Mundic was used from the 1690s to describe a copper ore that began to be smelted at Bristol and elsewhere in southwestern Britain. Smelting was carried out in cupolas, that is reverberatory furnaces using mineral coal. [1] For more details, see copper extraction.
Mundic once [2] referred to pyrite, [3] but has now adopted the wider meaning of concrete deterioration caused by oxidisation of pyrites within the aggregate (usually originating from mine waste). The action of water and oxygen on pyrite forms sulphate (a salt of sulphuric acid), thereby depleting the pyrite, causing loss of adhesion and physical expansion.
The Cornish word mundic is now used to describe a cause of deterioration in concrete due to the decomposition of mineral constituents within the aggregate. A typical source of such aggregates is metalliferous mine waste. RICS Professional guidance describes all of Cornwall and an area within 15 km of Tavistock as being areas where routine testing for mundic is required. The notes go on to state that testing should be confined to buildings which contain concrete elements (blocks or in situ) and that were built in or prior to 1950. However, the notes contain advice that testing may be required where there are visual or other signs of mundic decay. Testing leads to a classification of A (subdivided into A1, A2 and A3), B or C. All A classifications are sound, B is sound but contains sufficient deleterious aggregate for it to be considered unstable and C is unsound. Classifications B & C mean that a property may be unmortgageable. [4]
Typically a house is routinely screened if constructed between 1900 and 1960 from concrete block. [5]
The mineral pyrite, or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula FeS2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Chalcopyrite ( KAL-kə-PY-ryte, -koh-) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black.
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous, ferroalloy or non-ferrous/base metals. Within these general categories, slags can be further categorized by their precursor and processing conditions.
Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that commonly intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional, or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from a variety of sources; magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.
Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.
Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines or coal mines.
Copper extraction refers to the methods used to obtain copper from its ores. The conversion of copper ores consists of a series of physical, chemical and electrochemical processes. Methods have evolved and vary with country depending on the ore source, local environmental regulations, and other factors.
Tennantite is a copper arsenic sulfosalt mineral with an ideal formula Cu12As4S13. Due to variable substitution of the copper by iron and zinc the formula is Cu6[Cu4(Fe,Zn)2]As4S13. It is gray-black, steel-gray, iron-gray or black in color. A closely related mineral, tetrahedrite (Cu12Sb4S13) has antimony substituting for arsenic and the two form a solid solution series. The two have very similar properties and is often difficult to distinguish between tennantite and tetrahedrite. Iron, zinc, and silver substitute up to about 15% for the copper site.
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S. It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content decreases, and troilite is non-magnetic. Pyrrhotite is generally tabular and brassy/bronze in color with a metallic luster. The mineral occurs with mafic igneous rocks like norites, and may form from pyrite during metamorphic processes. Pyrrhottie is associated and mined with other sulfide minerals like pentlandite, pyrite, chalcopyrite, and magnetite, and has been found globally.
Cobaltite is a sulfide mineral composed of cobalt, arsenic, and sulfur, CoAsS. Its impurities may contain up to 10% iron and variable amounts of nickel. Structurally, it resembles pyrite (FeS2) with one of the sulfur atoms replaced by an arsenic atom.
Boliden AB is a Swedish multinational metals, mining, and smelting company headquartered in Stockholm. The company produces zinc, copper, lead, nickel, silver, and gold, with operations in Sweden, Finland, Norway, and Ireland.
The Bingham Canyon Mine, more commonly known as Kennecott Copper Mine among locals, is an open-pit mining operation extracting a large porphyry copper deposit southwest of Salt Lake City, Utah, in the Oquirrh Mountains. The mine is the largest man-made excavation, and deepest open-pit mine in the world, which is considered to have produced more copper than any other mine in history – more than 19,000,000 short tons. The mine is owned by Rio Tinto Group, a British-Australian multinational corporation. The copper operations at Bingham Canyon Mine are managed through Kennecott Utah Copper Corporation which operates the mine, a concentrator plant, a smelter, and a refinery. The mine has been in production since 1906, and has resulted in the creation of a pit over 0.75 miles (1,210 m) deep, 2.5 miles (4 km) wide, and covering 1,900 acres. It was designated a National Historic Landmark in 1966 under the name Bingham Canyon Open Pit Copper Mine. The mine experienced a massive landslide in April 2013 and a smaller slide in September 2013.
Gwennap is a village and civil parish in Cornwall, England. It is about five miles (8 km) southeast of Redruth. Hamlets of Burncoose, Comford, Coombe, Crofthandy, Cusgarne, Fernsplatt, Frogpool, Hick's Mill, Tresamble and United Downs lie in the parish, as does Little Beside country house.
Mount Isa Mines Limited ("MIM") operates the Mount Isa copper, lead, zinc and silver mines near Mount Isa, Queensland, Australia as part of the Glencore group of companies. For a brief period in 1980, MIM was Australia's largest company. It has pioneered several significant mining industry innovations, including the Isa Process copper refining technology, the Isasmelt smelting technology, and the IsaMill fine grinding technology, and it also commercialized the Jameson Cell column flotation technology.
In the United States, copper mining has been a major industry since the rise of the northern Michigan copper district in the 1840s. In 2017, the US produced 1.27 million metric tonnes of copper, worth $8 billion, making it the world's fourth largest copper producer, after Chile, China, and Peru. Copper was produced from 23 mines in the US. Top copper producing states in 2014 were Arizona, Utah, New Mexico, Nevada, and Montana. Minor production also came from Idaho, and Missouri. As of 2014, the US had 45 million tonnes of known remaining reserves of copper, the fifth largest known copper reserves in the world, after Chile, Australia, Peru, and Mexico.
The Leadville mining district, located in the Colorado Mineral Belt, was the most productive silver-mining district in the state of Colorado and hosts one of the largest lead-zinc-silver deposits in the world. Oro City, an early Colorado gold placer mining town located about a mile east of Leadville in California Gulch, was the location to one of the richest placer gold strikes in Colorado, with estimated gold production of 120,000–150,000 ozt, worth $2.5 to $3 million at the then-price of $20.67 per troy ounce.
Copper slag is a by-product of copper extraction by smelting. During smelting, impurities become slag which floats on the molten metal. Slag that is quenched in water produces angular granules which are disposed of as waste or utilized as discussed below.
Plants for the production of lead are generally referred to as lead smelters. Primary lead production begins with sintering. Concentrated lead ore is fed into a sintering machine with iron, silica, limestone fluxes, coke, soda ash, pyrite, zinc, caustics or pollution control particulates. Smelting uses suitable reducing substances that will combine with those oxidizing elements to free the metal. Reduction is the final, high-temperature step in smelting. It is here that the oxide becomes the elemental metal. A reducing environment pulls the final oxygen atoms from the raw metal.
The ISASMELT process is an energy-efficient smelting process that was jointly developed from the 1970s to the 1990s by Mount Isa Mines and the Government of Australia’s CSIRO. It has relatively low capital and operating costs for a smelting process.
The Blue Ledge Mine is an inactive underground copper mine that has been classified as a Superfund Site by the Environmental Protection Agency (EPA) due to high concentrations of heavy metals. The mine is located approximately 3 miles south of the California–Oregon border in the Rogue River-Siskiyou National Forest. It is within the Siskiyou Mountain range, and sits near a summit at about 4,800 feet above sea level. The underground mining excavations span over 2 miles, and it is one of the largest mining operations to have existed in the region.