High-pressure electrolysis

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ITM Power's HGas electrolyser stacks, each operating at 80bar pressure High-pressure PEM electrolyser stacks.jpg
ITM Power's HGas electrolyser stacks, each operating at 80bar pressure
High-pressure PEM electrolyser. PEM electrolyzer.jpg
High-pressure PEM electrolyser.
PEM high pressure electrolyser.jpg

High-pressure electrolysis (HPE) is the electrolysis of water by decomposition of water (H2O) into oxygen (O2) and hydrogen gas (H2) due to the passing of an electric current through the water. [1] The difference with a standard proton exchange membrane (PEM) electrolyzer is the compressed hydrogen output around 12–20 megapascals (120–200 bar) [2] at 70 °C. [3] By pressurising the hydrogen in the electrolyser the need for an external hydrogen compressor is eliminated, the average energy consumption for internal differential pressure compression is around 3%. [4]

Contents

Approaches

As the required compression power for water is less than that for hydrogen-gas the water is pumped up to a high-pressure, [5] in the other approach differential pressure is used. [6] There is also an importance for the electrolyser stacks to be able to accept a fluctuating electrical input, such as that found with renewable energy. [7] This then enables the ability to help with grid balancing and energy storage.

Ultrahigh-pressure electrolysis

Ultrahigh-pressure electrolysis is high-pressure electrolysis operating at 340–690 bars (5,000–10,000 psi). [8] At ultra-high pressures the water solubility and cross-permeation across the membrane of H2 and O2 is affecting hydrogen purity, modified PEMs are used to reduce cross-permeation in combination with catalytic H2/O2 recombiners to maintain H2 levels in O2 and O2 levels in H2 at values compatible with hydrogen safety requirements. [9] [10]

Research

The US DOE believes that high-pressure electrolysis, supported by ongoing research and development, will contribute to the enabling and acceptance of technologies where hydrogen is the energy carrier between renewable energy resources and clean energy consumers. [11]

High-pressure electrolysis is being investigated by the DOE for efficient production of hydrogen from water. The target total in 2005 is $4.75 per gge H2 at an efficiency of 64%. [10] The total goal for the DOE in 2010 is $2.85 per gge H2 at an efficiency of 75%. [11] As of 2005 the DOE provided a total of $1,563,882 worth of funding for research. [10]

Mitsubishi is pursuing such technology with its High-pressure hydrogen energy generator (HHEG) project. [12]

The Forschungszentrum Jülich, in Jülich Germany is currently researching the cost reduction of components used in high-pressure PEM electrolysis in the EKOLYSER [13] project. The primary goal of this research is to improve performance and gas purity, reduce cost and volume of expensive materials and reach the alternative energy targets set forth by the German government for 2050 in the Energy Concept published in 2010. [14] [15]

ThalesNano Energy released a lab-scale high pressure (100 bar) hydrogen generator as a replacement for hydrogen cylinders in chemistry laboratories. [16]

Commercial Products

Honda installed its Smart Hydrogen Station (SHS) in Los Angeles for use by fuel cell automobiles. [17]

See also

Related Research Articles

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<span class="mw-page-title-main">Electrolysis</span> Technique in chemistry and manufacturing

In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential. The word "lysis" means to separate or break, so in terms, electrolysis would mean "breakdown via electricity."

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<span class="mw-page-title-main">Proton-exchange membrane fuel cell</span> Power generation technology

Proton-exchange membrane fuel cells (PEMFC), also known as polymer electrolyte membrane (PEM) fuel cells, are a type of fuel cell being developed mainly for transport applications, as well as for stationary fuel-cell applications and portable fuel-cell applications. Their distinguishing features include lower temperature/pressure ranges and a special proton-conducting polymer electrolyte membrane. PEMFCs generate electricity and operate on the opposite principle to PEM electrolysis, which consumes electricity. They are a leading candidate to replace the aging alkaline fuel-cell technology, which was used in the Space Shuttle.

<span class="mw-page-title-main">High-temperature electrolysis</span> Technique for producing hydrogen from water

High-temperature electrolysis is a technology for producing hydrogen from water at high temperatures or other products, such as iron or carbon nanomaterials, as higher energy lowers needed electricity to split molecules and opens up new, potentially better electrolytes like molten salts or hydroxides. Unlike electrolysis at room temperature, HTE operates at elevated temperature ranges depending on the thermal capacity of the material. Because of the detrimental effects of burning fossil fuels on humans and the environment, HTE has become a necessary alternative and efficient method by which hydrogen can be prepared on a large scale and used as fuel. The vision of HTE is to move towards decarbonization in all economic sectors. The material requirements for this process are: the heat source, the electrodes, the electrolyte, the electrolyzer membrane, and the source of electricity.

A proton-exchange membrane, or polymer-electrolyte membrane (PEM), is a semipermeable membrane generally made from ionomers and designed to conduct protons while acting as an electronic insulator and reactant barrier, e.g. to oxygen and hydrogen gas. This is their essential function when incorporated into a membrane electrode assembly (MEA) of a proton-exchange membrane fuel cell or of a proton-exchange membrane electrolyser: separation of reactants and transport of protons while blocking a direct electronic pathway through the membrane.

<span class="mw-page-title-main">Electrolysis of water</span> Electricity-induced chemical reaction

Electrolysis of water is using electricity to split water into oxygen and hydrogen gas by electrolysis. Hydrogen gas released in this way can be used as hydrogen fuel, but must be kept apart from the oxygen as the mixture would be extremely explosive. Separately pressurised into convenient 'tanks' or 'gas bottles', hydrogen can be used for oxyhydrogen welding and other applications, as the hydrogen / oxygen flame can reach approximately 2,800°C.

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<span class="mw-page-title-main">Proton exchange membrane electrolysis</span> Technology for splitting water molecules

Proton exchange membrane(PEM) electrolysis is the electrolysis of water in a cell equipped with a solid polymer electrolyte (SPE) that is responsible for the conduction of protons, separation of product gases, and electrical insulation of the electrodes. The PEM electrolyzer was introduced to overcome the issues of partial load, low current density, and low pressure operation currently plaguing the alkaline electrolyzer. It involves a proton-exchange membrane.

Hydrogenics is a developer and manufacturer of hydrogen generation and fuel cell products based on water electrolysis and proton-exchange membrane (PEM) technology. Hydrogenics is divided into two business units: OnSite Generation and Power Systems. Onsite Generation is headquartered in Oevel, Belgium and had 73 full-time employees as of December 2013. Power Systems is based in Mississauga, Ontario, Canada, with a satellite facility in Gladbeck, Germany. It had 62 full-time employees as of December 2013. Hydrogenics maintains operations in Belgium, Canada and Germany with satellite offices in the United States, Indonesia, Malaysia and Russia.

<span class="mw-page-title-main">Pulse electrolysis</span> Pulse Electrolysis

Pulse electrolysis is an alternate electrolysis method that utilises a pulsed direct current to initiate non-spontaneous chemical reactions. Also known as pulsed direct current (PDC) electrolysis, the increased number of variables that it introduces to the electrolysis method can change the application of the current to the electrodes and the resulting outcome. This varies from direct current (DC) electrolysis, which only allows the variation of one value, the voltage applied. By utilising conventional pulse width modulation (PMW), multiple dependent variables can be altered, including the type of waveform, typically a rectangular pulse wave, the duty cycle, and the frequency. Currently, there has been a focus on theoretical and experimental research into PDC electrolysis in terms of the electrolysis of water to produce hydrogen. Past research has demonstrated that there is a possibility it can result in a higher electrical efficiency in comparison to DC electrolysis. This would allow electrolysis procedures to produce greater volumes of hydrogen with a reduced electrical energy consumption. Although theoretical research has made large promise for the efficiencies and benefits of utilising pulse electrolysis, it has many contradictions including a common issue that it is difficult to replicate the successes of patents experimentally and produces its own negative effects on the electrolyser.

<span class="mw-page-title-main">Nel ASA</span>

Nel ASA is a Norwegian company founded in 1927 and based in Oslo. Nel is a global company providing solutions for the production, storage and distribution of hydrogen from renewable energy sources. Nel is listed in the OBX Index of the Oslo Stock Exchange. As of March 2020, the largest shareholder is Clearstream Banking S.A. with a stake of 44.81%.

Hydrogen evolution reaction (HER) is a chemical reaction that yields H2. The conversion of protons to H2 requires reducing equivalents and usually a catalyst. In nature, HER is catalyzed by hydrogenase enzymes. Commercial electrolyzers typically employ supported platinum as the catalyst at the anode of the electrolyzer. HER is useful for producing hydrogen gas, providing a clean-burning fuel. HER, however, can also be an unwelcome side reaction that competes with other reductions such as nitrogen fixation, or electrochemical reduction of carbon dioxide or chrome plating.

<span class="mw-page-title-main">Anion exchange membrane electrolysis</span> Splitting of water using a semipermeable membrane

Anion exchange membrane(AEM) electrolysis is the electrolysis of water that utilises a semipermeable membrane that conducts hydroxide ions (OH) called an anion exchange membrane. Like a proton-exchange membrane (PEM), the membrane separates the products, provides electrical insulation between electrodes, and conducts ions. Unlike PEM, AEM conducts hydroxide ions. The major advantage of AEM water electrolysis is that a high-cost noble metal catalyst is not required, low-cost transition metal catalyst can be used instead. AEM electrolysis is similar to alkaline water electrolysis, which uses a non-ion-selective separator instead of an anion-exchange membrane.

References

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  4. 2003-PHOEBUS-Pag.9 Archived 2009-03-27 at the Wayback Machine
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  6. Differential pressure
  7. "Electrolyser Stacks | ITM Power". Archived from the original on 2013-05-12. Retrieved 2013-05-20.
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  11. 1 2 Alkaline, High Pressure Electrolysis (Available here Accessed 2008-08-9.)
  12. Mitsubishi Monitor August and September 2004 (available here Accessed 2008-08-9.)
  13. "Forschungszentrum Jülich EKOLYSER Project" . Retrieved 27 May 2013.
  14. "Das Energiekonzept der Bundesregierung 2010 und die Energiewende 2011" (PDF). Archived from the original (PDF) on 2013-02-26.
  15. Carmo, M; Fritz D; Mergel J; Stolten D (2013). "A comprehensive review on PEM water electrolysis". Journal of Hydrogen Energy. 38 (12): 4901. doi:10.1016/j.ijhydene.2013.01.151.
  16. "Hydrogen Generator & CO2 Cell Technology".
  17. "Smart Hydrogen Station".