List of piezoelectric materials

Last updated

This page lists properties of several commonly used piezoelectric materials.

Contents

Piezoelectric materials (PMs) can be broadly classified as either crystalline, ceramic, or polymeric. [1] The most commonly produced piezoelectric ceramics are lead zirconate titanate (PZT), barium titanate, and lead titanate. Gallium nitride and zinc oxide can also be regarded as a ceramic due to their relatively wide band gaps. Semiconducting PMs offer features such as compatibility with integrated circuits and semiconductor devices. Inorganic ceramic PMs offer advantages over single crystals, including ease of fabrication into a variety of shapes and sizes not constrained crystallographic directions. Organic polymer PMs, such as PVDF, have low Young's modulus compared to inorganic PMs. Piezoelectric polymers (PVDF, 240 mV-m/N) possess higher piezoelectric stress constants (g33), an important parameter in sensors, than ceramics (PZT, 11 mV-m/N), which show that they can be better sensors than ceramics. Moreover, piezoelectric polymeric sensors and actuators, due to their processing flexibility, can be readily manufactured into large areas, and cut into a variety of shapes. In addition polymers also exhibit high strength, high impact resistance, low dielectric constant, low elastic stiffness, and low density, thereby a high voltage sensitivity which is a desirable characteristic along with low acoustic and mechanical impedance useful for medical and underwater applications.

Among PMs, PZT ceramics are popular as they have a high sensitivity, a high g33 value. They are however brittle. Furthermore, they show low Curie temperature, leading to constraints in terms of applications in harsh environmental conditions. However, promising is the integration of ceramic disks into industrial appliances moulded from plastic. This resulted in the development of PZT-polymer composites, and the feasible integration of functional PM composites on large scale, by simple thermal welding or by conforming processes. Several approaches towards lead-free ceramic PM have been reported, such as piezoelectric single crystals (langasite), and ferroelectric ceramics with a perovskite structure and bismuth layer-structured ferroelectrics (BLSF), which have been extensively researched. Also, several ferroelectrics with perovskite-structure (BaTiO3 [BT], (Bi1/2Na1/2) TiO3 [BNT], (Bi1/2K1/2) TiO3 [BKT], KNbO3 [KN], (K, Na) NbO3 [KNN]) have been investigated for their piezoelectric properties.

Key piezoelectric properties

The following table lists the following properties for piezoelectric materials

Table

Single crystals
ReferenceMaterial & heterostructure used for the characterization (electrodes/material, electrode/substrate)OrientationPiezoelectric coefficients, d (pC/N)Relative permittivity, εrElectromechanical coupling factor, kQuality factor
Hutson 1963 [2] AlNd15 = -4.07perε33 = 11.4
d31 = -2
d33 = 5
Cook et al. 1963 [3] BaTiO3d15 = 392ε11 = 2920k15 = 0.57
d31 = -34.5ε33 = 168k31 = 0.315
d33 = 85.6k33 = 0.56
Warner et al. 1967 [4] LiNbO3 (Au-Au)<001>d15 = 68ε11 = 84
d22 = 21ε33 = 30
d31 = -1k31 = 0.02
d33 = 6kt = 0.17
Smith et al. 1971 [5] LiNbO3<001>d15 = 69.2ε11 = 85.2
d22 = 20.8ε33 = 28.2
d31 = -0.85
d33 = 6
Yamada et al. 1967 [6] LiNbO3 (Au-Au)<001>d15 = 74ε11 = 84.6
d22 = 21ε33 = 28.6k22 = 0.32
d31 = -0.87k31 = 0.023
d33 = 16k33 = 0.47
Yamada et al. 1969 [7] LiTaO3d15 = 26ε11 = 53
d22 = 8.5ε33 = 44
d31 = -3
d33 = 9.2
Cao et al. 2002 [8] PMN-PT (33%)d15 = 146ε11 = 1660k15 = 0.32
d31 = -1330ε33 = 8200k31 = 0.59
d33 = 2820k33 = 0.94
kt = 0.64
Badel et al. 2006 [9] PMN-25PT<110>d31 = -643ε33 = 2560k31 = -0.73362
Kobiakov 1980 [10] ZnOd15 = -8.3ε11 = 8.67k15 = 0.199
d31 = -5.12ε33 = 11.26k31 = 0.181
d33 = 12.3k33 = 0.466
Zgonik et al. 1994 [11] ZnO (pure with lithium dopant)d15 = -13.3kr = 8.2
d31 = -4.67
d33 = 12.0
Zgonik et al. 1994 [12] BaTiO3 single crystals[001] (single domain)d33 = 90
Zgonik et al. 1994 [12] BaTiO3 single crystals[111] (single domain)d33 = 224
Zgonik et al. 1994 [12] BaTiO3 single crystals[111] neutral (domain size of 100 ľm)d33 = 235ε33 = 1984k33 = 54.4
Zgonik et al. 1994 [12] BaTiO3 single crystals[111] neutral (domain size of 60 ľm)d33 = 241ε33 = 1959k33 = 55.9
Zgonik et al. 1994 [12] BaTiO3 single crystals[111] (domain size of 22 ľm)d33 = 256ε33 = 2008k33 = 64.7
Zgonik et al. 1994 [12] BaTiO3 single crystals[111] neutral (domain size of 15 ľm)d33 = 274ε33 = 2853k33 = 66.1
Zgonik et al. 1994 [12] BaTiO3 single crystals[111] neutral (domain size of 14 ľm)d33 = 289ε33 = 1962k33 = 66.7
Zgonik et al. 1994 [12] BaTiO3 single crystals[111] neutrald33 = 331ε33 = 2679k33 = 65.2
[13] LN crystald31 = -4.5

d33 = -0.27

Li et al. 2010 [14] PMNT31d33 = 2000ε33 = 5100k31 = 80
d31 = -750
Zhang et al. 2002 [15] PMNT31-A1400ε33 = 3600
Zhang et al. 2002 [15] PMNT31-B1500ε33 = 4800
Zhang et al. 2002 [15] PZNT4.5d33 = 2100ε33 = 4400k31 = 83
d31 = -900
Zhang et al. 2004 [16] PZNT8d33 = 2500ε33 = 6000k31 = 89
d31 = -1300
Zhang et al. 2004 [16] PZNT12d33 = 576ε33 = 870k31 = 52
d31 = -217
Yamashita et al. 1997 [17] PSNT33ε33 = 960/
Yasuda et al. 2001 [18] PINT28700ε33 = 1500/
Guo et al. 2003 [19] PINT342000ε33 = 5000/
Hosono et al. 2003 [20] PIMNT1950ε33 = 3630/
Zhang et al. 2002 [15] PYNT40d33 = 1200ε33 = 2700k31 = 76
d31 = -500
Zhang et al. 2012 [21] PYNT45d33 = 2000ε33 = 2000k31 = 78
Zhang et al. 2003 [22] BSPT57d33 = 1200ε33 = 3000k31 = 77
d31 = -560
Zhang et al. 2003 [23] BSPT58d33 = 1400ε33 = 3200k31 = 80
d31 = -670
Zhang et al. 2004 [16] BSPT66d33 = 440ε33 = 820k31 = 52
d31 = -162
Ye et al. 2008 [24] BSPT57d33 = 1150

d31 = -520

ε33 = 3000k31 = 0.52

k33 = 0.91

Ye et al. 2008 [24] BSPT66d33 = 440ε33 = 820k31 = 0.52

k33 = 0.88

d31 = -162
Ye et al. 2008 [24] PZNT4.5d33 = 2000

d31 = -970

ε33 = 5200k31 = 0.50

k33 = 0.91

Ye et al. 2008 [24] PZNT8d31 = -1455ε33 = 7700k31 = 0.60

k33 = 0.94

Ye et al. 2008 [24] PZNT12d33 = 576

d31 = -217

ε33 = 870k31 = 0.52

k33 = 0.86

Ye et al. 2008 [24] PMNT33d33 = 2820

d31 = -1330

ε33 = 8200k31 = 0.59

k33 = 0.94

Matsubara et al. 2004 [25] KCN-modified KNNd33 = 100

d31 = -180

ε33 = 220-330kp = 33-391200
Ryu et al. 2007 [26] KZT modifiedKNNd33 = 126ε33 = 590kp = 4258
Matsubara et al. 2005 [27] KCT modified KNNd33 = 190ε33 =kp = 421300
Wang et al. 2007 [28] Bi2O3 doped KNNd33 = 127ε33 = 1309kp = 28.3
Jiang et al. 2009 [29] doped KNN-0.005BFd33 = 257ε33 = 361kp= 5245
Ceramics
ReferenceMaterial & heterostructure used for the characterization (electrodes/material, electrode/substrate)OrientationPiezoelectric coefficients, d (pC/N)Relative permittivity, εrElectromechanical coupling factor, kQuality factor
Berlincourt et al. 1958 [30] BaTiO3d15 = 270ε11 = 1440k15 = 0.57
d31 = -79ε33 = 1680k31 = 0.49
d33 = 191k33 = 0.47
Tang et al. 2011 [31] BFOd33 = 37kt = 0.6
Zhang et al. 1999 [32] PMN-PTd31 = -74ε33 = 1170k31 = -0.312283
[33] PZT-5Ad31 = -171ε33 = 1700k31 = 0.34
d33 = 374k33 = 0.7
[34] PZT-5Hd15 = 741ε11 = 3130k15 = 0.6865
d31 = -274ε33 = 3400k31 = 0.39
d33 = 593k33 = 0.75
[35] PZT-5Kd33 = 870ε33 = 6200k33 = 0.75
Tanaka et al. 2009 [36] PZN7%PTd33 = 2400εr = 6500k33 = 0.94

kt = 0.55

Pang et al. 2010 [37] ANSZd33 = 2951.6145.584
Park et al. 2006 [38] KNN-BZd33 = 400257.448
Cho et al. 2007 [39] KNN-BTd33 = 2251.0636.0
Park et al. 2007 [40] KNN-STd33 = 2201.4540.070
Zhao et al. 2007 [41] KNN-CTd33 = 2411.3241.0
Zhang et al. 2006 [42] LNKNd33 = 314~70041.2
Saito et al. 2004 [43] KNN-LSd33 = 2701.3850.0
Saito et al. 2004 [43] LF4d33 = 3001.57
Tanaka et al. 2009 [36] Oriented LF4d33 = 4161.5761.0
Pang et al. 2010 [37] ANSZd33 = 2951.6145.584
Park et al. 2006 [38] KNN-BZd33 = 400257.448
Cho et al. 2007 [44] KNN-BTd33 = 2251.0636.0
Park et al. 2007 [40] KNN-STd33 = 2201.4540.070
Maurya et al. 2013 [45] KNN-CTd33 = 2411.3241.0
Maurya et al. 2013 [45] NBT-BT(001) Textured samplesd33 = 322...
Gao et al. 2008 [46] NBT-BT-KBT(001) Textured samplesd33 = 192
Zou et al. 2016 [47] NBT-KBT(001) Textured samplesd33 = 134kp= 35
Saito et al. 2004 [43] NBT-KBT(001) Textured samplesd33 = 217kp = 61
Chang et al. 2009 [48] KNLNTS(001) Textured samplesd33 = 416kp = 64
Chang et al. 2011 [49] KNNS(001) Textured samplesd33 = 208kp = 63
Hussain et al. 2013 [50] KNLN(001) Textured samplesd33 = 192kp = 60
Takao et al. 2006 [51] KNNT(001) Textured samplesd33 = 390kp = 54
Li et al. 2012 [52] KNN 1 CuO(001) Textured samplesd33 = 123kp = 54
Cho et al. 2012 [53] KNN-CuO(001) Textured samplesd33 = 133kp = 46
Hao et al. 2012 [54] NKLNT(001) Textured samplesd33 = 310kp = 43
Gupta et al. 2014 [55] KNLN(001) Textured samplesd33 = 254
Hao et al. 2012 [54] KNN(001) Textured samplesd33 = 180kp = 44
Bai et al. 2016 [56] BCZT(001) Textured samplesd33 = 470kp = 47
Ye et al. 2013 [57] BCZT(001) Textured samplesd33 = 462kp = 49
Schultheiß et al. 2017 [58] BCZT-T-H(001) Textured samplesd33 = 580
OMORI et al. 1990 [59] BCT(001) Textured samplesd33 = 170
Chan et al. 2008 [60] Pz34 (doped PbTiO3)d15 = 43.3ε33 = 237k31 = 4.6700
d31 = -5.1ε33 = 208k33 = 39.6
d33 = 46k15 = 22.8
kp = 7.4
Lee et al. 2009 [61] BNKLBTd33 = 163εr = 766k31 = 0.188142
ε33 = 444.3kt = 0.524
kp = 0.328
Sasaki et al. 1999 [62] KNLNTSεr = 1156k31 = 0.2680
ε33 = 746kt = 0.32
kp = 0.43
Takenaka et al. 1991 [63] (Bi0.5Na0.5)TiO3 (BNT)-based BNKTd31 = 46εr = 650kp = 0.27
d33 = 150k31 = 0.165
Tanaka et al. 1960 [64] (Bi0.5Na0.5)TiO3 (BNT)-based BNBTd31 = 40εr = 580k31 = 0.19
d33 = 12.5k33 = 0.55
Hutson 1960 [65] CdSd15 = -14.35
d31 = -3.67
d33 = 10.65
Schofield et al. 1957 [66] CdSd31 = -1.53
d33 = 2.56
Egerton et al. 1959 [67] BaCaOTid31 = -50k15 = 0.19400
d33 = 150k31 = 0.49
k33 = 0.325
Ikeda et al. 1961 [68] Nb2O6Pbd31 = -11kr = 0.0711
d33 = 80k31 = 0.045
k33 = 0.042
Ikeda et al. 1962 [69] C6H17N3O10Sd23 = 84k21 = 0.18
d21 = 22.7k22 = 0.18
d25 = 22k23 = 0.44
Brown et al. 1962 [70] BaTiO3 (95%) BaZrO3 (5%)k15 = 0.15200
d31 = -60k31 = 0.40
d33 = 150k33 = 0.28
Huston 1960 [65] BaNb2O6 (60%) Nb2O6Pb (40%)d31 = -25kr = 0.16
Baxter et al. 1960 [71] BaNb2O6 (50%) Nb2O6Pb (50%)d31= -36kr = 0.16
Pullin 1962 [72] BaTiO3 (97%) CaTiO3 (3%)d31 = -53ε33 = 1390k15 = 0.39
d33 = 135k31 = 0.17
k33 = 0.43
Berlincourt et al. 1960 [73] BaTiO3 (95%) CaTiO3 (5%)d15 = -257ε33 = 1355k15 = 0.495500
d31 = -58k31 = 0.19
d33 = 150k33 = 0.49
kr = 0.3
Berlincourt et al. 1960 [73] BaTiO3 (96%) PbTiO3 (4%)d31 = -38ε33 = 990k15 = 0.34
d33 = 105k31 = 0.14
k33 = 0.39
Jaffe et al. 1955 [74] PbHfO3 (50%) PbTiO3 (50%)d31 = -54kr = 0.38
Kell 1962 [75] Nb2O6Pb (80%) BaNb2O6 (20%)d31 = 25kr = 0.2015
Brown et al. 1962 [70] Nb2O6Pb (70%) BaNb2O6 (30%)d31 = -40ε33 = 900k31 = 0.13350
d33 = 100k33 = 0.3
kr = 0.24
Berlincourt et al. 1960 [76] PbTiO3 (52%) PbZrO3 (48%)d15 = 166k15 = 0.401170
d31 = -43k31 = 0.17
d33 = 110k33 = 0.43
kr = 0.28
Berlincourt et al. 1960 [77] PbTiO3 (50%) lead Zirconate (50%)d15 = 166k15 = 0.504950
d31 = -43k31 = 0.23
d33 = 110k33 = 0.546
kr = 0.397
Egerton et al. 1959 [67] KNbO3 (50%) NaNbO3 (50%)d31 = -32140
d33 = 80k31 = 0.21
k33 = 0.51
Brown et al. 1962 [70] NaNbO3 (80%) Cd2Nb2O7 (20%)d31 = -80ε33 = 2000k31 = 0.17
d33 = 200k33 = 0.42
kr = 0.30
Schofield et al. 1957 [66] BaTiO3 (95%) CaTiO3 (5%) CoCO3 (0.25%)d31 = -60ε33 = 1605kr = 0.33
Pullin 1962 [72] BaTiO3 (80%) PbTiO3 (12%) CaTiO3 (8%)d31 = -31k31 = 0.151200
d33 = 79k33 = 0.41
kr = 0.24
Defaÿ 2011 [78] AlN (Pt-Mo)d31 = -2.5
Shibata et al. 2011 [79] KNN(Pt-Pt)<001>d31 = -96.3εr = 1100
d33 = 138.2
Sessler 1981 [80] PVDFd31 = 17.9k31 = 10.3
d32 = 0.9k33 = 12.6
d33 = -27.1
Ren et al. 2017 [81] PVDFd31 = 23εr = 106
d32 = 2
d33 = -21
Tsubouchi et al. 1981 [82] Epi AlN/Al2O3<001>d33 = 5.53ε33 = 9.5kt = 6.52490
Nanomaterials
ReferenceMaterialStructurePiezoelectric coefficients, d (pC/N)Characterization methodSize (nm)
Ke et al. 2008 [83] NaNbO3nanowired33 = 0.85-4.26 pm/VPFMd = 100
Wang et al. 2008 [84] KNbO3nanowired33 = 0.9 pm/VPFMd = 100
Zhang et al. 2004 [85] PZTnanowirePFMd = 45
Zhao et al. 2004 [86] ZnOnanobeltd33 = 14.3-26.7 pm/VPFMw = 360 t = 65
Luo et al. 2003 [87] PZTnanoshelld33 = 90 pm/VPFMd = 700 t = 90
Yun et al. 2002 [88] BaTiO3nanowired33 = 0.5 pm/VPFMd = 120
Lin et al. 2008 [89] CdSnanowireBending with AFM tipd = 150
Wang et al. 2007 [90] PZTnanofiberpiezoelectric voltage constant~0.079 Vm/NBending using a tungsten probed = 10
Wang et al. 2007 [91] BaTiO3-d33 = 45 pC/NDirect tensile testd ~ 280
Jeong et al. 2014 [92] Alkaline niobate (KNLN)filmd33 = 310 pC/N-
Park et al. 2010 [93] BaTiO3Thin filmd33 = 190 pC/N
Stoppel et al. 2011 [94] AlNThin filmd33 =5 pC/NAFM
Lee et al. 2017 [95] WSe22D nanosheetd11 = 3.26 pm/V
Zhu et al. 2014 [96] MoS2Free standing layere11 = 2900pc/mAFM
Zhong et al. 2017 [97] PET/EVA/PETfilmd33 = 6300 pC/N

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