Lithium chloride (data page)

Last updated

This page provides supplementary chemical data on Lithium chloride.

Contents

Solubility

Solubility of LiCl in various solvents
(g LiCl / 100g of solvent at 25 °C)
H2O 84.5
Liquid ammonia 3.02
Liquid sulfur dioxide 0.012
Methanol 21 - 41
Formic acid 27.5
Sulfolane 1.5
Acetonitrile 0.14
Acetone 0.83
Formamide 28.2
Dimethylformamide 11 - 28
Reference:
Burgess, J. Metal Ions in Solution
(Ellis Horwood, New York, 1978)
ISBN   0-85312-027-7

Thermodynamic properties

Phase behavior
Triple point  ? K (? °C), ? Pa
Critical point  ? K (? °C), ? Pa
Std enthalpy
of fusionΔfusHo		+19.9 kJ/mol
Std entropy
of fusionΔfusSo		 ? J/(mol·K)
Std enthalpy
of vaporizationΔvapHo		 ? kJ/mol
Std entropy
of vaporizationΔvapSo		 ? J/(mol·K)
Solid properties
Std enthalpy
of formation ΔfHosolid		−408.27 kJ/mol
Standard molar entropy
Sosolid		59.33 J/(mol K)
Heat capacity cp47.99 J/(mol K)
Liquid properties
Std enthalpy
of formation ΔfHoliquid		−390.76 kJ/mol
Standard molar entropy
Soliquid		 ? J/(mol K)
Heat capacity cp ? J/(mol K)
Gas properties
Std enthalpy
of formation ΔfHogas		−195.2 kJ/mol
Standard molar entropy
Sogas		212.7 J/(mol K)
Heat capacity cp33.2 J/(mol K)

Spectral data

UV-Vis
Lambda-max  ? nm
Extinction coefficient  ?
IR
Major absorption bands ? cm −1
NMR
Proton NMR
Carbon-13 NMR
Other NMR data
MS
Masses of
main fragments

Structure and properties data

Structure and properties
Index of refraction 1.662
Dielectric constant  ? C2/(N·m2) at ? °C
Bond strength  ?
Bond length ?
Magnetic susceptibility -24.3 cgs units

Temperature Relative Humidity over saturated solution in water [1]

Temperature(C)Relative Humidity(%)
0.2314.7
9.5613.4
19.2212.4
29.6411.8
39.6411.8
46.7611.4

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions.

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Related Research Articles

Standard temperature and pressure (STP) are standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union of Pure and Applied Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), although these are not universally accepted standards. Other organizations have established a variety of alternative definitions for their standard reference conditions.

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References

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