Lipscombite

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Lipscombite
Lipscombite sample.jpg
Lipscombite: Small green crystals on quartz, Harvard Museum of Natural History
General
Category Phosphate minerals
Formula
(repeating unit)
(Fe2+,Mn2+)(Fe3+)2(PO4)2(OH)2
IMA symbol Lcb [1]
Strunz classification 8.BB.90
Dana classification41.10.02.01
Crystal system Tetragonal
Crystal class Trapezohedral (422)
(same H-M symbol)
Space group P43212
Unit cell a = 5.37, c = 12.81 [Å]; Z = 4
Identification
Formula mass 391.27 g/mol
ColorGreen gray, olive green, black.
Specific gravity 3.68
Optical propertiesTranslucent to opaque
References [2] [3]
Lipscombite: Small yellowish-green crystals, Lichtenberg Absetzer Mine dump, Ronneburg Uranium deposit, Gera, Thuringia, Germany Lipscombite-91263.jpg
Lipscombite: Small yellowish-green crystals, Lichtenberg Absetzer Mine dump, Ronneburg Uranium deposit, Gera, Thuringia, Germany
Lipscombite: Small black crystals on dark background. Smithsonian National Museum of Natural History Lipscombite.jpg
Lipscombite: Small black crystals on dark background. Smithsonian National Museum of Natural History

Lipscombite (Fe2+,Mn2+)(Fe3+)2(PO4)2(OH)2 [2] [3] is a green gray, olive green, or black. phosphate-based mineral containing iron, manganese, and iron phosphate.

Contents

Lipscombite is often formed at meteorite impact sites where its crystals are microscopically small, because crystal-forming conditions of pressure and temperature are brief.

In the Classification of non-silicate minerals lipscombite is in the lipscombite group, which also includes zinclipscombite. This group is within the non-silicate, category 8, anhydrous phosphates, lazulite supergroup.

Discovery

The mineral lipscombite was first made artificially and then found in nature. It was named after chemist William Lipscomb by the mineralogist John W. Gruner who first made it artificially. [4] [5]

While investigating the stability relations of iron oxides small, black, shiny crystals were obtained when a spherical iron pressure-temperature vessel was contaminated with phosphorus. [6] The x-ray powder diffraction pattern was similar to lazulite, but unknown.

Gruner, a mineralogist at the University of Minnesota, gave Lipscomb, a chemistry professor there, the crystals for Lewis Katz and Lipscomb to determine the atomic structure using single-crystal x-ray diffraction. They initially called the mineral iron lazulite. [7]

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Wollastonite</span> Single chain calcium inosilicate (CaSiO3)

Wollastonite is a calcium inosilicate mineral (CaSiO3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature and pressure, which sometimes occurs in the presence of silica-bearing fluids as in skarns or in contact with metamorphic rocks. Associated minerals include garnets, vesuvianite, diopside, tremolite, epidote, plagioclase feldspar, pyroxene and calcite. It is named after the English chemist and mineralogist William Hyde Wollaston (1766–1828).

<span class="mw-page-title-main">Torbernite</span> Copper uranyl phosphate mineral

Torbernite, also known as chalcolite, is a relatively common mineral with the chemical formula Cu[(UO2)(PO4)]2(H2O)12. It is a radioactive, hydrated green copper uranyl phosphate, found in granites and other uranium-bearing deposits as a secondary mineral. The chemical formula of torbernite is similar to that of autunite in which a Cu2+ cation replaces a Ca2+ cation. Torbernite tends to dehydrate to metatorbernite with the sum formula Cu[(UO2)(PO4)]2(H2O)8.

<span class="mw-page-title-main">Almandine</span> Species of mineral belonging to the garnet group

Almandine, also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia Minor. Almandine is an iron alumina garnet, of deep red color, inclining to purple. It is frequently cut with a convex face, or en cabochon, and is then known as carbuncle. Viewed through the spectroscope in a strong light, it generally shows three characteristic absorption bands.

<span class="mw-page-title-main">Stishovite</span> Tetragonal form of silicon dioxide

Stishovite is an extremely hard, dense tetragonal form (polymorph) of silicon dioxide. It is very rare on the Earth's surface; however, it may be a predominant form of silicon dioxide in the Earth, especially in the lower mantle.

<span class="mw-page-title-main">Illite</span> Group of related non-expanding clay minerals

Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. The space between this T-O-T sequence of layers is occupied by poorly hydrated potassium cations which are responsible for the absence of swelling. Structurally, illite is quite similar to muscovite with slightly more silicon, magnesium, iron, and water and slightly less tetrahedral aluminium and interlayer potassium. The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small monoclinic grey to white crystals. Due to the small size, positive identification usually requires x-ray diffraction or SEM-EDS analysis. Illite occurs as an altered product of muscovite and feldspar in weathering and hydrothermal environments; it may be a component of sericite. It is common in sediments, soils, and argillaceous sedimentary rocks as well as in some low grade metamorphic rocks. The iron-rich member of the illite group, glauconite, in sediments can be differentiated by x-ray analysis.

<span class="mw-page-title-main">Lithiophilite</span>

Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend", as lithiophilite is usually found with lithium.

<span class="mw-page-title-main">Triphylite</span>

Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4. It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.

<span class="mw-page-title-main">Celsian</span>

Celsian is an uncommon feldspar mineral, barium aluminosilicate, BaAl2Si2O8. The mineral occurs in contact metamorphic rocks with significant barium content. Its crystal system is monoclinic, and it is white, yellow, or transparent in appearance. In pure form, it is transparent. Synthetic barium aluminosilicate is used as a ceramic in dental fillings and other applications.

<span class="mw-page-title-main">Pyroxferroite</span>

Pyroxferroite (Fe2+,Ca)SiO3 is a single chain inosilicate. It is mostly composed of iron, silicon and oxygen, with smaller fractions of calcium and several other metals. Together with armalcolite and tranquillityite, it is one of the three minerals which were discovered on the Moon during the 1969 Apollo 11 mission. It was then found in Lunar and Martian meteorites as well as a mineral in the Earth's crust. Pyroxferroite can also be produced by annealing synthetic clinopyroxene at high pressures and temperatures. The mineral is metastable and gradually decomposes at ambient conditions, but this process can take billions of years.

<span class="mw-page-title-main">Birnessite</span> Manganese hydroxide mineral

Birnessite (nominally MnO2·nH2O), also known as δ-MnO2, is a hydrous manganese dioxide mineral with a chemical formula of Na0.7Ca0.3Mn7O14·2.8H2O. It is the main manganese mineral species at the Earth's surface, and commonly occurs as fine-grained, poorly crystallized aggregates in soils, sediments, grain and rock coatings (e.g., desert varnish), and marine ferromanganese nodules and crusts. It was discovered at Birness, Aberdeenshire, Scotland.

<span class="mw-page-title-main">Ferrihydrite</span> Iron oxyhydroxide mineral

Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hydrothermal hot springs and scales, soils, and areas affected by mining. It can be precipitated directly from oxygenated iron-rich aqueous solutions, or by bacteria either as a result of a metabolic activity or passive sorption of dissolved iron followed by nucleation reactions. Ferrihydrite also occurs in the core of the ferritin protein from many living organisms, for the purpose of intra-cellular iron storage.

<span class="mw-page-title-main">Wadsleyite</span> Mineral thought to be abundant in the Earths mantle

Wadsleyite is an orthorhombic mineral with the formula β-(Mg,Fe)2SiO4. It was first found in nature in the Peace River meteorite from Alberta, Canada. It is formed by a phase transformation from olivine (α-(Mg,Fe)2SiO4) under increasing pressure and eventually transforms into spinel-structured ringwoodite (γ-(Mg,Fe)2SiO4) as pressure increases further. The structure can take up a limited amount of other bivalent cations instead of magnesium, but contrary to the α and γ structures, a β structure with the sum formula Fe2SiO4 is not thermodynamically stable. Its cell parameters are approximately a = 5.7 Å, b = 11.71 Å and c = 8.24 Å.

<span class="mw-page-title-main">Iddingsite</span>

Iddingsite is a microcrystalline rock that is derived from alteration of olivine. It is usually studied as a mineral, and consists of a mixture of remnant olivine, clay minerals, iron oxides, and ferrihydrites. Debates over iddingsite's non-definite crystal structure caused it to be de-listed as an official mineral by the IMA; thus, it is properly referred to as a rock.

<span class="mw-page-title-main">Beraunite</span>

Beraunite is an iron phosphate mineral. It was first described by August Breithaupt for an occurrence in Beraun currently in the Czech Republic. Beraunite occurs as a secondary mineral in iron ore deposits, and as an alteration product of primary phosphate minerals in granite pegmatites.

<span class="mw-page-title-main">Zinclipscombite</span>

Zinclipscombite is a dark-green to brown zinc iron phosphate mineral with the formula Zn(Fe3+)2(PO4)2(OH)2. It occurs as fibrous spheres and exhibits tetragonal crystal structure.

Paulscherrerite, UO2(OH)2, is a newly named mineral of the schoepite subgroup of hexavalent uranium hydrate/hydroxides. It is monoclinic, but no space group has been determined because no single-crystal study has been done. Paulscherrerite occurs as a canary yellow microcrystalline powdery product with a length of ~500 nm. It forms by the weathering and ultimate pseudomorphism of uranium-lead bearing minerals such as metaschoepite. The type locality for paulscherrerite is the Number 2 Workings, Radium Ridge near Mount Painter, North Flinders Ranges, South Australia, an area where radiogenic heat has driven hydrothermal activity for millions of years. It is named for Swiss physicist Paul Scherrer, co-inventor of the Debye-Scherrer X-ray powder diffraction camera. Study of paulscherrerite and related minerals is important for understanding the mobility of uranium around mining sites, as well as designing successful strategies for the storage of nuclear weapons and the containment of nuclear waste.

<span class="mw-page-title-main">Minnesotaite</span> Iron silicate mineral

Minnesotaite is an iron silicate mineral with formula: (Fe2+,Mg)3Si4O10(OH)2. It crystallizes in the triclinic crystal system and occurs as fine needles and platelets with other silicates. It is isostructural with the pyrophyllite-talc mineral group.

Robert Day Shannon is a retired research chemist formerly at DuPont de Nemours, Inc.

John Walter Gruner was a German-born American mineralogist, crystallographer, and geologist. He scientifically described and named two minerals: minnesotaite (1944) and groutite (1945).

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Lipscombite on Mindat
  3. 1 2 Lipscombite data on WebMineral
  4. Gheith, M. A. , Lipscombite: A New Synthetic Iron Lazulite, Amer. Mineral., 38, 612–628 (1953)
  5. Structures and Mechanisms: From Ashes to Enzymes (Acs Symposium Series) Gareth R. Eaton (Editor), Don C. Wiley (Editor), Oleg Jardetzky (Editor), American Chemical Society, Washington, DC (2002) (Autobiographical sketch by William Lipscomb, 14 pp. (Lipscombite: p. xvii). This chapter is online at pubs.acs.org. Click PDF symbols at right.
  6. Gheith, Mohamed A. Stability relations of ferric oxides and their hydrates. Lipscombite: a new synthetic iron lazulite. Thesis University of Minnesota (1951)
  7. Katz L., Lipscomb W. N. The crystal structure of iron lazulite, a synthetic mineral related to lazulite: Acta Crystallographica, 4, 345–348 (1951).

Gallery of lipscombite pictures at mindat.org.