The ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately 15 to 35 kilometers (9 to 22 mi) above Earth, although its thickness varies seasonally and geographically.
Ozone depletion consists of two related events observed since the late 1970s: a steady lowering of about four percent in the total amount of ozone in Earth's atmosphere, and a much larger springtime decrease in stratospheric ozone around Earth's polar regions. The latter phenomenon is referred to as the ozone hole. There are also springtime polar tropospheric ozone depletion events in addition to these stratospheric events.
The stratosphere is the second layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. The stratosphere is an atmospheric layer composed of stratified temperature layers, with the warm layers of air high in the sky and the cool layers of air in the low sky, close to the planetary surface of the Earth. The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer. The temperature inversion is in contrast to the troposphere, and near the Earth's surface, where temperature decreases with altitude.
Atmospheric science is the study of the Earth's atmosphere and its various inner-working physical processes. Meteorology includes atmospheric chemistry and atmospheric physics with a major focus on weather forecasting. Climatology is the study of atmospheric changes that define average climates and their change over time, due to both natural and anthropogenic climate variability. Aeronomy is the study of the upper layers of the atmosphere, where dissociation and ionization are important. Atmospheric science has been extended to the field of planetary science and the study of the atmospheres of the planets and natural satellites of the Solar System.
The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth creates pressure, absorbs most meteoroids and ultraviolet solar radiation, warms the surface through heat retention, and reduces temperature extremes between day and night, maintaining conditions allowing life and liquid water to exist on the Earth's surface.
Ground-level ozone (O3), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. Ozone is also an important constituent of the stratosphere, where the ozone layer (2 to 8 parts per million ozone) exists which is located between 10 and 50 kilometers above the Earth's surface. The troposphere extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. Ground-level or tropospheric ozone is created by chemical reactions between NOx gases (oxides of nitrogen produced by combustion) and volatile organic compounds (VOCs). The combination of these chemicals in the presence of sunlight form ozone. Its concentration increases as height above sea level increases, with a maximum concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming.
Paul Jozef Crutzen was a Dutch meteorologist and atmospheric chemist. He and Mario Molina and Frank Sherwood Rowland were awarded the Nobel Prize in Chemistry in 1995 for their work on atmospheric chemistry and specifically for his efforts in studying the formation and decomposition of atmospheric ozone. In addition to studying the ozone layer and climate change, he popularized the term Anthropocene to describe a proposed new epoch in the Quaternary period when human actions have a drastic effect on the Earth. He was also amongst the first few scientists to introduce the idea of a nuclear winter to describe the potential climatic effects stemming from large-scale atmospheric pollution including smoke from forest fires, industrial exhausts, and other sources like oil fires.
Difluoromethane, also called difluoromethylene, HFC-32Methylene Fluoride or R-32, is an organic compound of the dihalogenoalkane variety. It has the formula of CH2F2. It is a colorless gas in the ambient atmosphere and is slightly soluble in the water, with a high thermal stability. Due to the low melting and boiling point, (-136.0 °C and -51.6 °C respectively) contact with this compound may result in frostbite. In the United States, the Clean Air Act Section 111 on Volatile Organic Compounds (VOC) has listed difluoromethane as an exception (since 1997) from the definition of VOC due to its low production of tropospheric ozone. Difluoromethane is commonly used in endothermic processes such as refrigeration or air conditioning.
Non-methane volatile organic compounds (NMVOCs) are a set of organic compounds that are typically photochemically reactive in the atmosphere—marked by the exclusion of methane. NMVOCs include a large variety of chemically different compounds, such as benzene, ethanol, formaldehyde, cyclohexane, 1,1,1-trichloroethane and acetone. Essentially, NMVOCs are identical to volatile organic compounds (VOCs), but with methane excluded. Methane is excluded in air-pollution contexts because it is not toxic. It is however a very potent greenhouse gas, with low reactivity and thus a long lifetime in the atmosphere. An important subset of NMVOCs are the non-methane hydrocarbons (NMHCs).
Tetrafluoromethane, also known as carbon tetrafluoride or R-14, is the simplest perfluorocarbon (CF4). As its IUPAC name indicates, tetrafluoromethane is the perfluorinated counterpart to the hydrocarbon methane. It can also be classified as a haloalkane or halomethane. Tetrafluoromethane is a useful refrigerant but also a potent greenhouse gas. It has a very high bond strength due to the nature of the carbon–fluorine bond.
In atmospheric chemistry, NOx is shorthand for nitric oxide and nitrogen dioxide, the nitrogen oxides that are most relevant for air pollution. These gases contribute to the formation of smog and acid rain, as well as affecting tropospheric ozone.
The Max Planck Institute for Chemistry is a non-university research institute under the auspices of the Max Planck Society in Mainz, Germany. It was created as the Kaiser Wilhelm Institute for Chemistry in 1911 in Berlin.
Chlorotrifluoromethane, R-13, CFC-13, or Freon 13, is a non-flammable, non-corrosive, nontoxic chlorofluorocarbon (CFC) and also a mixed halomethane. It is a man-made substance used primarily as a refrigerant. When released into the environment, CFC-13 has a high ozone depletion potential, and long atmospheric lifetime. Only a few other greenhouse gases surpass CFC-13 in global warming potential (GWP). The IPCC AR5 reported that CFC-13's atmospheric lifetime was 640 years.
Over the last two centuries many environmental chemical observations have been made from a variety of ground-based, airborne, and orbital platforms and deposited in databases. Many of these databases are publicly available. All of the instruments mentioned in this article give online public access to their data. These observations are critical in developing our understanding of the Earth's atmosphere and issues such as climate change, ozone depletion and air quality. Some of the external links provide repositories of many of these datasets in one place. For example, the Cambridge Atmospheric Chemical Database, is a large database in a uniform ASCII format. Each observation is augmented with the meteorological conditions such as the temperature, potential temperature, geopotential height, and equivalent PV latitude.
Tropospheric ozone depletion events are phenomena that reduce the concentration of ozone in the earth's troposphere. Ozone (O3) is a trace gas which has been of concern because of its unique dual role in different layers of the lower atmosphere. Apart from absorbing UV-B radiation and converting solar energy into heat in the stratosphere, ozone in the troposphere provides greenhouse effect and controls the oxidation capacity of the atmosphere.
Greenhouse gases are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. What distinguishes them from other gases is that they absorb the wavelengths of radiation that a planet emits, resulting in the greenhouse effect. The Earth is warmed by sunlight, causing its surface to radiate heat, which is then mostly absorbed by water vapor (H2O), carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), and ozone (O3). Without greenhouse gases, the average temperature of Earth's surface would be about −18 °C (0 °F), rather than the present average of 15 °C (59 °F).
SAGE III on ISS is the fourth generation of a series of NASA Earth-observing instruments, known as the Stratospheric Aerosol and Gas Experiment. The first SAGE III instrument was launched on a Russian Meteor-3M satellite. The recently revised SAGE III was mounted to the International Space Station where it uses the unique vantage point of ISS to make long-term measurements of ozone, aerosols, water vapor, and other gases in Earth's atmosphere.
In an oil and gas production, flash-gas is a spontaneous vapor that is produced from the heating or depressurization of the extracted oil mixture during different phases of production. Flash evaporation, or flashing, is the process of volatile components suddenly vaporizing from their liquid state. This often happens during the transportation of petroleum products through pipelines and into vessels, such as when the stream from a common separation unit flows into an on-site atmospheric storage tank. Vessels that are used to intentionally “flash” a mixture of gas and saturated liquids are aptly named "flash drums." A type of vapor-liquid separator. A venting apparatus is used in these vessels to prevent damage due to increasing pressure, extreme cases of this are referred to as boiling liquid expanding vapor explosion (BLEVE).
Johannes "Jos" Lelieveld is a Dutch atmospheric chemist. Since 2000, he has been a Scientific Member of the Max Planck Society and director of the Atmospheric Chemistry Department at the Max Planck Institute for Chemistry in Mainz. He is also professor at the University of Mainz and at the Cyprus Institute in Nicosia.
John W. Birks is an American atmospheric chemist and entrepreneur who is best known for co-discovery with Paul Crutzen of the potential atmospheric effects of nuclear war known as nuclear winter. His most recent awards include the 2019 Haagen-Smit Clean Air Award for his contributions to atmospheric chemistry and the 2022 Future of Life Award for discovery of the nuclear winter effect.
