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A nitrogen oxide sensor or NOx sensor is typically a high-temperature device built to detect nitrogen oxides in combustion environments such as an automobile, truck tailpipe or smokestack.
The term NOx represents several forms of nitrogen oxides such as NO (nitric oxide), NO2 (nitrogen dioxide) and N2O (nitrous oxide, also known as laughing gas). In a gasoline engine, NO is the most common form of NOx at around 93%, while NO2 is around 5% and the rest is N2O. There are other forms of NOx such as N2O4 (the dimer of NO2), which only exists at lower temperatures, and N2O5, for example. [1]
Meanwhile, for diesel engines, the emissions situation is different. Owing to their much higher combustion temperatures (resulting from their high cylinder compression ratios as well as turbocharging or supercharging), diesel engines produce much higher engine-out NOx emissions than spark-ignition gasoline engines. The recent availability of Selective catalytic reduction (SCR) allows properly equipped diesel engines to emit similar values of NOx at the tailpipe compared to a typical gasoline engine with a 3-way catalyst. The SCR changes the harmful nitrogen oxides by adding the solution AdBlue which reduces environmental pollution and protects the exhaust system. In addition, the diesel oxidation catalyst significantly increases the fraction of NO2 in "NOx" by oxidizing over 50% of NO using the excess oxygen in the diesel exhaust gases.
The drive to develop a NOx sensor arises from environmental factors. NOx gases can cause various problems such as smog and acid rain. Many governments around the world have passed laws to limit their emissions (along with other combustion gases such as SOx (oxides of sulfur), CO (carbon monoxide) and CO2 (carbon dioxide) and hydrocarbons). Companies have realized that one way of minimizing NOx emissions is to first detect them and then to employ some sort of feedback loop in the combustion process, thereby enabling the minimization of NOx production by, for example, combustion optimization or regeneration of NOx traps. Therefore, in many applications with exhaust-gas treatment systems, one NOx sensor is used upstream of the exhaust-gas treatment system (upstream) and a second sensor is used downstream of the exhaust-gas treatment system. The upstream sensor is used for the aforementioned feedback loop. Meanwhile, the downstream sensor is used mainly to confirm that the legislated emissions limits have not been exceeded.
Due to the high temperature of the combustion environment, only certain types of material can operate in situ . The majority of NOx sensors developed have been made out of ceramic type metal oxides, with the most common being yttria-stabilized zirconia (YSZ), which is currently used in the decades-old oxygen sensor. The YSZ is compacted into a dense ceramic and conducts oxygen ions (O2−) at the high temperatures of a tailpipe such at 400 °C and above. To get a signal from the sensor a pair of high-temperature electrodes such as noble metals (platinum, gold, or palladium) or other metal oxides are placed onto the surface and an electrical signal such as the change in voltage or current is measured as a function of NOx concentration.
The levels of NO are around 100–2000 ppm (parts per million) and NO2 20–200 ppm in a range of 1–10% O2. The sensor has to be very sensitive to pick up these levels.
The main challenges in the sensor development are selectivity, sensitivity, stability, reproducibility, response time, limit of detection, and cost. In addition due to the harsh environment of combustion the high gas flow rate can cool the sensor which alters the signal or it can delaminate the electrodes over time and soot particles can degrade the materials.
One of the major challenges faced by such gas sensors is humidity. The relative effect on signal response is highly subjective to the sensor type. Electrochemical sensors are mostly immune from humidity effect as water molecules help regulate the electrolyte concentration but long term exposure to dry gas can reduce the solvent concentration of the electrolyte. High amount of cross sensitivity has been observed in gas sensors due to similarity in electron exchange mechanism between target gases and water molecules. [2]
In internal combustion engines, exhaust gas recirculation (EGR) is a nitrogen oxide (NOx) emissions reduction technique used in petrol/gasoline, diesel engines and some hydrogen engines. EGR works by recirculating a portion of an engine's exhaust gas back to the engine cylinders. The exhaust gas displaces atmospheric air and reduces O2 in the combustion chamber. Reducing the amount of oxygen reduces the amount of fuel that can burn in the cylinder thereby reducing peak in-cylinder temperatures. The actual amount of recirculated exhaust gas varies with the engine operating parameters.
Nitrogen dioxide is a chemical compound with the formula NO2. It is one of several nitrogen oxides. NO
2 is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the production of fertilizers. At higher temperatures it is a reddish-brown gas. It can be fatal if inhaled in large quantities. Nitrogen dioxide is a paramagnetic, bent molecule with C2v point group symmetry.
Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds:
A catalytic converter is an exhaust emission control device that converts toxic gases and pollutants in exhaust gas from an internal combustion engine into less-toxic pollutants by catalyzing a redox reaction. Catalytic converters are usually used with internal combustion engines fueled by gasoline or diesel, including lean-burn engines, and sometimes on kerosene heaters and stoves.
Vehicle emissions control is the study of reducing the emissions produced by motor vehicles, especially internal combustion engines.
Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends, or coal. According to the type of engine, it is discharged into the atmosphere through an exhaust pipe, flue gas stack, or propelling nozzle. It often disperses downwind in a pattern called an exhaust plume.
An oxygen sensor (or lambda sensor, where lambda refers to air–fuel equivalence ratio, usually denoted by λ) or probe or sond, is an electronic device that measures the proportion of oxygen (O2) in the gas or liquid being analysed.
Diesel exhaust is the gaseous exhaust produced by a diesel type of internal combustion engine, plus any contained particulates. Its composition may vary with the fuel type or rate of consumption, or speed of engine operation, and whether the engine is in an on-road vehicle, farm vehicle, locomotive, marine vessel, or stationary generator or other application.
Lean-burn refers to the burning of fuel with an excess of air in an internal combustion engine. In lean-burn engines the air–fuel ratio may be as lean as 65:1. The air / fuel ratio needed to stoichiometrically combust gasoline, by contrast, is 14.64:1. The excess of air in a lean-burn engine emits far less hydrocarbons. High air–fuel ratios can also be used to reduce losses caused by other engine power management systems such as throttling losses.
Homogeneous Charge Compression Ignition (HCCI) is a form of internal combustion in which well-mixed fuel and oxidizer are compressed to the point of auto-ignition. As in other forms of combustion, this exothermic reaction produces heat that can be transformed into work in a heat engine.
Selective catalytic reduction (SCR) means of converting nitrogen oxides, also referred to as NO
x with the aid of a catalyst into diatomic nitrogen, and water. A reductant, typically anhydrous ammonia, aqueous ammonia, or a urea solution, is added to a stream of flue or exhaust gas and is reacted onto a catalyst. As the reaction drives toward completion, nitrogen, and carbon dioxide, in the case of urea use, are produced.
Diesel exhaust fluid is a liquid used to reduce the amount of air pollution created by a diesel engine. Specifically, DEF is an aqueous urea solution made with 32.5% urea and 67.5% deionized water. DEF is consumed in a selective catalytic reduction (SCR) that lowers the concentration of nitrogen oxides in the diesel exhaust emissions from a diesel engine.
In atmospheric chemistry, NOx is shorthand for nitric oxide and nitrogen dioxide, the nitrogen oxides that are most relevant for air pollution. These gases contribute to the formation of smog and acid rain, as well as affecting tropospheric ozone.
A NOx adsorber or NOx trap (also called Lean NOx trap, abbr. LNT) is a device that is used to reduce oxides of nitrogen (NO and NO2) emissions from a lean burn internal combustion engine by means of adsorption.
A LO NOx burner is a type of burner that is typically used in utility boilers to produce steam and electricity.
A nondispersive infrared sensor is a simple spectroscopic sensor often used as a gas detector. It is non-dispersive in the fact that no dispersive element is used to separate out the broadband light into a narrow spectrum suitable for gas sensing. The majority of NDIR sensors use a broadband lamp source and an optical filter to select a narrow band spectral region that overlaps with the absorption region of the gas of interest. In this context narrow may be 50-300nm bandwidth. Modern NDIR sensors may use Microelectromechanical systems (MEMs) or mid IR LED sources, with or without an optical filter.
An engine test stand is a facility used to develop, characterize and test engines. The facility, often offered as a product to automotive OEMs, allows engine operation in different operating regimes and offers measurement of several physical variables associated with the engine operation.
Engine efficiency of thermal engines is the relationship between the total energy contained in the fuel, and the amount of energy used to perform useful work. There are two classifications of thermal engines-
A hydrogen internal combustion engine vehicle (HICEV) is a type of hydrogen vehicle using an internal combustion engine. Hydrogen internal combustion engine vehicles are different from hydrogen fuel cell vehicles. Instead, the hydrogen internal combustion engine is simply a modified version of the traditional gasoline-powered internal combustion engine. The absence of carbon means that no CO2 is produced, which eliminates the main greenhouse gas emission of a conventional petroleum engine.
An exhaust gas analyser or exhaust carbon monoxide (CO) analyser is an instrument for the measurement of carbon monoxide among other gases in the exhaust, caused by an incorrect combustion, the Lambda coefficient measurement is the most common.
