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Ozone, or trioxygen, is an inorganic molecule with the chemical formula O
3. It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope O
2, breaking down in the lower atmosphere to O
2 (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the latter, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation.
The ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately 15 to 35 kilometers (9 to 22 mi) above Earth, although its thickness varies seasonally and geographically.
Ozone depletion consists of two related events observed since the late 1970s: a steady lowering of about four percent in the total amount of ozone in Earth's atmosphere, and a much larger springtime decrease in stratospheric ozone around Earth's polar regions. The latter phenomenon is referred to as the ozone hole. There are also springtime polar tropospheric ozone depletion events in addition to these stratospheric events.
The stratosphere is the second major layer of Earth's atmosphere, just above the troposphere, and below the mesosphere. The stratosphere is stratified (layered) in temperature, with warmer layers higher and cooler layers closer to the Earth; this increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet radiation by the ozone layer. This is in contrast to the troposphere, near the Earth's surface, where temperature decreases with altitude. The border between the troposphere and stratosphere, the tropopause, marks where this temperature inversion begins. Near the equator, the lower edge of the stratosphere is as high as 20 km, at midlatitudes around 10 km, and at the poles about 7 km Temperatures range from an average of −51 °C near the tropopause to an average of −15 °C near the mesosphere. Stratospheric temperatures also vary within the stratosphere as the seasons change, reaching particularly low temperatures in the polar night (winter). Winds in the stratosphere can far exceed those in the troposphere, reaching near 60 m/s in the Southern polar vortex.
The atmosphere of Earth is the layer of gases, commonly known as air, retained by Earth's gravity, surrounding the planet Earth and forming its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing for liquid water to exist on the Earth's surface, absorbing ultraviolet solar radiation, warming the surface through heat retention, and reducing temperature extremes between day and night.
Ozone (O3) is a trace gas of the troposphere, with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. Ozone is also an important constituent of the stratosphere, where the ozone layer exists which is located between 10 and 50 kilometers above the earths surface. The troposphere is the lowest layer of the Earth's atmosphere. It extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. Ground level or tropospheric ozone is created by chemical reactions between oxides of nitrogen (NOx gases) and volatile organic compounds (VOCs). The combination of these chemicals in the presence of sunlight form ozone. Its concentration increases as height above sea level increases, with a maximum concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming.
Dinitrogen pentoxide is the chemical compound with the formula N2O5, also known as nitrogen pentoxide or nitric anhydride. It is one of the binary nitrogen oxides, a family of compounds that only contain nitrogen and oxygen. It exists as colourless crystals that melt at 41 °C. Its boiling point is 47 °C, and sublimes slightly above room temperature, yielding a colorless gas.
The ozone–oxygen cycle is the process by which ozone is continually regenerated in Earth's stratosphere, converting ultraviolet radiation (UV) into heat. In 1930 Sydney Chapman resolved the chemistry involved. The process is commonly called the Chapman cycle by atmospheric scientists.
The hydroxyl radical, •OH, is the neutral form of the hydroxide ion (OH−). Hydroxyl radicals are highly reactive (easily becoming hydroxy groups) and consequently short-lived. They form an important part of radical chemistry. Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water. It is also an important radical formed in radiation chemistry, since it leads to the formation of hydrogen peroxide and oxygen, which can enhance corrosion and SCC in coolant systems subjected to radioactive environments. Hydroxyl radicals are also produced during UV-light dissociation of H2O2 (suggested in 1879) and likely in Fenton chemistry, where trace amounts of reduced transition metals catalyze peroxide-mediated oxidations of organic compounds.
Paul Jozef Crutzen was a Dutch meteorologist and atmospheric chemist. He was awarded the Nobel Prize in Chemistry in 1995 for his work on atmospheric chemistry and specifically for his efforts in studying the formation and decomposition of atmospheric ozone. In addition to studying the ozone layer and climate change, he popularized the term Anthropocene to describe a proposed new era when human actions have a drastic effect on the Earth. He was also amongst the first few scientists to introduce the idea of a nuclear winter to describe the potential climatic effects stemming from large-scale atmospheric pollution including smoke from forest fires, industrial exhausts, and other sources like oil fires.
In atmospheric chemistry, NO
x is a generic term for the nitrogen oxides that are most relevant for air pollution, namely nitric oxide (NO) and nitrogen dioxide. These gases contribute to the formation of smog and acid rain, as well as affecting tropospheric ozone.
Photodissociation, photolysis, or photodecomposition is a chemical reaction in which a chemical compound is broken down by photons. It is defined as the interaction of one or more photons with one target molecule. Photodissociation is not limited to visible light. Any photon with sufficient energy can affect the chemical bonds of a chemical compound. Since a photon's energy is inversely proportional to its wavelength, electromagnetic waves with the energy of visible light or higher, such as ultraviolet light, x-rays and gamma rays are usually involved in such reactions.
The homosphere is the layer of an atmosphere where the bulk gases are homogeneously mixed due to turbulent mixing or eddy diffusion. The bulk composition of the air is mostly uniform so the concentrations of molecules are the same throughout the homosphere. The top of the homosphere is called the homopause, also known as the turbopause. Above the homopause is the heterosphere, where diffusion is faster than mixing, and heavy gases decrease in density with altitude more rapidly than lighter gases.
A photoinitiator is a molecule that creates reactive species when exposed to radiation. Synthetic photoinitiators are key components in photopolymers.
Nitrogen trioxide or nitrate radical is an oxide of nitrogen with formula NO
3, consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems.
Paul O. Wennberg is the R. Stanton Avery Professor of Atmospheric Chemistry and Environmental Science and Engineering at the California Institute of Technology (Caltech). He is the director of the Ronald and Maxine Linde Center for Global Environmental Science. He is chair of the Total Carbon Column Observing Network and a founding member of the Orbiting Carbon Observatory project, which created NASA's first spacecraft for analysis of carbon dioxide in the atmosphere. He is also the principal investigator for the Mars Atmospheric Trace Molecule Occultation Spectrometer (MATMOS) to investigate trace gases in Mars's atmosphere.
In atmospheric chemistry, the Leighton relationship is an equation that determines the concentration of tropospheric ozone in areas polluted by the presence of nitrogen oxides. Ozone in the troposphere is primarily produced through the photolysis of nitrogen dioxide by photons with wavelengths (λ) less than 420 nanometers, which are able to reach the lowest levels of the atmosphere, through the following mechanism:
Barbara J. Finlayson-Pitts is Canadian-American atmospheric chemist. She is a professor in the chemistry department at the University of California, Irvine and is the Director of AirUCI Institute. Finlayson-Pitts and James N. Pitts, Jr. are the authors of Chemistry of the Upper and Lower Atmosphere: Theory, Experiments, and Applications (1999). She has been a member of the National Academy of Sciences since 2006 and is the laureate for the 2017 Garvan–Olin Medal. In 2016 she co-chaired the National Academy of Science report "The Future of Atmospheric Chemistry Research"
Urine patches in cattle pastures generate large concentrations of the greenhouse gas nitrous oxide through nitrification and denitrification processes in urine-contaminated soils. Over the past few decades, the cattle population has increased more rapidly than the human population. Between the years 2000 and 2050, the cattle population is expected to increase from 1.5 billion to 2.6 billion. When large populations of cattle are packed into pastures, excessive amounts of urine soak into soils. This increases the rate at which nitrification and denitrification occur and produce nitrous oxide. Currently, nitrous oxide is one of the single most important ozone-depleting emissions and is expected to remain the largest throughout the 21st century.
Akkihebbal Ramaiah (Ravi) Ravishankara ForMemRS FAAAS FRSC is a scientist specializing in Chemistry and Atmospheric Sciences, and University Distinguished Professor in the Departments of Chemistry and Atmospheric Sciences at Colorado State University, Fort Collins.
References
- ↑ M., Holloway, Ann (2010). Atmospheric chemistry. Wayne, Richard P. Cambridge: RSC Pub. ISBN 9781847558077. OCLC 471801630.
- 1 2 Pitts, Barbara J. (2000). Chemistry of the upper and lower atmosphere : theory, experiments, and applications. Pitts, James N. San Diego: Academic Press. p. 661. ISBN 9780080529073. OCLC 162128929.
- ↑ "The Stratosphere - overview". scied.ucar.edu. University Corporation for Atmospheric Research. Retrieved 1 November 2018.