Interface and colloid science

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Milk is an emulsified colloid of liquid butterfat globules dispersed within a water-based solution. Milk.jpg
Milk is an emulsified colloid of liquid butterfat globules dispersed within a water-based solution.

Interface and colloid science is an interdisciplinary intersection of branches of chemistry, physics, nanoscience and other fields dealing with colloids, heterogeneous systems consisting of a mechanical mixture of particles between 1 nm and 1000 nm dispersed in a continuous medium. A colloidal solution is a heterogeneous mixture in which the particle size of the substance is intermediate between a true solution and a suspension, i.e. between 1–1000 nm. Smoke from a fire is an example of a colloidal system in which tiny particles of solid float in air. Just like true solutions, colloidal particles are small and cannot be seen by the naked eye. They easily pass through filter paper. But colloidal particles are big enough to be blocked by parchment paper or animal membrane.

Contents

Interface and colloid science has applications and ramifications in the chemical industry, pharmaceuticals, biotechnology, ceramics, minerals, nanotechnology, and microfluidics, among others.

There are many books dedicated to this scientific discipline, [1] [2] [3] [4] and there is a glossary of terms, Nomenclature in Dispersion Science and Technology, published by the US National Institute of Standards and Technology. [5]

See also

Related Research Articles

Colloid Mixture of an insoluble substance microscopically dispersed throughout another substance

A colloid is a mixture in which one substance of microscopically dispersed insoluble particles are suspended throughout another substance. However, some definitions specify that the particles must be dispersed in a liquid, and others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture. A colloid has a dispersed phase and a continuous phase. The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre.

An emulsion is a mixture of two or more liquids that are normally immiscible owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion should be used when both phases, dispersed and continuous, are liquids. In an emulsion, one liquid is dispersed in the other. Examples of emulsions include vinaigrettes, homogenized milk, liquid biomolecular condensates, and some cutting fluids for metal working.

In chemistry, a mixture is a material made up of two or more different substances which are not chemically combined. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the form of solutions, suspensions and colloids.

Suspension (chemistry) Heterogeneous mixture of solid particles dispersed in a medium

In chemistry, a suspension is a heterogeneous mixture of a fluid that contains solid particles sufficiently large for sedimentation. The particles may be visible to the naked eye, usually must be larger than one micrometer, and will eventually settle, although the mixture is only classified as a suspension when and while the particles have not settled out.

Colloidal gold

Colloidal gold is a sol or colloidal suspension of nanoparticles of gold in a fluid, usually water. The colloid is usually either an intense red colour or blue/purple . Due to their optical, electronic, and molecular-recognition properties, gold nanoparticles are the subject of substantial research, with many potential or promised applications in a wide variety of areas, including electron microscopy, electronics, nanotechnology, materials science, and biomedicine.

A sol is a colloid made out of very small solid particles in a continuous liquid medium. Sols are quite stable and show the Tyndall effect. Examples include blood, pigmented ink, cell fluids, paint, antacids and mud.

Zeta potential Electrokinetic potential in colloidal dispersions

Zeta potential is the electrical potential at the slipping plane. This plane is the interface which separates mobile fluid from fluid that remains attached to the surface.

The DLVO theory explains the aggregation of aqueous dispersions quantitatively and describes the force between charged surfaces interacting through a liquid medium. It combines the effects of the van der Waals attraction and the electrostatic repulsion due to the so-called double layer of counterions. The electrostatic part of the DLVO interaction is computed in the mean field approximation in the limit of low surface potentials - that is when the potential energy of an elementary charge on the surface is much smaller than the thermal energy scale, . For two spheres of radius each having a charge separated by a center-to-center distance in a fluid of dielectric constant containing a concentration of monovalent ions, the electrostatic potential takes the form of a screened-Coulomb or Yukawa potential,

Nanoparticle Particle with size less than 100 nm

A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At the lowest range, metal particles smaller than 1 nm are usually called atom clusters instead.

Flocculation Process by which colloidal particles come out of suspension to precipitate as floc or flake

Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from precipitation in that, prior to flocculation, colloids are merely suspended, under the form of a stable dispersion, in a liquid and are not truly dissolved in solution.

Point of zero charge The pH value at which the surface of a colloidal solid carries no net electrical charge

The point of zero charge (pzc) is generally described as the pH at which the net charge of total particle surface is equal to zero, which concept has been introduced in the studies dealt with colloidal flocculation to explain pH affecting the phenomenon.

A dispersion is a system in which distributed particles of one material are dispersed in a continuous phase of another material. The two phases may be in the same or different states of matter.

Electroacoustic phenomena arise when ultrasound propagates through a fluid containing ions. The associated particle motion generates electric signals because ions have electric charge. This coupling between ultrasound and electric field is called electroacoustic phenomena. The fluid might be a simple Newtonian liquid, or complex heterogeneous dispersion, emulsion or even a porous body. There are several different electroacoustic effects depending on the nature of the fluid.

Double layer (surface science) Condensed matter physics

A double layer is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object. The first layer, the surface charge, consists of ions adsorbed onto the object due to chemical interactions. The second layer is composed of ions attracted to the surface charge via the Coulomb force, electrically screening the first layer. This second layer is loosely associated with the object. It is made of free ions that move in the fluid under the influence of electric attraction and thermal motion rather than being firmly anchored. It is thus called the "diffuse layer".

Electrokinetic phenomena are a family of several different effects that occur in heterogeneous fluids, or in porous bodies filled with fluid, or in a fast flow over a flat surface. The term heterogeneous here means a fluid containing particles. Particles can be solid, liquid or gas bubbles with sizes on the scale of a micrometer or nanometer. There is a common source of all these effects—the so-called interfacial 'double layer' of charges. Influence of an external force on the diffuse layer generates tangential motion of a fluid with respect to an adjacent charged surface. This force might be electric, pressure gradient, concentration gradient, or gravity. In addition, the moving phase might be either continuous fluid or dispersed phase.

Sedimentation potential occurs when dispersed particles move under the influence of either gravity or centrifugation in a medium. This motion disrupts the equilibrium symmetry of the particle's double layer. While the particle moves, the ions in the electric double layer lag behind due to the liquid flow. This causes a slight displacement between the surface charge and the electric charge of the diffuse layer. As a result, the moving particle creates a dipole moment. The sum of all of the dipoles generates an electric field which is called sedimentation potential. It can be measured with an open electrical circuit, which is also called sedimentation current.

Particle size

Particle size is a notion introduced for comparing dimensions of solid particles (flecks), liquid particles (droplets), or gaseous particles (bubbles). The notion of particle size applies to colloidal particles, particles in ecology, particles present in granular material, and particles that form a granular material.

Colloidal crystal

A colloidal crystal is an ordered array of colloid particles and fine grained materials analogous to a standard crystal whose repeating subunits are atoms or molecules. A natural example of this phenomenon can be found in the gem opal, where spheres of silica assume a close-packed locally periodic structure under moderate compression. Bulk properties of a colloidal crystal depend on composition, particle size, packing arrangement, and degree of regularity. Applications include photonics, materials processing, and the study of self-assembly and phase transitions.

The Stöber process is a chemical process used to prepare silica particles of controllable and uniform size for applications in materials science. It was pioneering when it was reported by Werner Stöber and his team in 1968, and remains today the most widely used wet chemistry synthetic approach to silica nanoparticles. It is an example of a sol-gel process wherein a molecular precursor is first reacted with water in an alcoholic solution, the resulting molecules then joining together to build larger structures. The reaction produces silica particles with diameters ranging from 50 to 2000 nm, depending on conditions. The process has been actively researched since its discovery, including efforts to understand its kinetics and mechanism – a particle aggregation model was found to be a better fit for the experimental data than the initially hypothesized LaMer model. The newly acquired understanding has enabled researchers to exert a high degree of control over particle size and distribution and to fine-tune the physical properties of the resulting material in order to suit intended applications.

In polymer science, dispersion polymerization is a heterogeneous polymerization process carried out in the presence of a polymeric stabilizer in the reaction medium. Dispersion polymerization is a type of precipitation polymerization, meaning the solvent selected as the reaction medium is a good solvent for the monomer and the initiator, but is a non-solvent for the polymer. As the polymerization reaction proceeds, particles of polymer form, creating a non-homogeneous solution. In dispersion polymerization these particles are the locus of polymerization, with monomer being added to the particle throughout the reaction. In this sense, the mechanism for polymer formation and growth has features similar to that of emulsion polymerization. With typical precipitation polymerization, the continuous phase is the main locus of polymerization, which is the main difference between precipitation and dispersion.

References

  1. Lyklema, J. “Fundamentals of Interface and Colloid Science”, vol.2, page.3.208, 1995 ISBN   0-12-460529-X
  2. Russel, W.B., Saville, D.A. and Schowalter, W.R. “Colloidal Dispersions”, Cambridge University Press, 1992 ISBN   0-521-42600-6
  3. Dukhin, A. S. and Goetz, P. J. Characterization of liquids, nano- and micro- particulates and porous bodies using Ultrasound, Elsevier, 2017 ISBN   978-0-444-63908-0
  4. Israelachvili, Jacob (2010). Intermolecular and Surface Forces, Second Edition: With Applications to Colloidal and Biological Systems. London: Academic Press. p. 480. ISBN   978-0-12-375181-2.
  5. Hackley, V.A. and Ferraris, C.F. "The Use of Nomenclature in Dispersion Science and Technology", NIST, special publication 960-3 (2001);