A marl lake is a type of alkaline lake whose bottom sediments include large deposits of marl, a mixture of clay and carbonate minerals. The term is particularly applied to lakes that have been dredged or mined for marl, often for manufacturing Portland cement.
Marl lakes are found around the Great Lakes of North America, in Britain, and in other areas that were once glaciated. They support distinctive ecological communities that are vulnerable to damage from silting, nutrient pollution, drainage, and invasive species.
Marl lakes typically are found in areas that were recently glaciated, and they often fill kettle depressions left behind by melting glaciers. [1] Their most distinctive characteristic is that they deposit sediments rich in calcium carbonate. More precisely, a marl lake is a lake in which calcium carbonate makes up at least 50% of the dry weight of the inorganic fraction of the surface sediments. [2] In some lakes, the sediments are almost pure calcium carbonate. [3]
The calcium carbonate precipitates from lake water that is alkaline, typically with a pH 8.0 or greater, [4] and has a high concentration of divalent ions and is low in dissolved organic compounds. [5] The concentration of calcium carbonate in the lake water usually exceeds 100 mg per liter. [6] Young marl lakes are sometimes visually stunning, with very fine suspended crystals of calcium carbonate giving the water an opaque light blue color. [7]
In Britain, marl lakes are of glacial origin and are shallow (less than 4 meters or 13 feet deep). They are associated with carbonate bedrock or bedrock of the Old Red Sandstone. Their concentration of calcium carbonate is 140 mg/L, typical of temperate limestone groundwater. [2]
The precipitation of calcium carbonate from marl lakes is a consequence of removal of carbon dioxide by photosynthesis (particularly by Chara , stonewort, which becomes encrusted with low-magnesium calcite during the summer [3] ) or outgassing of saturated groundwater, [8] or as a result of the common-ion effect. [2]
Higgins Lake, in central Michigan, US, is the only known location of freshwater oolites. These are found in a narrow band between a beach rich in clastic sediments and deeper water below wave base. [9]
Marl lakes of the upper Great Lakes region have a very low biological productivity. [5] They typically are very sparse in macrophytes (macroscopic plants and algae), and their productivity is dominated by one macrophyte species, Scirpus subterminalis (water bulrush), which is responsible for an average of 79% of the total biomass. Chara (stonewort) accounts for 12% of the biomass but limited to the most shallow, protected parts of the lake. Potamogeton (pondweed) provides most of the remaining biomass. [10]
Marl lakes often contain lakemounts. These are thought to begin with thin patches in the original kettle ice, which were colonized by Najas , Potamogeton, and Chara. These locally enhanced the sediment deposition rate to build up the lakemounts to near the lake surface. [5] The lakes are often surrounded by beachrock composed of cemented pisoliths (calcite concretions) and gastropod shells. [8] The shallow beachrock slopes are inhabited by Chara. [3]
British marl lakes are dominated by Chara, which is the source of the marl. By contrast with marl lakes of the Great Lakes region, they have a rich emergent and submerged macrophyte community. They are also home to many gastropods and crustaceans. [2]
Iron is a limiting nutrient in marl lakes, as it is practically insoluble in oxygenated, alkaline water. To be available at all, it must be chelated by organic matter. But because the primary productivity is low, organic matter is scarce; this means there is little chelation of iron, which keeps primary productivity low in a vicious cycle. [4] Phosphate, another essential nutrient, is precipitated along with carbonates, further reducing the supply of nutrients. [11]
Some mare lakes are meromictic lakes in which bottom water never mixes with surface water. Green Lake, at Fayetteville, New York, is a meromictic marl lake containing a cyanobacterial thrombolitic bioherm. [12]
Marl lakes are ecologically important, [13] but are vulnerable to damage by silting, nutrient pollution, drainage, and invasive species. To some extent, the high calcium content of marl lake water buffers it against phosphate, but the native ecological community is sensitive even to small changes in chemistry and the introduction of nutrient pollution renders the lake more hospitable to invasive species. [14] Eventually a threshold is reached at which the lake rapidly loses its marl characteristics and flowering plants replace Chara. [15] In Britain, only the marl lakes of the more remote parts of northern Scotland are likely to remain pristine into the near future. Many are transient or eutrophic, and at least half those in Britain have been affected by nutrient pollution. [2]
Marl ponds steadily deposit sediments that can be dated by carbon-14. They also contain proxies for local climate. For example, the sediments of Pretty Lake in Indiana, USA, contain chlorophyll degradation products from which its history of biological productivity can be estimated. This record shows a peak in productivity during the Boreal Age (9 to 7.6 thousand years ago) and another peak at about 6000 years ago. [5]
Wallywash Great Pond in Jamaica is an unusual tropical marl lake whose sediments also record climate fluctuations. Cores of the bottom sediments show deposition of marls during wet periods and sea highstands; organic-rich sediments during intervals of swampy conditions; and calcareous brown mud suggesting periods when the pond was an ephemeral lake. These cores record climate from the last interglacial, around 120,000 years ago, to nearly the present. [16]
The carbonate-rich sediments deposited by marl lakes is a mixture of clay and carbonate minerals described as marl. Marl lakes have frequently been dredged or mined for marl, often used for manufacturing Portland cement. [17]
Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.
Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae.
Eutrophication is the process by which an entire body of water, or parts of it, becomes progressively enriched with minerals and nutrients, particularly nitrogen and phosphorus. It has also been defined as "nutrient-induced increase in phytoplankton productivity". Water bodies with very low nutrient levels are termed oligotrophic and those with moderate nutrient levels are termed mesotrophic. Advanced eutrophication may also be referred to as dystrophic and hypertrophic conditions. Eutrophication can affect freshwater or salt water systems. In freshwater ecosystems it is almost always caused by excess phosphorus. In coastal waters on the other hand, the main contributing nutrient is more likely to be nitrogen, or nitrogen and phosphorus together. This depends on the location and other factors.
An estuary is a partially enclosed coastal body of brackish water with one or more rivers or streams flowing into it, and with a free connection to the open sea. Estuaries form a transition zone between river environments and maritime environments and are an example of an ecotone. Estuaries are subject both to marine influences such as tides, waves, and the influx of saline water, and to fluvial influences such as flows of freshwater and sediment. The mixing of seawater and freshwater provides high levels of nutrients both in the water column and in sediment, making estuaries among the most productive natural habitats in the world.
Chert is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a diagenetic replacement, as in petrified wood.
Water pollution is the contamination of water bodies, usually as a result of human activities, so that it negatively affects its uses. Water bodies include lakes, rivers, oceans, aquifers, reservoirs and groundwater. Water pollution results when contaminants are introduced into these water bodies. Water pollution can be attributed to one of four sources: sewage discharges, industrial activities, agricultural activities, and urban runoff including stormwater. It can be grouped into surface water pollution or groundwater pollution. For example, releasing inadequately treated wastewater into natural waters can lead to degradation of these aquatic ecosystems. Water pollution can also lead to water-borne diseases for people using polluted water for drinking, bathing, washing or irrigation. Water pollution reduces the ability of the body of water to provide the ecosystem services that it would otherwise provide.
Tufa is a variety of limestone formed when carbonate minerals precipitate out of ambient temperature water. Geothermally heated hot springs sometimes produce similar carbonate deposits, which are known as travertine. Tufa is sometimes referred to as (meteogene) travertine. It should not be confused with hot spring (thermogene) travertine. Tufa, which is calcareous, should also not be confused with tuff, a porous volcanic rock with a similar etymology that is sometimes also called "tufa".
The purple sulfur bacteria (PSB) are part of a group of Pseudomonadota capable of photosynthesis, collectively referred to as purple bacteria. They are anaerobic or microaerophilic, and are often found in stratified water environments including hot springs, stagnant water bodies, as well as microbial mats in intertidal zones. Unlike plants, algae, and cyanobacteria, purple sulfur bacteria do not use water as their reducing agent, and therefore do not produce oxygen. Instead, they can use sulfur in the form of sulfide, or thiosulfate (as well, some species can use H2, Fe2+, or NO2−) as the electron donor in their photosynthetic pathways. The sulfur is oxidized to produce granules of elemental sulfur. This, in turn, may be oxidized to form sulfuric acid.
Paleolimnology is a scientific sub-discipline closely related to both limnology and paleoecology. Paleolimnological studies focus on reconstructing the past environments of inland waters using the geologic record, especially with regard to events such as climatic change, eutrophication, acidification, and internal ontogenic processes.
The phosphorus cycle is the biogeochemical cycle that describes the movement of phosphorus through the lithosphere, hydrosphere, and biosphere. Unlike many other biogeochemical cycles, the atmosphere does not play a significant role in the movement of phosphorus, because phosphorus and phosphorus-based compounds are usually solids at the typical ranges of temperature and pressure found on Earth. The production of phosphine gas occurs in only specialized, local conditions. Therefore, the phosphorus cycle should be viewed from whole Earth system and then specifically focused on the cycle in terrestrial and aquatic systems.
Human impact on the nitrogen cycle is diverse. Agricultural and industrial nitrogen (N) inputs to the environment currently exceed inputs from natural N fixation. As a consequence of anthropogenic inputs, the global nitrogen cycle (Fig. 1) has been significantly altered over the past century. Global atmospheric nitrous oxide (N2O) mole fractions have increased from a pre-industrial value of ~270 nmol/mol to ~319 nmol/mol in 2005. Human activities account for over one-third of N2O emissions, most of which are due to the agricultural sector. This article is intended to give a brief review of the history of anthropogenic N inputs, and reported impacts of nitrogen inputs on selected terrestrial and aquatic ecosystems.
An aragonite sea contains aragonite and high-magnesium calcite as the primary inorganic calcium carbonate precipitates. The chemical conditions of the seawater must be notably high in magnesium content relative to calcium for an aragonite sea to form. This is in contrast to a calcite sea in which seawater low in magnesium content relative to calcium favors the formation of low-magnesium calcite as the primary inorganic marine calcium carbonate precipitate.
Chara is a genus of charophyte green algae in the family Characeae. They are multicellular and superficially resemble land plants because of stem-like and leaf-like structures. They are found in freshwater, particularly in limestone areas throughout the northern temperate zone, where they grow submerged, attached to the muddy bottom. They prefer less oxygenated and hard water and are not found in waters where mosquito larvae are present. They are covered with calcium carbonate deposits and are commonly known as stoneworts. Cyanobacteria have been found growing as epiphytes on the surfaces of Chara, where they may be involved in fixing nitrogen, which is important to plant nutrition.
Marine chemistry, also known as ocean chemistry or chemical oceanography, is influenced by plate tectonics and seafloor spreading, turbidity currents, sediments, pH levels, atmospheric constituents, metamorphic activity, and ecology. The field of chemical oceanography studies the chemistry of marine environments including the influences of different variables. Marine life has adapted to the chemistries unique to earth's oceans, and marine ecosystems are sensitive to changes in ocean chemistry.
A soda lake or alkaline lake is a lake on the strongly alkaline side of neutrality, typically with a pH value between 9 and 12. They are characterized by high concentrations of carbonate salts, typically sodium carbonate, giving rise to their alkalinity. In addition, many soda lakes also contain high concentrations of sodium chloride and other dissolved salts, making them saline or hypersaline lakes as well. High pH and salinity often coincide, because of how soda lakes develop. The resulting hypersaline and highly alkalic soda lakes are considered some of the most extreme aquatic environments on Earth.
A whiting event is a phenomenon that occurs when a suspended cloud of fine-grained calcium carbonate precipitates in water bodies, typically during summer months, as a result of photosynthetic microbiological activity or sediment disturbance. The phenomenon gets its name from the white, chalky color it imbues to the water. These events have been shown to occur in temperate waters as well as tropical ones, and they can span for hundreds of meters. They can also occur in both marine and freshwater environments. The origin of whiting events is debated among the scientific community, and it is unclear if there is a single, specific cause. Generally, they are thought to result from either bottom sediment re-suspension or by increased activity of certain microscopic life such as phytoplankton. Because whiting events affect aquatic chemistry, physical properties, and carbon cycling, studying the mechanisms behind them holds scientific relevance in various ways.
Marine biogeochemical cycles are biogeochemical cycles that occur within marine environments, that is, in the saltwater of seas or oceans or the brackish water of coastal estuaries. These biogeochemical cycles are the pathways chemical substances and elements move through within the marine environment. In addition, substances and elements can be imported into or exported from the marine environment. These imports and exports can occur as exchanges with the atmosphere above, the ocean floor below, or as runoff from the land.
Euxinia or euxinic conditions occur when water is both anoxic and sulfidic. This means that there is no oxygen (O2) and a raised level of free hydrogen sulfide (H2S). Euxinic bodies of water are frequently strongly stratified, have an oxic, highly productive, thin surface layer, and have anoxic, sulfidic bottom water. The word euxinia is derived from the Greek name for the Black Sea (Εὔξεινος Πόντος (Euxeinos Pontos)) which translates to "hospitable sea". Euxinic deep water is a key component of the Canfield ocean, a model of oceans during the Proterozoic period (known as the Boring Billion) proposed by Donald Canfield, an American geologist, in 1998. There is still debate within the scientific community on both the duration and frequency of euxinic conditions in the ancient oceans. Euxinia is relatively rare in modern bodies of water, but does still happen in places like the Black Sea and certain fjords.
Benthic-pelagic coupling are processes that connect the benthic zone and the pelagic zone through the exchange of energy, mass, or nutrients. These processes play a prominent role in both freshwater and marine ecosystems and are influenced by a number of chemical, biological, and physical forces that are crucial to functions from nutrient cycling to energy transfer in food webs.
Biogenous ooze is a type of marine sediment composed of a high percentage of organic compounds.