The hydrodynamic radius of a macromolecule or colloid particle is . The macromolecule or colloid particle is a collection of subparticles. This is done most commonly for polymers; the subparticles would then be the units of the polymer. For polymers in solution, is defined by
where is the distance between subparticles and , and where the angular brackets represent an ensemble average. [1] The theoretical hydrodynamic radius was originally an estimate by John Gamble Kirkwood of the Stokes radius of a polymer, and some sources still use hydrodynamic radius as a synonym for the Stokes radius.
Note that in biophysics, hydrodynamic radius refers to the Stokes radius, [2] or commonly to the apparent Stokes radius obtained from size exclusion chromatography. [3]
The theoretical hydrodynamic radius arises in the study of the dynamic properties of polymers moving in a solvent. It is often similar in magnitude to the radius of gyration. [4]
The mobility of non-spherical aerosol particles can be described by the hydrodynamic radius. In the continuum limit, where the mean free path of the particle is negligible compared to a characteristic length scale of the particle, the hydrodynamic radius is defined as the radius that gives the same magnitude of the frictional force, as that of a sphere with that radius, i.e.
where is the viscosity of the surrounding fluid, and is the velocity of the particle. This is analogous to the Stokes' radius, however this is untrue as the mean free path becomes comparable to the characteristic length scale of the particulate - a correction factor is introduced such that the friction is correct over the entire Knudsen regime. As is often the case, [5] the Cunningham correction factor is used, where:
where were found by Millikan [6] to be: 1.234, 0.414, and 0.876 respectively.
In physics, the cross section is a measure of the probability that a specific process will take place in a collision of two particles. For example, the Rutherford cross-section is a measure of probability that an alpha particle will be deflected by a given angle during an interaction with an atomic nucleus. Cross section is typically denoted σ (sigma) and is expressed in units of area, more specifically in barns. In a way, it can be thought of as the size of the object that the excitation must hit in order for the process to occur, but more exactly, it is a parameter of a stochastic process.
The Navier–Stokes equations are partial differential equations which describe the motion of viscous fluid substances. They were named after French engineer and physicist Claude-Louis Navier and the Irish physicist and mathematician George Gabriel Stokes. They were developed over several decades of progressively building the theories, from 1822 (Navier) to 1842–1850 (Stokes).
A Fermi gas is an idealized model, an ensemble of many non-interacting fermions. Fermions are particles that obey Fermi–Dirac statistics, like electrons, protons, and neutrons, and, in general, particles with half-integer spin. These statistics determine the energy distribution of fermions in a Fermi gas in thermal equilibrium, and is characterized by their number density, temperature, and the set of available energy states. The model is named after the Italian physicist Enrico Fermi.
In fluid dynamics, Stokes' law is an empirical law for the frictional force – also called drag force – exerted on spherical objects with very small Reynolds numbers in a viscous fluid. It was derived by George Gabriel Stokes in 1851 by solving the Stokes flow limit for small Reynolds numbers of the Navier–Stokes equations.
A Newtonian fluid is a fluid in which the viscous stresses arising from its flow are at every point linearly correlated to the local strain rate — the rate of change of its deformation over time. Stresses are proportional to the rate of change of the fluid's velocity vector.
In physics and astronomy, the Reissner–Nordström metric is a static solution to the Einstein–Maxwell field equations, which corresponds to the gravitational field of a charged, non-rotating, spherically symmetric body of mass M. The analogous solution for a charged, rotating body is given by the Kerr–Newman metric.
In physics, the Hamilton–Jacobi equation, named after William Rowan Hamilton and Carl Gustav Jacob Jacobi, is an alternative formulation of classical mechanics, equivalent to other formulations such as Newton's laws of motion, Lagrangian mechanics and Hamiltonian mechanics.
In general relativity, Schwarzschild geodesics describe the motion of test particles in the gravitational field of a central fixed mass that is, motion in the Schwarzschild metric. Schwarzschild geodesics have been pivotal in the validation of Einstein's theory of general relativity. For example, they provide accurate predictions of the anomalous precession of the planets in the Solar System and of the deflection of light by gravity.
In quantum mechanics, the spin–orbit interaction is a relativistic interaction of a particle's spin with its motion inside a potential. A key example of this phenomenon is the spin–orbit interaction leading to shifts in an electron's atomic energy levels, due to electromagnetic interaction between the electron's magnetic dipole, its orbital motion, and the electrostatic field of the positively charged nucleus. This phenomenon is detectable as a splitting of spectral lines, which can be thought of as a Zeeman effect product of two effects: the apparent magnetic field seen from the electron perspective due to special relativity and the magnetic moment of the electron associated with its intrinsic spin due to quantum mechanics.
This article describes the mathematics of the Standard Model of particle physics, a gauge quantum field theory containing the internal symmetries of the unitary product group SU(3) × SU(2) × U(1). The theory is commonly viewed as describing the fundamental set of particles – the leptons, quarks, gauge bosons and the Higgs boson.
Stokes flow, also named creeping flow or creeping motion, is a type of fluid flow where advective inertial forces are small compared with viscous forces. The Reynolds number is low, i.e. . This is a typical situation in flows where the fluid velocities are very slow, the viscosities are very large, or the length-scales of the flow are very small. Creeping flow was first studied to understand lubrication. In nature, this type of flow occurs in the swimming of microorganisms and sperm. In technology, it occurs in paint, MEMS devices, and in the flow of viscous polymers generally.
The Stokes radius or Stokes–Einstein radius of a solute is the radius of a hard sphere that diffuses at the same rate as that solute. Named after George Gabriel Stokes, it is closely related to solute mobility, factoring in not only size but also solvent effects. A smaller ion with stronger hydration, for example, may have a greater Stokes radius than a larger ion with weaker hydration. This is because the smaller ion drags a greater number of water molecules with it as it moves through the solution.
In directional statistics, the von Mises–Fisher distribution, is a probability distribution on the -sphere in . If the distribution reduces to the von Mises distribution on the circle.
In quantum mechanics, the Pauli equation or Schrödinger–Pauli equation is the formulation of the Schrödinger equation for spin-1/2 particles, which takes into account the interaction of the particle's spin with an external electromagnetic field. It is the non-relativistic limit of the Dirac equation and can be used where particles are moving at speeds much less than the speed of light, so that relativistic effects can be neglected. It was formulated by Wolfgang Pauli in 1927. In its linearized form it is known as Lévy-Leblond equation.
In fluid dynamics and electrostatics, slender-body theory is a methodology that can be used to take advantage of the slenderness of a body to obtain an approximation to a field surrounding it and/or the net effect of the field on the body. Principal applications are to Stokes flow — at very low Reynolds numbers — and in electrostatics.
In fluid dynamics, Faxén's laws relate a sphere's velocity and angular velocity to the forces, torque, stresslet and flow it experiences under low Reynolds number conditions.
Chapman–Enskog theory provides a framework in which equations of hydrodynamics for a gas can be derived from the Boltzmann equation. The technique justifies the otherwise phenomenological constitutive relations appearing in hydrodynamical descriptions such as the Navier–Stokes equations. In doing so, expressions for various transport coefficients such as thermal conductivity and viscosity are obtained in terms of molecular parameters. Thus, Chapman–Enskog theory constitutes an important step in the passage from a microscopic, particle-based description to a continuum hydrodynamical one.
In probability theory, a logit-normal distribution is a probability distribution of a random variable whose logit has a normal distribution. If Y is a random variable with a normal distribution, and t is the standard logistic function, then X = t(Y) has a logit-normal distribution; likewise, if X is logit-normally distributed, then Y = logit(X)= log (X/(1-X)) is normally distributed. It is also known as the logistic normal distribution, which often refers to a multinomial logit version (e.g.).
The optical metric was defined by German theoretical physicist Walter Gordon in 1923 to study the geometrical optics in curved space-time filled with moving dielectric materials.
In mathematical physics, the Gordon decomposition of the Dirac current is a splitting of the charge or particle-number current into a part that arises from the motion of the center of mass of the particles and a part that arises from gradients of the spin density. It makes explicit use of the Dirac equation and so it applies only to "on-shell" solutions of the Dirac equation.