Identifiers | |
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3D model (JSmol) | |
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Properties | |
F4HoLi | |
Molar mass | 247.86 g·mol−1 |
Related compounds | |
Other cations | Yttrium lithium fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lithium holmium fluoride is a ternary salt with chemical formula LiHoF4. At temperatures below 1.53 K, it is ferromagnetic described by the Ising model, but the interaction coefficients arise through superexchange. [1] [2] Above that temperature, it paramagnetizes. [2] Even at 0 K, LiHoF4 exhibits a quantum phase transition, aligning with an external magnetic field. [3]
Ferromagnetism is a property of certain materials that results in a significant, observable magnetic permeability, and in many cases, a significant magnetic coercivity, allowing the material to form a permanent magnet. Ferromagnetic materials are familiar metals that are noticeably attracted to a magnet, a consequence of their substantial magnetic permeability. Magnetic permeability describes the induced magnetization of a material due to the presence of an external magnetic field. This temporarily induced magnetization, for example, inside a steel plate, accounts for its attraction to the permanent magnet. Whether or not that steel plate acquires a permanent magnetization itself depends not only on the strength of the applied field but on the so-called coercivity of the ferromagnetic material, which can vary greatly.
Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.
In chemistry, thermodynamics, and other related fields, a phase transition is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point.
In physics and materials science, the Curie temperature (TC), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Curie temperature is named after Pierre Curie, who showed that magnetism was lost at a critical temperature.
The Ising model, named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent magnetic dipole moments of atomic "spins" that can be in one of two states. The spins are arranged in a graph, usually a lattice, allowing each spin to interact with its neighbors. Neighboring spins that agree have a lower energy than those that disagree; the system tends to the lowest energy but heat disturbs this tendency, thus creating the possibility of different structural phases. The model allows the identification of phase transitions as a simplified model of reality. The two-dimensional square-lattice Ising model is one of the simplest statistical models to show a phase transition.
A magnon is a quasiparticle, a collective excitation of the spin structure of an electron in a crystal lattice. In the equivalent wave picture of quantum mechanics, a magnon can be viewed as a quantized spin wave. Magnons carry a fixed amount of energy and lattice momentum, and are spin-1, indicating they obey boson behavior.
Jellium, also known as the uniform electron gas (UEG) or homogeneous electron gas (HEG), is a quantum mechanical model of interacting electrons in a solid where the positive charges are assumed to be uniformly distributed in space; the electron density is a uniform quantity as well in space. This model allows one to focus on the effects in solids that occur due to the quantum nature of electrons and their mutual repulsive interactions without explicit introduction of the atomic lattice and structure making up a real material. Jellium is often used in solid-state physics as a simple model of delocalized electrons in a metal, where it can qualitatively reproduce features of real metals such as screening, plasmons, Wigner crystallization and Friedel oscillations.
Magnetic semiconductors are semiconductor materials that exhibit both ferromagnetism and useful semiconductor properties. If implemented in devices, these materials could provide a new type of control of conduction. Whereas traditional electronics are based on control of charge carriers, practical magnetic semiconductors would also allow control of quantum spin state. This would theoretically provide near-total spin polarization, which is an important property for spintronics applications, e.g. spin transistors.
Critical exponents describe the behavior of physical quantities near continuous phase transitions. It is believed, though not proven, that they are universal, i.e. they do not depend on the details of the physical system, but only on some of its general features. For instance, for ferromagnetic systems, the critical exponents depend only on:
Multiferroics are defined as materials that exhibit more than one of the primary ferroic properties in the same phase:
A spin ice is a magnetic substance that does not have a single minimal-energy state. It has magnetic moments (i.e. "spin") as elementary degrees of freedom which are subject to frustrated interactions. By their nature, these interactions prevent the moments from exhibiting a periodic pattern in their orientation down to a temperature much below the energy scale set by the said interactions. Spin ices show low-temperature properties, residual entropy in particular, closely related to those of common crystalline water ice. The most prominent compounds with such properties are dysprosium titanate (Dy2Ti2O7) and holmium titanate (Ho2Ti2O7). The orientation of the magnetic moments in spin ice resembles the positional organization of hydrogen atoms (more accurately, ionized hydrogen, or protons) in conventional water ice (see figure 1).
A quantum critical point is a point in the phase diagram of a material where a continuous phase transition takes place at absolute zero. A quantum critical point is typically achieved by a continuous suppression of a nonzero temperature phase transition to zero temperature by the application of a pressure, field, or through doping. Conventional phase transitions occur at nonzero temperature when the growth of random thermal fluctuations leads to a change in the physical state of a system. Condensed matter physics research over the past few decades has revealed a new class of phase transitions called quantum phase transitions which take place at absolute zero. In the absence of the thermal fluctuations which trigger conventional phase transitions, quantum phase transitions are driven by the zero point quantum fluctuations associated with Heisenberg's uncertainty principle.
In statistical physics, the axialnext-nearest neighbor Ising model, usually known as the ANNNI model, is a variant of the Ising model. In the ANNNI model, competing ferromagnetic and antiferromagnetic exchange interactions couple spins at nearest and next-nearest neighbor sites along one of the crystallographic axes of the lattice.
Ferromagnetic superconductors are materials that display intrinsic coexistence of ferromagnetism and superconductivity. They include UGe2, URhGe, and UCoGe. Evidence of ferromagnetic superconductivity was also reported for ZrZn2 in 2001, but later reports question these findings. These materials exhibit superconductivity in proximity to a magnetic quantum critical point.
Iron-based superconductors (FeSC) are iron-containing chemical compounds whose superconducting properties were discovered in 2006. In 2008, led by recently discovered iron pnictide compounds, they were in the first stages of experimentation and implementation..
In magnetism, a nanomagnet is a nanoscopic scale system that presents spontaneous magnetic order (magnetization) at zero applied magnetic field (remanence).
Subir Sachdev is Herchel Smith Professor of Physics at Harvard University specializing in condensed matter. He was elected to the U.S. National Academy of Sciences in 2014, and received the Lars Onsager Prize from the American Physical Society and the Dirac Medal from the ICTP in 2018. He was a co-editor of the Annual Review of Condensed Matter Physics from 2017–2019.
In statistical mechanics, the Griffiths inequality, sometimes also called Griffiths–Kelly–Sherman inequality or GKS inequality, named after Robert B. Griffiths, is a correlation inequality for ferromagnetic spin systems. Informally, it says that in ferromagnetic spin systems, if the 'a-priori distribution' of the spin is invariant under spin flipping, the correlation of any monomial of the spins is non-negative; and the two point correlation of two monomial of the spins is non-negative.
Quantum simulators permit the study of a quantum system in a programmable fashion. In this instance, simulators are special purpose devices designed to provide insight about specific physics problems. Quantum simulators may be contrasted with generally programmable "digital" quantum computers, which would be capable of solving a wider class of quantum problems.
In condensed matter physics, an Arrott plot is a plot of the square of the magnetization of a substance, against the ratio of the applied magnetic field to magnetization at one fixed temperature(s). Arrott plots are an easy way of determining the presence of ferromagnetic order in a material. They are named after American physicist Anthony Arrott who introduced them as a technique for studying magnetism in 1957.