofluid-based direct solar collectors are solar thermal collectors where nanoparticles in a liquid medium can scatter and absorb solar radiation. They have recently received interest to efficiently distribute solar energy. Nanofluid-based solar collector have the potential to harness solar radiant energy more efficiently compared to conventional solar collectors. Nanofluids have recently found relevance in applications requiring quick and effective heat transfer such as industrial applications, cooling of microchips, microscopic fluidic applications, etc. Moreover, in contrast to conventional heat transfer like water, ethylene glycol, and molten salts, nanofluids are not transparent to solar radiant energy; instead, they absorb and scatter significantly the solar irradiance passing through them. Typical solar collectors use a black-surface absorber to collect the sun's heat energy which is then transferred to a fluid running in tubes embedded within. Various limitations have been discovered with these configuration and alternative concepts have been addressed. Among these, the use of nanoparticles suspended in a liquid is the subject of research. Nanoparticle materials including aluminium, copper, carbon nanotubes and carbon-nanohorns have been added to different base fluids and characterized in terms of their performance for improving heat transfer efficiency.
The integral molten salt reactor (IMSR) is a nuclear power plant design targeted at developing a commercial product for the small modular reactor (SMR) market. It employs molten salt reactor technology which is being developed by the Canadian company Terrestrial Energy.