Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk chalk. Gypsum also crystallizes as translucent crystals of selenite. It forms as an evaporite mineral and as a hydration product of anhydrite. The Mohs scale of mineral hardness defines gypsum as hardness value 2 based on scratch hardness comparison.
Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct during the purification and refining of zinc and is also commonly associated with acid mine drainage and acid sulfate soil environments.
Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium (celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The Mohs hardness is 3.5, and the specific gravity is 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is glassy. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to around 200 °C (400 °F) under normal atmospheric conditions. Anhydrite is commonly associated with calcite, halite, and sulfides such as galena, chalcopyrite, molybdenite, and pyrite in vein deposits.
Aphthitalite is a potassium sulfate mineral with the chemical formula: (K,Na)3Na(SO4)2.
Blödite or bloedite is a hydrated sodium magnesium sulfate mineral with the formula Na2Mg(SO4)2·4H2O. The mineral is clear to yellow in color often darkened by inclusions and forms monoclinic crystals.
Kalinite is a mineral composed of hydrated potassium aluminium sulfate. It is a fibrous monoclinic alum, distinct from isometric potassium alum, named in 1868. Its name comes from kalium (derived from Arabic: القَلْيَه al-qalyah "plant ashes", which is the Latin name for potassium, hence its chemical symbol, "K".
Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. The space between this T-O-T sequence of layers is occupied by poorly hydrated potassium cations which are responsible for the absence of swelling. Structurally, illite is quite similar to muscovite with slightly more silicon, magnesium, iron, and water and slightly less tetrahedral aluminium and interlayer potassium. The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small monoclinic grey to white crystals. Due to the small size, positive identification usually requires x-ray diffraction or SEM-EDS analysis. Illite occurs as an altered product of muscovite and feldspar in weathering and hydrothermal environments; it may be a component of sericite. It is common in sediments, soils, and argillaceous sedimentary rocks as well as in some low grade metamorphic rocks. The iron-rich member of the illite group, glauconite, in sediments can be differentiated by x-ray analysis.
Afghanite, (Na,K)22Ca10[Si24Al24O96](SO4)6Cl6, is a hydrous sodium, calcium, potassium, sulfate, chloride, carbonate alumino-silicate mineral. Afghanite is a feldspathoid of the cancrinite group and typically occurs with sodalite group minerals. It forms blue to colorless, typically massive crystals in the trigonal crystal system. The lowering of the symmetry from typical (for cancrinite group) hexagonal one is due to ordering of Si and Al. It has a Mohs hardness of 5.5 to 6 and a specific gravity of 2.55 to 2.65. It has refractive index values of nω = 1.523 and nε = 1.529. It has one direction of perfect cleavage and exhibits conchoidal fracture. It fluoresces a bright orange.
Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: K2Ca2Mg(SO4)4·2H2O. Polyhalite crystallizes in the triclinic system, although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it may be brick red due to iron oxide inclusions. It has a Mohs hardness of 3.5 and a specific gravity of 2.8. It is used as a fertilizer.
Zincobotryogen is a hydrous sulfate mineral with the chemical formula (Zn,Mg,Mn)Fe3+(SO4)2(OH)·7H2O. It forms bright orange red monoclinic prismatic crystals that exhibit a vitreous to greasy luster. Its specific gravity is 2.201 and it has a Mohs hardness of 2.5.
Sodium aluminium sulfate is the inorganic compound with the chemical formula NaAl(SO4)2·12H2O (sometimes written Na2SO4·Al2(SO4)3·24H2O). Also known as soda alum, sodium alum, or SAS, this white solid is used in the manufacture of baking powder and as a food additive. Its official mineral name is alum-Na (IMA symbol: Aum-Na).
Johannite is a rare uranium sulfate mineral. It crystallizes in the triclinic crystal system with the chemical composition Cu[UO2(OH)SO4]2·8H2O. It crystallizes in the triclinic system and develops only small prism or thin to thick tabular crystals, usually occurs as flaky or spheroidal aggregates and efflorescent coatings. Its color is emerald-green to apple-green and its streak is pale green.
Alum-(K) is a hydrous potassium aluminium sulfate mineral with formula KAl(SO4)2·12(H2O). It is the mineral form of potassium alum and is referred to as potassium alum in older sources. It is a member of the alum group.
Syngenite is an uncommon potassium calcium sulfate mineral with formula K2Ca(SO4)2·H2O. It forms as prismatic monoclinic crystals and as encrustations.
Langbeinites are a family of crystalline substances based on the structure of langbeinite with general formula M2M'2(SO4)3, where M is a large univalent cation, and M' is a small divalent cation. The sulfate group, SO2−4, can be substituted by other tetrahedral anions with a double negative charge such as tetrafluoroberyllate, selenate, chromate, molybdate, or tungstates. Although monofluorophosphates are predicted, they have not been described. By redistributing charges other anions with the same shape such as phosphate also form langbeinite structures. In these the M' atom must have a greater charge to balance the extra three negative charges.
Piypite is a rare potassium, copper sulfate mineral with formula: K2Cu2O(SO4)2. It crystallizes in the tetragonal system and occurs as needlelike crystals and masses. Individual crystals are square in cross-section and often hollow. It is emerald green to black in color with a vitreous to greasy luster.
Leonite is a hydrated double sulfate of magnesium and potassium. It has the formula K2SO4·MgSO4·4H2O. The mineral was named after Leo Strippelmann, who was director of the salt works at Westeregeln in Germany. The mineral is part of the blodite group of hydrated double sulfate minerals.
Nabimusaite is a very rare mineral with formula KCa12(SiO4)4(SO4)2O2F. Its structure, as in case of similar aradite and zadovite, is a derivative of the one of hatrurite. Nabimusaite gives its name to the nabimusaite group. The mineral was found in a pyrometamorphic rock of the Hatrurim Formation, a site known for the natural pyrometamorphism. It is interpreted to have formed due to interaction of a precursor assemblage with sulfate-rich melt. Nabimusaite is potassium- and fluorine-analogue of dargaite.
The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.
Fumarole minerals are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes following deposition from volcanic gas during an eruption or discharge from a volcanic vent or fumarole, but have been encountered on burning coal deposits as well. They can be black or multicoloured and are often unstable upon exposure to the atmosphere.
