Manganvesuvianite

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Manganvesuvianite
Manganvesuvianite-122296.jpg
Manganvesuvianite from Wessels Mine, Northern Cape Province, South Africa (4.2 x 3.9 x 3.3 cm)
General
Category Sorosilicates
Formula
(repeating unit)
Ca19Mn3+(Al,Mn3+,Fe3+)10(Mg,Mn2+)2(Si2O7)4(SiO4)10O(OH)9
IMA symbol Mnves [1]
Strunz classification 9.BG.35
Dana classification58.02.04.04 [2]
Crystal system Tetragonal
Crystal class Dipyramidal (4/m)
(same H-M symbol)
Space group P4/n
Unit cell a = 15.575 Å, c = 11.824 Å, Z = 2
Identification
ColorDeep red-brown, red, nearly black
Cleavage None observed
Fracture Conchoidal
Mohs scale hardness6 to 7
Luster Vitreous
Streak White
Diaphaneity Transparent, translucent, opaque
Optical propertiesUniaxial (-)
Refractive index nω = 1.735, nε = 1.724
Birefringence δ = 0.012
Pleochroism Strong
References [3]

Manganvesuvianite is a rare mineral with formula Ca19Mn3+(Al,Mn3+,Fe3+)10(Mg,Mn2+)2(Si2O7)4(SiO4)10O(OH)9. The mineral is red to nearly black in color. Discovered in South Africa and described in 2002, it was so named for the prevalence of manganese in its composition and its relation to vesuvianite.

Contents

Occurrence and formation

Manganvesuvianite crystals occur as long prisms up to 1.5 cm (0.59 in). [4] Small crystals are transparent and red to lilac in color; large crystals are opaque and nearly black in color with dark-red internal reflections. [5] Strongly zoned crystals less than 0.2 mm (0.0079 in) in size constitute rock-forming manganvesuvianite. [6]

As of 2012, manganvesuvianite has been found at two locations in South Africa. [3] It formed at temperatures of 250 to 400 °C (482 to 752 °F) by the hydrothermal alteration of sedimentary and metamorphic manganese ores. Crystallization occurred in fault planes and lenticular bodies in the ore bed or by filling veins and vugs. [7] Manganvesuvianite has been found in association with calcite, manganese-poor grossular, hydrogrossular-henritermierite, mozartite, serandite-pectolite, strontiopiemontite-tweddillite, and xonotlite. [8]

Manganvesuvianite is a member of the vesuvianite group and is the manganese analogue of vesuvianite. [3]

History

In 1883, Arnold von Lasaulx made the first detailed description of vesuvianite containing up to 3.2 wt% MnO from Lower Silesia in Poland. [9] Studies in the 1980s and 1990s revealed that the vesuvianite group was more complex than previously assumed, necessitating the definition of new minerals. [4] In 2000, vesuvianite was found containing up to 14.3 wt% MnO from the Kalahari manganese fields of Northern Cape Province, South Africa. [10] Manganvesuvianite proper was discovered in the Wessels ( 27°6′56.43″S22°51′27.87″E / 27.1156750°S 22.8577417°E / -27.1156750; 22.8577417 ) and N'Chwaning (shaft II; 27°8′6.84″S22°51′55.99″E / 27.1352333°S 22.8655528°E / -27.1352333; 22.8655528 ) mines of the Kalahari manganese fields [3] and described in 2002 in the journal Mineralogical Magazine. [7] It was named manganvesuvianite for the significant manganese in its formula and its relation to vesuvianite. [3] The mineral and name were approved by the IMA Commission on New Minerals and Mineral Names (IMA 2000-40). [3] [7] The type specimen from the N'Chwaning II Mine is held at the Natural History Museum of Bern in Switzerland. [11]

Related Research Articles

<span class="mw-page-title-main">Axinite</span>

Axinite is a brown to violet-brown, or reddish-brown bladed group of minerals composed of calcium aluminium boro-silicate, (Ca,Fe,Mn)3Al2BO3Si4O12OH. Axinite is pyroelectric and piezoelectric.

<span class="mw-page-title-main">Vesuvianite</span> Silicate mineral

Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within included blocks or adjacent to lavas on Mount Vesuvius, hence its name. Attractive-looking crystals are sometimes cut as gemstones. Localities which have yielded fine crystallized specimens include Mount Vesuvius and the Ala Valley near Turin, Piedmont.

<span class="mw-page-title-main">Grossular</span> Garnet, nesosilicate mineral

Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.

<span class="mw-page-title-main">Braunite</span>

Braunite is a silicate mineral containing both di- and tri-valent manganese with the chemical formula: Mn2+Mn3+6[O8|SiO4]. Common impurities include iron, calcium, boron, barium, titanium, aluminium, and magnesium.

Geigerite is a mineral, a complex hydrous manganese arsenate with formula: Mn5(AsO3OH)2(AsO4)2·10H2O. It forms triclinic pinacoidal, vitreous, colorless to red to brown crystals. It has a Mohs hardness of 3 and a specific gravity of 3.05.

<span class="mw-page-title-main">Eosphorite</span> Phosphate mineral

Eosphorite is a brown (occasionally pink) manganese hydrous phosphate mineral with chemical formula: MnAl(PO4)(OH)2·H2O. It is used as a gemstone.

<span class="mw-page-title-main">Cabalzarite</span>

Cabalzarite is a rare arsenate mineral with the chemical formula Ca(Mg,Al,Fe3+
)
2
[AsO
4
]
2
•2(H
2
O,OH)
. It is a member of the tsumcorite group. It crystallizes in the monoclinic system and typically occurs as clusters of crystals or granular aggregates.

<span class="mw-page-title-main">Hodgkinsonite</span>

Hodgkinsonite is a rare zinc manganese silicate mineral Zn2MnSiO4(OH)2. It crystallizes in the monoclinic system and typically forms radiating to acicular prismatic crystals with variable color from pink, yellow-red to deep red. Hodgkinsonite was discovered in 1913 by H. H. Hodgkinson, for whom it is named in Franklin, New Jersey, and it is only found in that area.

<span class="mw-page-title-main">Kanoite</span>

Kanoite is a light pinkish brown silicate mineral that is found in metamorphic rocks. It is an inosilicate and has a chemical formula of (Mg,Mn2+)2Si2O6. It is a member of pyroxene group and clinopyroxene subgroup.

<span class="mw-page-title-main">Shigaite</span>

Shigaite is a mineral with formula NaAl3(Mn2+)6(SO4)2(OH)18·12H2O that typically occurs as small, hexagonal crystals or thin coatings. It is named for Shiga Prefecture, Japan, where it was discovered in 1985. The formula was significantly revised in 1996, identifying sodium as a previously unknown constituent.

<span class="mw-page-title-main">Serandite</span> Mineral

Serandite is a mineral with formula Na(Mn2+,Ca)2Si3O8(OH). The mineral was discovered in Guinea in 1931 and named for J. M. Sérand. Serandite is generally red, brown, black or colorless. The correct name lacks an accent.

Gatehouseite is a manganese hydroxy phosphate mineral with formula Mn5(PO4)2(OH)4. First discovered in 1987, it was identified as a new mineral species in 1992 and named for Bryan M. K. C. Gatehouse (born 1932). As of 2012, it is known from only one mine in South Australia.

<span class="mw-page-title-main">Leucophoenicite</span>

Leucophoenicite is a mineral with formula Mn7(SiO4)3(OH)2. Generally brown to red or pink in color, the mineral gets its name from the Greek words meaning "pale purple-red". Leucophoenicite was discovered in New Jersey, US and identified as a new mineral in 1899.

<span class="mw-page-title-main">Sarkinite</span>

Sarkinite, synonymous with chondrarsenite and polyarsenite, is a mineral with formula Mn2(AsO4)(OH). The mineral is named for the Greek word σάρκιυος, meaning made of flesh, for its red color and greasy luster. The mineral was first noted in Sweden in 1865 as chondrarsenite, though not identified as sarkinite until 1885.

<span class="mw-page-title-main">Ruizite</span>

Ruizite is a sorosilicate mineral with formula Ca2Mn2Si4O11(OH)4·2H2O. It was discovered at the Christmas mine in Christmas, Arizona, and described in 1977. The mineral is named for discoverer Joe Ana Ruiz.

<span class="mw-page-title-main">Perettiite-(Y)</span>

Perettiite-(Y) is a complex silicate–borate mineral with the formula Y2Mn4FeSi2B8O24. It was first discovered in 2015 by Adolf Peretti of the Gemresearch Swisslab (GRS). It was found as inclusions in a phenakite crystal from Mogok, Myanmar.

Cyprine is a copper-rich member of the vesuvianite group with the formula Ca19Cu2+(Al10Mg2)Si18O68(OH)10. A similar name is given to a Cu-bearing variety but not Cu-dominant member within the group. Cyprine (sensu stricto) was discovered in the Wessels mine in the vicinity of Hotazel, Kalahari Manganese Field, South Africa.

<span class="mw-page-title-main">Sturmanite</span>

Sturmanite is a rare sulfate mineral with the chemical formula Ca6Fe3+2(SO4)2.5(B(OH)4)(OH)12 · 25 H2O. It crystallises in the tetragonal system and it has a Moh's hardness of 2.5. Sturmanite has a bright yellow to amber colour and falls in the ettringite group. It was named after Bozidar Darko Sturman (born 1937), Croatian-Canadian mineralogist and Curator Emeritus of Mineralogy, Royal Ontario Museum.

<span class="mw-page-title-main">Inesite</span>

Inesite is a hydrous calcium manganese silicate mineral. Its chemical formula is Ca2Mn7Si10O28(OH)2•5(H2O). Inesite is an inosilicate with a triclinic crystal system. It has a Mohs hardness of 5.5 to 6, and a specific gravity of 3.0. Its name originates from the Greek Ίνες (ines), "fibers" in allusion to its color and habit.

Effenbergerite is the natural occurrence of the color Han blue.It was first found in the Wessels mine, Kalahari Manganese Field, South Africa. Effenbergerite was approved as a valid mineral species by the IMA in 1993.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Manganvesuvianite". Webmineral. Retrieved July 22, 2012.
  3. 1 2 3 4 5 6 "Manganvesuvianite". Mindat. Retrieved July 22, 2012.
  4. 1 2 Armbruster 2002, p. 138.
  5. Armbruster 2002, pp. 138–9.
  6. Armbruster 2002, p. 139.
  7. 1 2 3 Armbruster 2002, p. 137.
  8. Armbruster 2002, pp. 139–40.
  9. Armbruster 2000, p. 571.
  10. Armbruster 2000, p. 570.
  11. Armbruster 2002, p. 140.
Bibliography

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