Leonhard Grill

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Leonhard Grill
Alma mater
OccupationExperimental physicist  OOjs UI icon edit-ltr-progressive.svg

Leonhard Grill is an Austrian experimental physicist. He is a professor at the University of Graz in the field of nanoscience, in particular with functional molecules on surfaces.

Contents

Education

After his undergraduate studies in physics at the University of Graz, [1] [2] Grill worked with Silvio Modesti at the Istituto Nazionale per la Fisica della Materia (INFM) in Trieste on his doctoral thesis: "Growth of thin metallic overlayers on Ge(111): Electron confinement and characterization of image resonances by selective electron scattering". [3] [4] He then moved to the Freie University of Berlin (FU Berlin) to work with Karl-Heinz Rieder [5] where he began to work on the manipulation of single molecules using scanning tunneling microscopy (STM). [6] [7] In 2007 he submitted his habilitation at the FU Berlin. [8]

Academic career

He was appointed Professor of Physical Chemistry at the University of Graz in 2013. [9]

Research

Grill's research group uses scanning tunneling microscopy and spectroscopy to study and selectively manipulate molecules on surfaces. His interests range from chemical processes of single atoms and molecules to the bottom-up growth of two-dimensional supra- and macromolecular assemblies. Additional research areas include molecules with mechanical, chemical, electronic, optical or electrical functionalities. [10]

By pulling individual polymers off of a surface with the tip of the scanning tunnelling microscope, Grill's group was able to measure for the first time the conductivity of individual molecular wires as a function of their length. [11] [12] He studied the switching mechanism of single-molecule switches, [13] based on intramolecular isomerization or proton transfer. In addition, his group found that a strong influence of the immediate environment on each molecule existed – caused both by the atomic lattice of the surface [14] and single atoms in the vicinity of the molecule. [15] His contributions to the field of molecular dynamics on surfaces include rolling [16] the first molecular wheels across a surface, activating molecular motors with light, [17] and moving individual molecules over relatively large distances with extremely high precision. [18] [19] [20] By combining a molecule with a surface, his group discovered a novel type of molecular motor that can move unidirectionally with 100% efficiency, and even transport individual carbon monoxide molecules as "cargo". [21] This system has been described as "a nanoscale bulldozer". [22]

Grill developed, together with Stefan Hecht, "covalent on-surface polymerization", [23] in which molecular building blocks are connected to construct highly defined and stable networks on surfaces. [24] [25]

Awards

References

  1. "Leonhard Grill, Professor an der Universität Graz - nano-lab.uni-graz.at". nano-lab.uni-graz.at. Retrieved 2024-11-26.
  2. Diploma thesis - Leonhard Grill, Struktur und Reaktivität der seltenen Erdmetalle Praseodym, Europium und Erbium auf Si(111) : auf der Suche nach zweidimensionalen Siliziden, 1996 Catalogue, Library of the University of Graz https://permalink.obvsg.at/UGR/AC01649386
  3. "Leonhard Grill, Professor an der Universität Graz - nano-lab.uni-graz.at". nano-lab.uni-graz.at. Retrieved 2024-11-26.
  4. PhD thesis - Leonhard Grill, Growth of thin metallic overlayers on Ge(111) : electron confinement and characterization of image resonances by selective electron scattering, 2001 Catalogue, Library of the University of Graz https://permalink.obvsg.at/UGR/AC03345182
  5. "Research highlights". Nature. 445 (7126): 342–343. January 2007. Bibcode:2007Natur.445..342.. doi:10.1038/445342a. ISSN   1476-4687.
  6. Rieder, Karl-Heinz; Meyer, Gerhard; Moresco, Francesca; et al. (2005). "Force induced and electron stimulated STM manipulations: Routes to artificial nanostructures as well as to molecular contacts, engines and switches". Journal of Physics: Conference Series. 19 (1): 175–181. Bibcode:2005JPhCS..19..175R. doi: 10.1088/1742-6596/19/1/028 .
  7. ALEXANDER, Still (2011). "MaxPlanckResearch 2/2011 - Focus: Medicine of Tomorrow" (PDF). Research - the Science Magazine of the Max Planck Society. 2–2011: 73–77.
  8. Leonhard, Grill (2007). Functionalized molecules studied by STM: Towards molecular nanotechnology: Habilitationsschrift (Thesis). doi: 10.17169/refubium-45504 .
  9. "Journal of the University of Graz with the Appointment of Leonhard Grill as Professor, Section 329". mitteilungsblatt.uni-graz.at. Retrieved 2024-11-25.
  10. "Leonhard Grill, Professor an der Universität Graz - nano-lab.uni-graz.at". nano-lab.uni-graz.at. Retrieved 2024-12-04.
  11. Lafferentz, Leif; Ample, Francisco; Yu, Hao; Hecht, Stefan; Joachim, Christian; Grill, Leonhard (2009-02-27). "Conductance of a Single Conjugated Polymer as a Continuous Function of Its Length" . Science. 323 (5918): 1193–1197. Bibcode:2009Sci...323.1193L. doi:10.1126/science.1168255. ISSN   0036-8075. PMID   19251624.
  12. Koch, Matthias; Ample, Francisco; Joachim, Christian; Grill, Leonhard (December 2012). "Voltage-dependent conductance of a single graphene nanoribbon" . Nature Nanotechnology. 7 (11): 713–717. Bibcode:2012NatNa...7..713K. doi:10.1038/nnano.2012.169. ISSN   1748-3387. PMID   23064554.
  13. Alemani, Micol; Peters, Maike V.; Hecht, Stefan; Rieder, Karl-Heinz; Moresco, Francesca; Grill, Leonhard (2006-11-01). "Electric Field-Induced Isomerization of Azobenzene by STM" . Journal of the American Chemical Society. 128 (45): 14446–14447. Bibcode:2006JAChS.12814446A. doi:10.1021/ja065449s. ISSN   0002-7863. PMID   17090013.
  14. Dri, Carlo; Peters, Maike V.; Schwarz, Jutta; Hecht, Stefan; Grill, Leonhard (November 2008). "Spatial periodicity in molecular switching" . Nature Nanotechnology. 3 (11): 649–653. Bibcode:2008NatNa...3..649D. doi:10.1038/nnano.2008.269. ISSN   1748-3387. PMID   18989329.
  15. Kumagai, Takashi; Hanke, Felix; Gawinkowski, Sylwester; Sharp, John; Kotsis, Konstantinos; Waluk, Jacek; Persson, Mats; Grill, Leonhard (January 2014). "Controlling intramolecular hydrogen transfer in a porphycene molecule with single atoms or molecules located nearby". Nature Chemistry. 6 (1): 41–46. Bibcode:2014NatCh...6...41K. doi:10.1038/nchem.1804. hdl: 11858/00-001M-0000-0014-7472-2 . ISSN   1755-4330. PMID   24345945.
  16. Grill, L.; Rieder, K.-H.; Moresco, F.; Rapenne, G.; Stojkovic, S.; Bouju, X.; Joachim, C. (February 2007). "Rolling a single molecular wheel at the atomic scale" . Nature Nanotechnology. 2 (2): 95–98. Bibcode:2007NatNa...2...95G. doi:10.1038/nnano.2006.210. ISSN   1748-3387. PMID   18654226.
  17. Saywell, Alex; Bakker, Anne; Mielke, Johannes; Kumagai, Takashi; Wolf, Martin; García-López, Víctor; Chiang, Pinn-Tsong; Tour, James M.; Grill, Leonhard (2016-12-27). "Light-Induced Translation of Motorized Molecules on a Surface" . ACS Nano. 10 (12): 10945–10952. doi:10.1021/acsnano.6b05650. ISSN   1936-0851. PMID   27783488.
  18. "Nano-Forscher der Uni Graz entwickelten neuartigen molekularen Motor". APA Science (in German). 6 September 2023. Retrieved 4 December 2024.
  19. Civita, Donato; Kolmer, Marek; Simpson, Grant J.; Li, An-Ping; Hecht, Stefan; Grill, Leonhard (2020-11-20). "Control of long-distance motion of single molecules on a surface". Science. 370 (6519): 957–960. Bibcode:2020Sci...370..957C. doi:10.1126/science.abd0696. ISSN   0036-8075. PMID   33214276.
  20. mdr.de. "Grazer Forscher versenden und empfangen einzelne Moleküle | MDR.DE". www.mdr.de (in German). Retrieved 2024-12-04.
  21. Simpson, Grant J.; Persson, Mats; Grill, Leonhard (2023-09-07). "Adsorbate motors for unidirectional translation and transport" . Nature. 621 (7977): 82–86. Bibcode:2023Natur.621...82S. doi:10.1038/s41586-023-06384-y. ISSN   0028-0836. PMID   37673992.
  22. Cutts, Elise (2023). "Nanoscale Bulldozer". Scientific American. 329 (5): 14. doi: 10.1038/scientificamerican1223-14a . PMID   39017309.
  23. Grill, Leonhard; Dyer, Matthew; Lafferentz, Leif; Persson, Mats; Peters, Maike V.; Hecht, Stefan (November 2007). "Nano-architectures by covalent assembly of molecular building blocks" . Nature Nanotechnology. 2 (11): 687–691. Bibcode:2007NatNa...2..687G. doi:10.1038/nnano.2007.346. ISSN   1748-3387. PMID   18654406.
  24. Grill, Leonhard; Hecht, Stefan (February 2020). "Covalent on-surface polymerization" . Nature Chemistry. 12 (2): 115–130. Bibcode:2020NatCh..12..115G. doi:10.1038/s41557-019-0392-9. ISSN   1755-4330. PMID   31996811.
  25. "Steirer des Tages: Auf Du und Du mit den kleinsten Maschinen". www.kleinezeitung.at (in German). 2023-04-03. Retrieved 2024-12-04.
  26. Rupprecht, Wissenschaft-Land Steiermark, Anita. "Forschungspreise des Landes Steiermark". Wissenschaft - Land Steiermark (in German). Retrieved 2024-11-22.{{cite web}}: CS1 maint: multiple names: authors list (link)
  27. Simpson, Grant J.; García-López, Víctor; Petermeier, Philipp; Grill, Leonhard; Tour, James M. (July 2017). "How to build and race a fast nanocar" . Nature Nanotechnology. 12 (7): 604–606. Bibcode:2017NatNa..12..604S. doi:10.1038/nnano.2017.137. ISSN   1748-3387. PMID   28681857.
  28. Rapenne, Gwénaël; Joachim, Christian (2017-06-06). "The first nanocar race" . Nature Reviews Materials. 2 (6): 17040. Bibcode:2017NatRM...217040R. doi:10.1038/natrevmats.2017.40. ISSN   2058-8437.
  29. unigraz (2017-10-05). American-Austrian NanoPrix Team is winner of the first NanoCarRace . Retrieved 2024-12-04 via YouTube.
  30. Jacquot De Rouville, Henri-Pierre; Kammerer, Claire; Rapenne, Gwénaël (2018). "From the Synthesis of Nanovehicles to Participation in the First Nanocar Race—View from the French Team". Molecules. 23 (3): 612. doi: 10.3390/molecules23030612 . PMC   6017560 . PMID   29518034.
  31. "2011 Foresight Institute Feynman Prize". legacy.foresight.org. Retrieved 2024-11-22.