Single crystal

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Crystallization
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Fundamentals
Concepts
Methods and technology

In materials science, a single crystal (or single-crystal solid or monocrystalline solid) is a material in which the crystal lattice of the entire sample is continuous and unbroken to the edges of the sample, with no grain boundaries. [1] The absence of the defects associated with grain boundaries can give monocrystals unique properties, particularly mechanical, optical and electrical, which can also be anisotropic, depending on the type of crystallographic structure. [2] These properties, in addition to making some gems precious, are industrially used in technological applications, especially in optics and electronics. [3]

Contents

Because entropic effects favor the presence of some imperfections in the microstructure of solids, such as impurities, inhomogeneous strain and crystallographic defects such as dislocations, perfect single crystals of meaningful size are exceedingly rare in nature. [2] The necessary laboratory conditions often add to the cost of production. On the other hand, imperfect single crystals can reach enormous sizes in nature: several mineral species such as beryl, gypsum and feldspars are known to have produced crystals several meters across.[ citation needed ]

The opposite of a single crystal is an amorphous structure where the atomic position is limited to short-range order only. [4] In between the two extremes exist polycrystalline , which is made up of a number of smaller crystals known as crystallites , and paracrystalline phases. [5] Single crystals will usually have distinctive plane faces and some symmetry, where the angles between the faces will dictate its ideal shape. Gemstones are often single crystals artificially cut along crystallographic planes to take advantage of refractive and reflective properties. [5]

Production methods

Although current methods are extremely sophisticated with modern technology, the origins of crystal growth can be traced back to salt purification by crystallization in 2500 BCE. A more advanced method using an aqueous solution was started in 1600 CE while the melt and vapor methods began around 1850 CE. [6]

Single-crystal growth methods tree diagram Single Crystal Growth Methods Flow Chart .png
Single-crystal growth methods tree diagram

Basic crystal growth methods can be separated into four categories based on what they are artificially grown from: melt, solid, vapor, and solution. [2] Specific techniques to produce large single crystals (aka boules) include the Czochralski process (CZ), Floating zone (or Zone Movement), and the Bridgman technique. Dr. Teal and Dr. Little of Bell Telephone Laboratories were the first to use the Czochralski method to create Ge and Si single crystals. [7] Other methods of crystallization may be used, depending on the physical properties of the substance, including hydrothermal synthesis, sublimation, or simply solvent-based crystallization. [8] For example, a modified Kyropoulos method can be used to grow high quality 300 kg sapphire single crystals. [9] The Verneuil method, also called the flame-fusion method, was used in the early 1900s to make rubies before CZ. [6] The diagram on the right illustrates most of the conventional methods. There have been new breakthroughs such as chemical vapor depositions (CVD) along with different variations and tweaks to the existing methods. These are not shown in the diagram.

A single-crystal quartz bar grown by the hydrothermal method Quartz synthese.jpg
A single-crystal quartz bar grown by the hydrothermal method

In the case of metal single crystals, fabrication techniques also include epitaxy and abnormal grain growth in solids. [10] Epitaxy is used to deposit very thin (micrometer to nanometer scale) layers of the same or different materials on the surface of an existing single crystal. [11] Applications of this technique lie in the areas of semiconductor production, with potential uses in other nanotechnological fields and catalysis. [12]

It is extremely difficult to grow single crystals of the polymers. It is mainly because that the polymer chains are of different length and due to the various entropy reasons. However, topochemical reactions are one of the easy methods to get single crystals of the polymer.

Applications

Semiconductor industry

One of the most used single crystals is that of Silicon in the semiconductor industry. The four main production methods for semiconductor single crystals are from metallic solutions: liquid phase epitaxy (LPE), liquid phase electroepitaxy (LPEE), the traveling heater method (THM), and liquid phase diffusion (LPD). [13] However, there are many other single crystals besides inorganic single crystals capable semiconducting, including single-crystal organic semiconductors.

A high-purity (99.999 %) tantalum single crystal, made by the floating zone process, some single crystalline fragments of tantalum, and a high-purity (99.99% = 4N) 1 cm tantalum cube for comparison. This photo was taken by Alchemist-hp. Tantalum single crystal and 1cm3 cube.jpg
A high-purity (99.999 %) tantalum single crystal, made by the floating zone process, some single crystalline fragments of tantalum, and a high-purity (99.99% = 4N) 1 cm tantalum cube for comparison. This photo was taken by Alchemist-hp.

Monocrystalline silicon used in the fabrication of semiconductors and photovoltaics is the greatest use of single-crystal technology today. [14] In photovoltaics, the most efficient crystal structure will yield the highest light-to-electricity conversion. [15] On the quantum scale that microprocessors operate on, the presence of grain boundaries would have a significant impact on the functionality of field effect transistors by altering local electrical properties. [16] Therefore, microprocessor fabricators have invested heavily in facilities to produce large single crystals of silicon. The Czochralski method and floating zone are popular methods for the growth of Silicon crystals. [17]

Fluorescence of (9H-carbazol-9-yl)(4-chlorophenyl)methanone single crystal. ClPhCz monokristall.jpg
Fluorescence of (9H-carbazol-9-yl)(4-chlorophenyl)methanone single crystal.

Other inorganic semiconducting single crystals include GaAs, GaP, GaSb, Ge, InAs, InP, InSb, CdS, CdSe, CdTe, ZnS, ZnSe, and ZnTe. Most of these can also be tuned with various doping for desired properties. [18] Single-crystal graphene is also highly desired for applications in electronics and optoelectronics with its large carrier mobility and high thermal conductivity, and remains a topic of fervent research. [19] One of the main challenges has been growing uniform single crystals of bilayer or multilayer graphene over large areas; epitaxial growth and the new CVD (mentioned above) are among the new promising methods under investigation. [20]

Organic semiconducting single crystals are different from the inorganic crystals. The weak intermolecular bonds mean lower melting temperatures, and higher vapor pressures and greater solubility. [21] For single crystals to grow, the purity of the material is crucial and the production of organic materials usually require many steps to reach the necessary purity. [22] Extensive research is being done to look for materials that are thermally stable with high charge-carrier mobility. Past discoveries include naphthalene, tetracene, and 9,10-diphenylanthacene (DPA). [23] Triphenylamine derivatives have shown promise, and recently in 2021, the single-crystal structure of α-phenyl-4′-(diphenylamino)stilbene (TPA) grown using the solution method exhibited even greater potential for semiconductor use with its anisotropic hole transport property. [24]

Optical application

A huge KDP, potassium dihydrogen phosphate, crystal grown from a seed crystal in a supersaturated aqueous solution at LLNL which is to be cut into slices and used on the National Ignition Facility for frequency doubling and tripling. KDP crystal.jpg
A huge KDP, potassium dihydrogen phosphate, crystal grown from a seed crystal in a supersaturated aqueous solution at LLNL which is to be cut into slices and used on the National Ignition Facility for frequency doubling and tripling.

Single crystals have unique physical properties due to being a single grain with molecules in a strict order and no grain boundaries. [2] This includes optical properties, and single crystals of silicon is also used as optical windows because of its transparency at specific infrared (IR) wavelengths, making it very useful for some instruments. [4]

Sapphires: Also known as the alpha phase of aluminum oxide (Al2O3) to scientists, sapphire single crystals are widely used in hi-tech engineering. It can be grown from gaseous, solid, or solution phases. [9] The diameter of the crystals resulting from the growth method are important when considering electronic uses after. They are used for lasers and nonlinear optics. Some notable uses are as in the window of a biometric fingerprint reader, optical disks for long-term data storage, and X-ray interferometer. [2]

Indium Phosphide: These single crystals are particularly appropriate for combining optoelectronics with high-speed electronics in the form of optical fiber with its large-diameter substrates. [25] Other photonic devices include lasers, photodetectors, avalanche photo diodes, optical modulators and amplifiers, signal processing, and both optoelectronic and photonic integrated circuits. [26]

Aluminum oxide crystals Aluminum oxide cristals (corundum).jpg
Aluminum oxide crystals

Germanium: This was the material in the first transistor invented by Bardeen, Brattain, and Shockley in 1947. It is used in some gamma-ray detectors and infrared optics. [27] Now it has become the focus of ultrafast electronic devices for its intrinsic carrier mobility. [26]

Arsenide: Arsenide III can be combined with various elements such as B, Al, Ga, and In, with the GaAs compound being in high demand for wafers. [26]

Cadmium Telluride: CdTe crystals have several applications as substrates for IR imaging, electrooptic devices, and solar cells. [28] By alloying CdTe and ZnTe together room-temperature X-ray and gamma-ray detectors can be made. [26]

Electrical conductors

Metals can be produced in single-crystal form and provide a means to understand the ultimate performance of metallic conductors. It is vital for understanding the basic science such as catalytic chemistry, surface physics, electrons, and monochromators. [29] Production of metallic single crystals have the highest quality requirements and are grown, or pulled, in the form of rods. [30] Certain companies can produce specific geometries, grooves, holes, and reference faces along with varying diameters. [18]

Of all the metallic elements, silver and copper have the best conductivity at room temperature, setting the bar for performance. [31] The size of the market, and vagaries in supply and cost, have provided strong incentives to seek alternatives or find ways to use less of them by improving performance.

The conductivity of commercial conductors is often expressed relative to the International Annealed Copper Standard, according to which the purest copper wire available in 1914 measured around 100%. The purest modern copper wire is a better conductor, measuring over 103% on this scale. The gains are from two sources. First, modern copper is more pure. However, this avenue for improvement seems at an end. Making the copper purer still makes no significant improvement. Second, annealing and other processes have been improved. Annealing reduces the dislocations and other crystal defects which are sources of resistance. But the resulting wires are still polycrystalline. The grain boundaries and remaining crystal defects are responsible for some residual resistance. This can be quantified and better understood by examining single crystals.

Single-crystal copper did prove to have better conductivity than polycrystalline copper. [32]

Electrical resistivity ρ for silver (Ag) / copper (Cu) materials at room temperature (293 K) [33]
Materialρ (μΩ∙cm) IACS [34]
Single-crystal Ag, doped with 3 mol% Cu1.35127%
Single-crystal Cu, further processed [35] 1.472117.1%
Single-crystal Ag1.49115.4%
Single-crystal Cu1.52113.4%
High-purity Ag wire (polycrystalline)1.59108%
High-purity Cu wire (polycrystalline)1.67˃ 103%

However, the single-crystal copper not only became a better conductor than high purity polycrystalline silver, but with prescribed heat and pressure treatment could surpass even single-crystal silver. Although impurities are usually bad for conductivity, a silver single crystal with a small amount of copper substitutions proved to be the best.

As of 2009, no single-crystal copper is manufactured on a large scale industrially, but methods of producing very large individual crystal sizes for copper conductors are exploited for high performance electrical applications. These can be considered meta-single crystals with only a few crystals per meter of length.

Pigtail from single-crystal blade casting Pigtail from Single Crystal Blade Casting shown with Kennedy Half Dollar for size comparison.jpg
Pigtail from single-crystal blade casting

Single-crystal turbine blades

Another application of single-crystal solids is in materials science in the production of high strength materials with low thermal creep, such as turbine blades. [36] Here, the absence of grain boundaries actually gives a decrease in yield strength, but more importantly decreases the amount of creep which is critical for high temperature, close tolerance part applications. [37] Researcher Barry Piearcey found that a right-angle bend at the casting mold would decrease the number of columnar crystals and later, scientist Giamei used this to start the single-crystal structure of the turbine blade. [38]

In research

Single crystals are essential in research especially condensed-matter physics and all aspects of materials science such as surface science. [2] The detailed study of the crystal structure of a material by techniques such as Bragg diffraction and helium atom scattering is easier with single crystals because it is possible to study directional dependence of various properties and compare with theoretical predictions. [39] Furthermore, macroscopically averaging techniques such as angle-resolved photoemission spectroscopy or low-energy electron diffraction are only possible or meaningful on surfaces of single crystals. [40] [41] In superconductivity there have been cases of materials where superconductivity is only seen in single-crystalline specimen. [42] They may be grown for this purpose, even when the material is otherwise only needed in polycrystalline form.

As such, numerous new materials are being studied in their single-crystal form. The young field of metal-organic-frameworks (MOFs) is one of many which qualify to have single crystals. In January 2021 Dr. Dong and Dr. Feng demonstrated how polycyclic aromatic ligands can be optimized to produce large 2D MOF single crystals of sizes up to 200 μm. This could mean scientists can fabricate single-crystal devices and determine intrinsic electrical conductivity and charge transport mechanism. [43]

The field of photodriven transformation can also be involved with single crystals with something called single-crystal-to-single-crystal (SCSC) transformations. These provide direct observation of molecular movement and understanding of mechanistic details. [44] This photoswitching behavior has also been observed in cutting-edge research on intrinsically non-photo-responsive mononuclear lanthanide single-molecule-magnets (SMM). [45]

See also

Related Research Articles

<span class="mw-page-title-main">Chemical vapor deposition</span> Method used to apply surface coatings

Chemical vapor deposition (CVD) is a vacuum deposition method used to produce high-quality, and high-performance, solid materials. The process is often used in the semiconductor industry to produce thin films.

A semiconductor is a material that has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity generally falls as its temperature rises; metals behave in the opposite way. In many cases their conducting properties may be altered in useful ways by introducing impurities ("doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits.

<span class="mw-page-title-main">Gallium arsenide</span> Chemical compound

Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a zinc blende crystal structure.

<span class="mw-page-title-main">Czochralski method</span> Method of crystal growth

The Czochralski method, also Czochralski technique or Czochralski process, is a method of crystal growth used to obtain single crystals of semiconductors, metals, salts and synthetic gemstones. The method is named after Polish scientist Jan Czochralski, who invented the method in 1915 while investigating the crystallization rates of metals. He made this discovery by accident: instead of dipping his pen into his inkwell, he dipped it in molten tin, and drew a tin filament, which later proved to be a single crystal. The method is still used in over 90 percent of all electronics in the world that use semiconductors.

<span class="mw-page-title-main">Silicon carbide</span> Extremely hard semiconductor

Silicon carbide (SiC), also known as carborundum, is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal since 1893 for use as an abrasive. Grains of silicon carbide can be bonded together by sintering to form very hard ceramics that are widely used in applications requiring high endurance, such as car brakes, car clutches and ceramic plates in bulletproof vests. Large single crystals of silicon carbide can be grown by the Lely method and they can be cut into gems known as synthetic moissanite.

<span class="mw-page-title-main">Epitaxy</span> Crystal growth process relative to the substrate

Epitaxy refers to a type of crystal growth or material deposition in which new crystalline layers are formed with one or more well-defined orientations with respect to the crystalline seed layer. The deposited crystalline film is called an epitaxial film or epitaxial layer. The relative orientation(s) of the epitaxial layer to the seed layer is defined in terms of the orientation of the crystal lattice of each material. For most epitaxial growths, the new layer is usually crystalline and each crystallographic domain of the overlayer must have a well-defined orientation relative to the substrate crystal structure. Epitaxy can involve single-crystal structures, although grain-to-grain epitaxy has been observed in granular films. For most technological applications, single-domain epitaxy, which is the growth of an overlayer crystal with one well-defined orientation with respect to the substrate crystal, is preferred. Epitaxy can also play an important role while growing superlattice structures.

<span class="mw-page-title-main">Thermoelectric materials</span> Materials whose temperature variance leads to voltage change

Thermoelectric materials show the thermoelectric effect in a strong or convenient form.

<span class="mw-page-title-main">Synthetic diamond</span> Diamond created by controlled processes

Laboratory-grown (LGD), also called lab-grown diamond, laboratory-created, man-made, artisan-created, artificial, synthetic, or cultured diamond, is diamond that is produced in a controlled technological process. Unlike diamond simulants, synthetic diamonds are composed of the same material as naturally formed diamonds—pure carbon crystallized in an isotropic 3D form—and share identical chemical and physical properties. As of 2023 the heaviest synthetic diamond ever made weighs 30.18 ct, and the heaviest natural diamond ever found weighs 3167 ct.

Organic semiconductors are solids whose building blocks are pi-bonded molecules or polymers made up by carbon and hydrogen atoms and – at times – heteroatoms such as nitrogen, sulfur and oxygen. They exist in the form of molecular crystals or amorphous thin films. In general, they are electrical insulators, but become semiconducting when charges are either injected from appropriate electrodes, upon doping or by photoexcitation.

<span class="mw-page-title-main">Bridgman–Stockbarger method</span> Method of crystallization

The Bridgman–Stockbarger method, or Bridgman–Stockbarger technique, is named after physicist Percy Williams Bridgman (1882–1961) and physicist Donald C. Stockbarger (1895–1952). The method includes two similar but distinct techniques primarily used for growing boules, but which can be used for solidifying polycrystalline ingots as well.

<span class="mw-page-title-main">Aluminium nitride</span> Nitride of aluminum

Aluminium nitride (AlN) is a solid nitride of aluminium. It has a high thermal conductivity of up to 321 W/(m·K) and is an electrical insulator. Its wurtzite phase (w-AlN) has a band gap of ~6 eV at room temperature and has a potential application in optoelectronics operating at deep ultraviolet frequencies.

<span class="mw-page-title-main">Oxygen-free copper</span> Pure copper without oxygen in its crystal lattice

Oxygen-free copper (OFC) or oxygen-free high thermal conductivity (OFHC) copper is a group of wrought high-conductivity copper alloys that have been electrolytically refined to reduce the level of oxygen to 0.001% or below. Oxygen-free copper is a premium grade of copper that has a high level of conductivity and is virtually free from oxygen content. The oxygen content of copper affects its electrical properties and can reduce conductivity.

<span class="mw-page-title-main">Tin selenide</span> Chemical compound

Tin selenide, also known as stannous selenide, is an inorganic compound with the formula SnSe. Tin(II) selenide is a typical layered metal chalcogenide as it includes a group 16 anion (Se2−) and an electropositive element (Sn2+), and is arranged in a layered structure. Tin(II) selenide is a narrow band-gap (IV-VI) semiconductor structurally analogous to black phosphorus. It has received considerable interest for applications including low-cost photovoltaics, and memory-switching devices.

<span class="mw-page-title-main">Diindenoperylene</span> Chemical compound

Diindenoperylene (DIP) is an organic semiconductor which receives attention because of its potential application in optoelectronics (solar cells, OLEDs) and electronics (RFID tags). DIP is a planar perylene derivative with two indeno-groups attached to opposite sides of the perylene core. Its chemical formula is C32H16, the full chemical name is diindeno[1,2,3-cd:1',2',3'-lm]perylene. Its chemical synthesis has been described.

Monocrystalline silicon, more often called single-crystal silicon, in short mono c-Si or mono-Si, is the base material for silicon-based discrete components and integrated circuits used in virtually all modern electronic equipment. Mono-Si also serves as a photovoltaic, light-absorbing material in the manufacture of solar cells.

<span class="mw-page-title-main">Solid</span> State of matter

Solid is one of the four fundamental states of matter along with liquid, gas, and plasma. The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas. The atoms in a solid are bound to each other, either in a regular geometric lattice, or irregularly. Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because the molecules in a gas are loosely packed.

<span class="mw-page-title-main">Transparent conducting film</span> Optically transparent and electrically conductive material

Transparent conducting films (TCFs) are thin films of optically transparent and electrically conductive material. They are an important component in a number of electronic devices including liquid-crystal displays, OLEDs, touchscreens and photovoltaics. While indium tin oxide (ITO) is the most widely used, alternatives include wider-spectrum transparent conductive oxides (TCOs), conductive polymers, metal grids and random metallic networks, carbon nanotubes (CNT), graphene, nanowire meshes and ultra thin metal films.

<span class="mw-page-title-main">Crystalline silicon</span> Semiconducting material used in solar cell technology

Crystalline silicon or (c-Si) Is the crystalline forms of silicon, either polycrystalline silicon, or monocrystalline silicon. Crystalline silicon is the dominant semiconducting material used in photovoltaic technology for the production of solar cells. These cells are assembled into solar panels as part of a photovoltaic system to generate solar power from sunlight.

<span class="mw-page-title-main">Polycrystalline silicon</span> High purity form of silicon

Polycrystalline silicon, or multicrystalline silicon, also called polysilicon, poly-Si, or mc-Si, is a high purity, polycrystalline form of silicon, used as a raw material by the solar photovoltaic and electronics industry.

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  33. ↑ Ji Young Kim; Min-Wook Oh; Seunghun Lee; Yong Chan Cho; Jang-Hee Yoon; Geun Woo Lee; Chae-Ryong Cho; Chul Hong Park; Se-Young Jeong (June 26, 2014). "Abnormal drop in electrical resistivity with impurity doping of single-crystal Ag". Scientific Reports. 4: 5450. Bibcode:2014NatSR...4E5450K. doi:10.1038/srep05450. PMC   4071311 . PMID   24965478.
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  43. ↑ Dong, Renhao; Feng, Xinliang (February 2021). "Making large single crystals of 2D MOFs". Nature Materials. 20 (2): 122–123. Bibcode:2021NatMa..20..122D. doi:10.1038/s41563-020-00912-1. PMID   33504985. S2CID   231745364.
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  45. ↑ Hojorat, Maher; Al Sabea, Hassan; Norel, Lucie; Bernot, Kevin; Roisnel, Thierry; Gendron, Frederic; Guennic, Boris Le; Trzop, Elzbieta; Collet, Eric; Long, Jeffrey R.; Rigaut, Stéphane (15 January 2020). "Hysteresis Photomodulation via Single-Crystal-to-Single-Crystal Isomerization of a Photochromic Chain of Dysprosium Single-Molecule Magnets" (PDF). Journal of the American Chemical Society. 142 (2): 931–936. doi:10.1021/jacs.9b10584. PMID   31880442. S2CID   209490756.

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