Intergranular fracture

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Intergranular fracture, intergranular cracking or intergranular embrittlement occurs when a crack propagates along the grain boundaries of a material, usually when these grain boundaries are weakened. [1] The more commonly seen transgranular fracture, occurs when the crack grows through the material grains. As an analogy, in a wall of bricks, intergranular fracture would correspond to a fracture that takes place in the mortar that keeps the bricks together.

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Intergranular cracking is likely to occur if there is a hostile environmental influence and is favored by larger grain sizes and higher stresses. [1] Intergranular cracking is possible over a wide range of temperatures. [2] While transgranular cracking is favored by strain localization (which in turn is encouraged by smaller grain sizes), intergranular fracture is promoted by strain homogenization resulting from coarse grains. [3]

Intergranular fracture produced by crack propagation along grain boundaries Intergranular Fracture.svg
Intergranular fracture produced by crack propagation along grain boundaries

Embrittlement, or loss of ductility, is often accompanied by a change in fracture mode from transgranular to intergranular fracture. [4] This transition is particularly significant in the mechanism of impurity-atom embrittlement. [4] Additionally, hydrogen embrittlement is a common category of embrittlement in which intergranular fracture can be observed. [5]

Intergranular fracture can occur in a wide variety of materials, including steel alloys, copper alloys, aluminum alloys, and ceramics. [6] [7] [3] In metals with multiple lattice orientations, when one lattice ends and another begins, the fracture changes direction to follow the new grain. This results in a fairly jagged looking fracture with straight edges of the grain and a shiny surface may be seen. In ceramics, intergranular fractures propagate through grain boundaries, producing smooth bumpy surfaces where grains can be easily identified.

Mechanisms of intergranular fracture

Though it is easy to identify intergranular cracking, pinpointing the cause is more complex as the mechanisms are more varied, compared to transgranular fracture. [6] There are several other processes that can lead to intergranular fracture or preferential crack propagation at the grain boundaries: [8] [6]

From an energy standpoint, the energy released by intergranular crack propagation is higher than that predicted by Griffith theory, implying that the additional energy term to propagate a crack comes from a grain-boundary mechanism. [9]

Types of intergranular fracture

Intergranular fracture can be categorized into the following: [6]

Role of solutes and impurities

At room temperature, intergranular fracture is commonly associated with altered cohesion resulting from segregation of solutes or impurities at the grain boundaries. [10] Examples of solutes known to influence intergranular fracture are sulfur, phosphorus, arsenic, and antimony specifically in steels, lead in aluminum alloys, and hydrogen in numerous structural alloys. [10] At high impurity levels, especially in the case of hydrogen embrittlement, the likelihood of intergranular fracture is greater. [6] Solutes like hydrogen are hypothesized to stabilize and increase the density of strain-induced vacancies, [11] leading to microcracks and microvoids at grain boundaries. [5]

Role of grain boundary orientation

Intergranular cracking is dependent on the relative orientation of the common boundary between two grains. The path of intergranular fracture typically occurs along the highest-angle grain boundary. [6] In a study, it was shown that cracking was never exhibited for boundaries with misorientation of up to 20 degrees, regardless of boundary type. [12] At greater angles, large areas of cracked, uncracked, and mixed behavior were seen. The results imply that the degree of grain boundary cracking, and hence intergranular fracture, is largely determined by boundary porosity, or the amount of atomic misfit. [12]

See also

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Ductility is a mechanical property commonly described as a material's amenability to drawing. In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stress before failure. Ductility is an important consideration in engineering and manufacturing, defining a material's suitability for certain manufacturing operations and its capacity to absorb mechanical overload. Some metals that are generally described as ductile include gold and copper. However, not all metals experience ductile failure as some can be characterized with brittle failure like cast iron. Polymers generally can be viewed as ductile materials as they typically allow for plastic deformation.

Fracture Split of materials or structures under stress

Fracture is the separation of an object or material into two or more pieces under the action of stress. The fracture of a solid usually occurs due to the development of certain displacement discontinuity surfaces within the solid. If a displacement develops perpendicular to the surface, it is called a normal tensile crack or simply a crack; if a displacement develops tangentially, it is called a shear crack, slip band or dislocation.

Creep (deformation) Tendency of a solid material to move slowly or deform permanently under mechanical stress

In materials science, creep is the tendency of a solid material to move slowly or deform permanently under the influence of persistent mechanical stresses. It can occur as a result of long-term exposure to high levels of stress that are still below the yield strength of the material. Creep is more severe in materials that are subjected to heat for long periods and generally increases as they near their melting point.

Hydrogen embrittlement Embrittlement of a metal exposed to hydrogen

Hydrogen embrittlement (HE) also known as hydrogen assisted cracking or hydrogen-induced cracking, describes the embrittlement of a metal by diffusible hydrogen. The essential facts about the nature of the hydrogen embrittlement of steels have now been known for 140 years. It is diffusible atomic hydrogen that is harmful to the toughness of iron and steel. It is a low temperature effect: most metals are relatively immune to hydrogen embrittlement above approximately 150°C.

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Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature below the critical point for a certain period of time, then allowing it to cool in still air. The exact temperature determines the amount of hardness removed, and depends on both the specific composition of the alloy and on the desired properties in the finished product. For instance, very hard tools are often tempered at low temperatures, while springs are tempered at much higher temperatures.

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Intergranular corrosion

Intergranular corrosion (IGC), also known as intergranular attack (IGA), is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides.

Liquid metal embrittlement (LME), also known as liquid metal induced embrittlement, is a phenomenon of practical importance, where certain ductile metals experience drastic loss in tensile ductility or undergo brittle fracture when exposed to specific liquid metals. Generally, a tensile stress, either externally applied or internally present, is needed to induce embrittlement. Exceptions to this rule have been observed, as in the case of aluminium in the presence of liquid gallium. This phenomenon has been studied since the beginning of the 20th century. Many of its phenomenological characteristics are known and several mechanisms have been proposed to explain it. The practical significance of liquid metal embrittlement is revealed by the observation that several steels experience ductility losses and cracking during hot-dip galvanizing or during subsequent fabrication. Cracking can occur catastrophically and very high crack growth rates have been measured.

Corrosion fatigue is fatigue in a corrosive environment. It is the mechanical degradation of a material under the joint action of corrosion and cyclic loading. Nearly all engineering structures experience some form of alternating stress, and are exposed to harmful environments during their service life. The environment plays a significant role in the fatigue of high-strength structural materials like steel, aluminum alloys and titanium alloys. Materials with high specific strength are being developed to meet the requirements of advancing technology. However, their usefulness depends to a large extent on the degree to which they resist corrosion fatigue.

Embrittlement

Embrittlement is a significant decrease of ductility of a material, which makes the material brittle. Embrittlement is used to describe any phenomena where the environment compromises a stressed material's mechanical performance, such as temperature or environmental composition. This is oftentimes undesirable as brittle fracture occurs quicker and can much more easily propagate than ductile fracture, leading to complete failure of the equipment. Various materials have different mechanisms of embrittlement, therefore it can manifest in a variety of ways, from slow crack growth to a reduction of tensile ductility and toughness.

Radiation damage is the effect of ionizing radiation on physical objects including non-living structural materials.

In materials science, segregation is the enrichment of atoms, ions, or molecules at a microscopic region in a materials system. While the terms segregation and adsorption are essentially synonymous, in practice, segregation is often used to describe the partitioning of molecular constituents to defects from solid solutions, whereas adsorption is generally used to describe such partitioning from liquids and gases to surfaces. The molecular-level segregation discussed in this article is distinct from other types of materials phenomena that are often called segregation, such as particle segregation in granular materials, and phase separation or precipitation, wherein molecules are segregated in to macroscopic regions of different compositions. Segregation has many practical consequences, ranging from the formation of soap bubbles, to microstructural engineering in materials science, to the stabilization of colloidal suspensions.

Microvoid coalescence

Microvoid coalescence (MVC) is a high energy microscopic fracture mechanism observed in the majority of metallic alloys and in some engineering plastics.

Dynamic strain aging (DSA) for materials science is an instability in plastic flow of materials, associated with interaction between moving dislocations and diffusing solutes. Although sometimes dynamic strain aging is used interchangeably with the Portevin–Le Chatelier effect, dynamic strain aging refers specifically to the microscopic mechanism that induces the Portevin–Le Chatelier effect. This strengthening mechanism is related to solid-solution strengthening and has been observed in a variety of fcc and bcc substitutional and interstitial alloys, metalloids like silicon, and ordered intermetallics within specific ranges of temperature and strain rate.

Polymer fracture is the study of the fracture surface of an already failed material to determine the method of crack formation and extension in polymers both fiber reinforced and otherwise. Failure in polymer components can occur at relatively low stress levels, far below the tensile strength because of four major reasons: long term stress or creep rupture, cyclic stresses or fatigue, the presence of structural flaws and stress-cracking agents. Formations of submicroscopic cracks in polymers under load have been studied by x ray scattering techniques and the main regularities of crack formation under different loading conditions have been analyzed. The low strength of polymers compared to theoretically predicted values are mainly due to the many microscopic imperfections found in the material. These defects namely dislocations, crystalline boundaries, amorphous interlayers and block structure can all lead to the non-uniform distribution of mechanical stress.

Toughening is the improvement of the fracture resistance of a given material. The material's toughness is described by irreversible work accompanying crack propagation. Designing against this crack propagation leads to toughening the material.

Static fatigue describes the fracture happening at a stress level less than the value required to cause an ordinary tensile fracture. It is a manifestation of the possible adverse effect of environment on the behaviour of materials. This term highlights the contribution of environment to the crack propagation in materials under applied or residual stress, which leads to stress concentration and thus stress fatigue. It is also called “delayed fracture”, referring to the long period of time the crack takes to grow large enough to cause spontaneous failure. It is a form of material embrittlement, and occurs in various materials and diverse environments.

Neutron embrittlement, sometimes more broadly radiation embrittlement, is the embrittlement of various materials due to the action of neutrons. This is primarily seen in nuclear reactors, where the release of high-energy neutrons causes the long-term degradation of the reactor materials. The embrittlement is caused by the microscopic movement of atoms that are hit by the neutrons; this same action also gives rise to neutron-induced swelling causing materials to grow in size, and the Wigner effect causing energy buildup in certain materials that can lead to sudden releases of energy.

Metal-induced embrittlement (MIE) is the embrittlement caused by diffusion of metal, either solid or liquid, into the base material. Metal induced embrittlement occurs when metals are in contact with low-melting point metals while under tensile stress. The embrittler can be either solid (SMIE) or liquid. Under sufficient tensile stress, MIE failure occurs instantaneously at temperatures just above melting point. For temperatures below the melting temperature of the embrittler, solid-state diffusion is the main transport mechanism. This occurs in the following ways:

Striation (fatigue)

Striations are marks produced on the fracture surface that show the incremental growth of a fatigue crack. A striation marks the position of the crack tip at the time it was made. The term striation generally refers to ductile striations which are rounded bands on the fracture surface separated by depressions or fissures and can have the same appearance on both sides of the mating surfaces of the fatigue crack. Although some research has suggested that many loading cycles are required to form a single striation, it is now generally thought that each striation is the result of a single loading cycle.

References

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