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A reverberatory furnace is a metallurgical or process furnace that isolates the material being processed from contact with the fuel, but not from contact with combustion gases. The term reverberation is used here in a generic sense of rebounding or reflecting , not in the acoustic sense of echoing.
Chemistry determines the optimum relationship between the fuel and the material, among other variables. The reverberatory furnace can be contrasted on the one hand with the blast furnace, in which fuel and material are mixed in a single chamber, and, on the other hand, with crucible, muffling, or retort furnaces, in which the subject material is isolated from the fuel and all of the products of combustion including gases and flying ash. There are, however, a great many furnace designs, and the terminology of metallurgy has not been very consistently defined, so it is difficult to categorically contradict other views.
The applications of these devices fall into two general categories, metallurgical melting furnaces, and lower temperature processing furnaces typically used for metallic ores and other minerals.
A reverberatory furnace is at a disadvantage from the standpoint of efficiency compared to a blast furnace due to the separation of the burning fuel and the subject material, and it is necessary to effectively utilize both reflected radiant heat and direct contact with the exhaust gases (convection) to maximize heat transfer. Historically these furnaces have used solid fuel, and bituminous coal has proven to be the best choice. The brightly visible flames, due to the substantial volatile component, give more radiant heat transfer than anthracite coal or charcoal.
Contact with the products of combustion, which may add undesirable elements to the subject material, is used to advantage in some processes. Control of the fuel/air balance can alter the exhaust gas chemistry toward either an oxidizing or a reducing mixture, and thus alter the chemistry of the material being processed. For example, cast iron can be puddled in an oxidizing atmosphere to convert it to the lower-carbon mild steel or bar iron. The Siemens-Martin oven in open hearth steelmaking is also a reverberatory furnace.
Reverberatory furnaces (in this context, usually called air furnaces) were formerly also used for melting brass, bronze, and pig iron for foundry work. They were also, for the first 75 years of the 20th century, the dominant smelting furnace used in copper production, treating either roasted calcine or raw copper sulfide concentrate. [1] While they have been supplanted in this role, first by flash furnaces and more recently also by the Ausmelt [1] and ISASMELT furnaces, [2] they are very effective at producing slags with low copper losses. [1]
The first reverberatory furnaces were perhaps in the medieval period, and were used for melting bronze for casting bells. The earliest known detailed description was provided by Biringuccio. [3] They were first applied to smelting metals in the late 17th century. Sir Clement Clerke and his son Talbot built cupolas or reverberatory furnaces in the Avon Gorge below Bristol in about 1678. In 1687, while obstructed from smelting lead (by litigation), they moved on to copper. In the following decades, reverberatory furnaces were widely adopted for smelting these metals and also tin. They had the advantage over older methods that the fuel was mineral coal, not charcoal or 'white coal' (chopped dried wood).
In the 1690s, they (or associates) applied the reverberatory furnace (in this case known as an air furnace) to melting pig iron for foundry purposes. This was used at Coalbrookdale and various other places, but became obsolete at the end of the 18th century with the introduction of the foundry cupola furnace, which was a kind of small blast furnace, and a quite different species from the reverberatory furnace.[ citation needed ]
The puddling furnace, introduced by Henry Cort in the 1780s to replace the older finery process, was also a variety of reverberatory furnace.[ citation needed ]
Reverberatory furnaces are widely used to melt secondary aluminium scrap for eventual use by die-casting industries. [4]
The simplest reverberatory furnace is nothing more than a steel box lined with alumina refractory brick with a flue at one end and a vertically lifting door at the other. Conventional oil or gas burners are placed usually on either side of the furnace to heat the brick and the eventual bath of molten metal is then poured into a casting machine to produce ingots. [4]
Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron, copper, silver, tin, lead and zinc. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal behind. The reducing agent is commonly a fossil-fuel source of carbon, such as carbon monoxide from incomplete combustion of coke—or, in earlier times, of charcoal. The oxygen in the ore binds to carbon at high temperatures, as the chemical potential energy of the bonds in carbon dioxide is lower than that of the bonds in the ore.
Coke is a grey, hard, and porous coal-based fuel with a high carbon content. It is made by heating coal or oil in the absence of air. Coke is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and forges.
Wrought iron is an iron alloy with a very low carbon content in contrast to that of cast iron. It is a semi-fused mass of iron with fibrous slag inclusions, which give it a wood-like "grain" that is visible when it is etched, rusted, or bent to failure. Wrought iron is tough, malleable, ductile, corrosion resistant, and easily forge welded, but is more difficult to weld electrically.
A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. Blast refers to the combustion air being supplied above atmospheric pressure.
Industrial processes are procedures involving chemical, physical, electrical, or mechanical steps to aid in the manufacturing of an item or items, usually carried out on a very large scale. Industrial processes are the key components of heavy industry.
Copper extraction refers to the methods used to obtain copper from its ores. The conversion of copper ores consists of a series of physical, chemical and electrochemical processes. Methods have evolved and vary with country depending on the ore source, local environmental regulations, and other factors.
An open-hearth furnace or open hearth furnace is any of several kinds of industrial furnace in which excess carbon and other impurities are burnt out of pig iron to produce steel. Because steel is difficult to manufacture owing to its high melting point, normal fuels and furnaces were insufficient for mass production of steel, and the open-hearth type of furnace was one of several technologies developed in the nineteenth century to overcome this difficulty. Compared with the Bessemer process, which it displaced, its main advantages were that it did not expose the steel to excessive nitrogen, was easier to control, and permitted the melting and refining of large amounts of scrap iron and steel.
Calcination is thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition.
Pyrometallurgy is a branch of extractive metallurgy. It consists of the thermal treatment of minerals and metallurgical ores and concentrates to bring about physical and chemical transformations in the materials to enable recovery of valuable metals. Pyrometallurgical treatment may produce products able to be sold such as pure metals, or intermediate compounds or alloys, suitable as feed for further processing. Examples of elements extracted by pyrometallurgical processes include the oxides of less reactive elements like iron, copper, zinc, chromium, tin, and manganese.
Puddling is the process of converting pig iron to bar (wrought) iron in a coal fired reverberatory furnace. It was developed in England during the 1780s. The molten pig iron was stirred in a reverberatory furnace, in an oxidizing environment to burn the carbon, resulting in wrought iron. It was one of the most important processes for making the first appreciable volumes of valuable and useful bar iron without the use of charcoal. Eventually, the furnace would be used to make small quantities of specialty steels.
A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals processed are aluminum and cast iron. However, other metals, such as bronze, brass, steel, magnesium, and zinc, are also used to produce castings in foundries. In this process, parts of desired shapes and sizes can be formed.
Sir Clement Clerke, 1st Baronet was an important English entrepreneur, whose greatest achievement was the application of the reverberatory furnace (cupola) to smelting lead and copper, and to remelting pig iron for foundry purposes.
In metallurgy, refining consists of purifying an impure metal. It is to be distinguished from other processes such as smelting and calcining in that those two involve a chemical change to the raw material, whereas in refining the final material is chemically identical to the raw material. Refining thus increases the purity of the raw material via processing. There are many processes including pyrometallurgical and hydrometallurgical techniques.
Mount Isa Mines Limited ("MIM") operates the Mount Isa copper, lead, zinc and silver mines near Mount Isa, Queensland, Australia as part of the Glencore group of companies. For a brief period in 1980, MIM was Australia's largest company. It has pioneered several significant mining industry innovations, including the Isa Process copper refining technology, the Isasmelt smelting technology, and the IsaMill fine grinding technology, and it also commercialized the Jameson Cell column flotation technology.
A cupola or cupola furnace is a melting device used in foundries that can be used to melt cast iron, Ni-resist iron and some bronzes. The cupola can be made almost any practical size. The size of a cupola is expressed in diameters and can range from 1.5 to 13 feet. The overall shape is cylindrical and the equipment is arranged vertically, usually supported by four legs. The overall look is similar to a large smokestack.
Archaeometallurgical slag is slag discovered and studied in the context of archaeology. Slag, the byproduct of iron-working processes such as smelting or smithing, is left at the iron-working site rather than being moved away with the product. As it weathers well, it is readily available for study. The size, shape, chemical composition and microstructure of slag are determined by features of the iron-working processes used at the time of its formation.
Plants for the production of lead are generally referred to as lead smelters. Primary lead production begins with sintering. Concentrated lead ore is fed into a sintering machine with iron, silica, limestone fluxes, coke, soda ash, pyrite, zinc, caustics or pollution control particulates. Smelting uses suitable reducing substances that will combine with those oxidizing elements to free the metal. Reduction is the final, high-temperature step in smelting. It is here that the oxide becomes the elemental metal. A reducing environment pulls the final oxygen atoms from the raw metal.
The ISASMELT process is an energy-efficient smelting process that was jointly developed from the 1970s to the 1990s by Mount Isa Mines and the Government of Australia's CSIRO. It has relatively low capital and operating costs for a smelting process.
The Bottom-blown Oxygen Converter or BBOC is a smelting furnace developed by the staff at Britannia Refined Metals Limited (“BRM”), a British subsidiary of MIM Holdings Limited. The furnace is currently marketed by Glencore Technology. It is a sealed, flat-bottomed furnace mounted on a tilting frame that is used in the recovery of precious metals. A key feature is the use of a shrouded lance to inject oxygen through the bottom of the furnace, directly into the precious metals contained in the furnace, to oxidize base metals or other impurities as part of their removal as slag.
A metallurgical furnace, often simply referred to as a furnace when the context is known, is an industrial furnace used to heat, melt, or otherwise process metals. Furnaces have been a central piece of equipment throughout the history of metallurgy; processing metals with heat is even its own engineering specialty known as pyrometallurgy.
