Northstarite

Northstarite
General
Category	Thiosulfate
Formula (repeating unit)	Pb 6(Te 4+ O 3)5(S 6+ O 3 S 2-)
IMA symbol	Nsr [1]
Strunz classification	7.JA.20
Crystal system	Hexagonal
Crystal class	Pyramidal
Space group	P63
Unit cell	a = 10.2573  Å, c = 11.678 Å V = 1064.0 Å3 Z = 2
Identification
Color	Beige
Crystal habit	Short prisms with pyramidal terminations
Twinning	None
Cleavage	None
Fracture	Irregular
Tenacity	Brittle
Mohs scale hardness	2
Luster	Adamantine
Streak	White
Diaphaneity	Transparent
Specific gravity	6.888
Density	6.888 g/cm3
Optical properties	Uniaxial
Refractive index	nα= 1.686 nβ= 1.694 nγ= 1.709
Birefringence	δ
Pleochroism	Non-pleochroic
References	[2] [3]

Northstarite is an immensely rare lead-tellurite-thiosulfate mineral with an ideal formula of Pb ₆(Te ⁴⁺ O ₃)₅(S ⁶⁺ O ₃ S ^2-). Northstarite was first discovered in 2019 by Charles Adan in the North Star Mine of the Tintic Mining District, Juab County, Utah, USA. Northstarite received its name after this type locality where it was originally discovered, the North Star Mine. Northstarite is the fourth thiosulfate mineral that exists on Earth, and although all thiosulfates have essential lead components, northstarite is the first thiosulfate species containing groups of both thiosulfate and tellurite (Te⁴⁺O₃). ^{[2] [3]}

Occurrence

Northstarite is a mineral found in the oxidation zone of Earth, meaning that it is found near the Earth's surface and formed as a result of the chemical decomposition of other minerals that are unstable at the surface. Northstarite occurs in small rock cavities with quartz, baryte, enargite, and pyrite, but is also associated with anglesite, azurite, chrysocolla, fluorapatite, plumbogummite, tellurite, zincospiroffite, as well as a type of copper-tellurite that possesses poor crystallization. Northstarite is associated with another new mineral called adanite, which was also discovered in the North Star Mine and shares a similar chemical composition as northstarite. The holotype specimen of northstarite originated from the holotype specimen of adanite. ^{[2] [3]}

Physical properties

The crystals of northstarite are about 1 mm in length and are short and prismatic, with pyramidal terminations. The irregular or uneven faces of the crystals avert accurate measurements, but rough measurements have been recorded as {100}, {101}, and {101} based on the general appearance of the crystals and the Donnay-Harker Law. ^[2] The crystals display no twinning or cleavage, and have an uneven fracture. Northstarite is very brittle. Based on scratch tests, the hardness of northstarite is approximately 2 on the Mohs scale of hardness. Northstarite displays an adamantine luster and has transparent to translucent crystals with a beige color and a white streak. ^[2]

Optical properties

Northstarite is a nonpleochroic and uniaxial negative mineral. The calculated average index of refraction for northstarite is 2.15 based on the empirical formula of Pb_5.80Sb³⁺_0.05Te⁴⁺_5.04S⁶⁺_1.02O₁₈. ^[2]

Chemical properties

Northstarite is a thiosulfate mineral that contains tellurite. The empirical formula of northstarite is Pb_5.80Sb³⁺_0.05Te⁴⁺_5.04S⁶⁺_1.02O₁₈. When simplified, this formula becomes an ideal formula of Pb ₆(Te ⁴⁺ O ₃)₅(S ⁶⁺ O ₃ S ^2-). Chemically, northstarite resembles adanite, schieffelinite, and also eztlite to an extent. ^[3] Northstarite is indicated to be an anhydrous mineral. ^[2] When introduced to concentrated hydrochloric acid at room temperature, the crystals of northstarite are slowly soluble. ^[2]

Chemical composition

Constituent	wt%	Range
PbO	57.16	56.43-58.53
Sb2O3	0.32	0.21-0.43
TeO2	35.46	35.03-35.89
SO3*	7.22	7.06-7.38
SO3*	3.61	-
S*	1.44	-
O=S	-0.72	-
Total	97.27	-

_{* The measured SO3 in parentheses is allocated as SO3 and S based on S⁶⁺:S^2– = 1:1} ^[2]

X-ray crystallography

Northstarite is in the hexagonal crystal system with a space group of P6₃. The unit cell dimensions are a= 10.253 Å and c= 11.6747 Å with a standard unit cell volume of 1061.50 ų. ^[2]

Powder diffraction data:

d-spacing	Intensity
5.12 Å	(21)
3.098 Å	(100)
2.957 Å	(74)
2.140 Å	(44)
1.940 Å	(13)
1.733 Å	(41)
1.706 Å	(18)
1.626 Å	(31)

^[3]

See also

• List of minerals

References

1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
2. Kampf, Anthony R.; Housley, Robert M.; Rossman, George R. (2020-07-01). "Northstarite, a new lead-tellurite-thiosulfate mineral from the North Star mine, Tintic, Utah, USA". The Canadian Mineralogist. 58 (4): 533–542. Bibcode:2020CaMin..58..533K. doi:10.3749/canmin.1900105. ISSN   1499-1276. S2CID   225626916.
3. "Northstarite". www.mindat.org. Retrieved 2021-12-12.