Homogeneity and heterogeneity

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Homogeneity and heterogeneity;
only 'b' is homogeneous Homogene heterogene.png
Homogeneity and heterogeneity;
only 'b' is homogeneous

Homogeneity and heterogeneity are concepts relating to the uniformity of a substance, process or image. A homogeneous feature is uniform in composition or character (i.e. color, shape, size, weight, height, distribution, texture, language, income, disease, temperature, radioactivity, architectural design, etc.); one that is heterogeneous is distinctly nonuniform in at least one of these qualities. [1] [2]

Contents

Etymology and spelling

The words homogeneous and heterogeneous come from Medieval Latin homogeneus and heterogeneus, from Ancient Greek ὁμογενής (homogenēs) and ἑτερογενής (heterogenēs), from ὁμός (homos, "same") and ἕτερος (heteros, "other, another, different") respectively, followed by γένος (genos, "kind"); -ous is an adjectival suffix. [3]

Alternate spellings omitting the last -e- (and the associated pronunciations) are common, but mistaken: [4] homogenous is strictly a biological/pathological term which has largely been replaced by homologous . But use of homogenous to mean homogeneous has seen a rise since 2000 sufficient enough for it to now be considered an "established variant". [5] Similarly, heterogenous is a spelling traditionally reserved to biology and pathology, referring to the property of an object in the body having its origin outside the body. [6]

Scaling

The concepts are the same to every level of complexity. From atoms to galaxies, plants, animals, humans, and other living organisms all share both a common or unique set of complexities. Hence, an element may be homogeneous on a larger scale, compared to being heterogeneous on a smaller scale. This is known as an effective medium approximation. [7] [8]

Examples

Various disciplines understand heterogeneity, or being heterogeneous, in different ways. [2]

Biology

Environmental heterogeneity

Environmental heterogeneity (EH) is a hypernym for different environmental factors that contribute to the diversity of species, like climate, topography, and land cover. [9] Biodiversity is correlated with geodiversity on a global scale. Heterogeneity in geodiversity features and environmental variables are indicators of environmental heterogeneity. They drive biodiversity at local and regional scales.

Scientific literature in ecology contains a big number of different terms for environmental heterogeneity, often undefined or conflicting in their meaning. [10] Habitat diversity and Habitat heterogeneity are a synonyms of environmental heterogeneity. [10]

Chemistry

In chemistry, a heterogeneous mixture consists of either or both of 1) multiple states of matter or 2) hydrophilic and hydrophobic substances in one mixture; an example of the latter would be a mixture of water, octane, and silicone grease. Heterogeneous solids, liquids, and gases may be made homogeneous by melting, stirring, or by allowing time to pass for diffusion to distribute the molecules evenly. For example, adding dye to water will create a heterogeneous solution at first, but will become homogeneous over time. Entropy allows for heterogeneous substances to become homogeneous over time.[ citation needed ]

A heterogeneous mixture is a mixture of two or more compounds. Examples are: mixtures of sand and water or sand and iron filings, a conglomerate rock, water and oil, a salad, trail mix, and concrete (not cement). [11] A mixture can be determined to be homogeneous when everything is settled and equal, and the liquid, gas, the object is one color or the same form. Various models have been proposed to model the concentrations in different phases. The phenomena to be considered are mass rates and reaction.[ citation needed ]

Homogeneous and heterogeneous reactions

Homogeneous reactions are chemical reactions in which the reactants and products are in the same phase, while heterogeneous reactions have reactants in two or more phases. Reactions that take place on the surface of a catalyst of a different phase are also heterogeneous. A reaction between two gases or two miscible liquids is homogeneous. A reaction between a gas and a liquid, a gas and a solid or a liquid and a solid is heterogeneous. [ citation needed ]

Geology

Earth is a heterogeneous substance in many aspects; for instance, rocks (geology) are inherently heterogeneous, usually occurring at the micro-scale and mini-scale. [7]

Information technology

With information technology, heterogeneous computing occurs in a network comprising different types of computers, potentially with vastly differing memory sizes, processing power and even basic underlying architecture. [ citation needed ]

Mathematics and statistics

In algebra, homogeneous polynomials have the same number of factors of a given kind.

In the study of binary relations, a homogeneous relation R is on a single set (RX × X) while a heterogeneous relation concerns possibly distinct sets (RX × Y,  X = Y or XY). [12]

In statistical meta-analysis, study heterogeneity is when multiple studies on an effect are measuring somewhat different effects due to differences in subject population, intervention, choice of analysis, experimental design, etc.; this can cause problems in attempts to summarize the meaning of the studies.

Medicine

In medicine and genetics, a genetic or allelic heterogeneous condition is one where the same disease or condition can be caused, or contributed to, by several factors, or in genetic terms, by varying or different genes or alleles.

In cancer research, cancer cell heterogeneity is thought to be one of the underlying reasons that make treatment of cancer difficult. [13]

Physics

In physics, "heterogeneous" is understood to mean "having physical properties that vary within the medium".

Sociology

In sociology, "heterogeneous" may refer to a society or group that includes individuals of differing ethnicities, cultural backgrounds, sexes, or ages. Diverse is the more common synonym in the context. [14]

See also

Related Research Articles

<span class="mw-page-title-main">Catalysis</span> Process of increasing the rate of a chemical reaction

Catalysis is the increase in rate of a chemical reaction due to an added substance known as a catalyst. Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst.

<span class="mw-page-title-main">Chemical reaction</span> Process that results in the interconversion of chemical species

A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei, and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.

<span class="mw-page-title-main">Physical chemistry</span> Physics applied to chemical systems

Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria.

<span class="mw-page-title-main">Solution (chemistry)</span> Homogeneous mixture of a solute and a solvent

In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used when one of the solvents is water.

<span class="mw-page-title-main">Phase diagram</span> Chart used to show conditions at which physical phases of a substance occur

A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions at which thermodynamically distinct phases occur and coexist at equilibrium.

Homogeneity is a sameness of constituent structure.

In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. When both temperature and pressure are held constant, and the number of particles is expressed in moles, the chemical potential is the partial molar Gibbs free energy. At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free energy is at a minimum. In a system in diffusion equilibrium, the chemical potential of any chemical species is uniformly the same everywhere throughout the system.

In chemistry, a mixture is a material made up of two or more different chemical substances which are not chemically bonded. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the form of solutions, suspensions and colloids.

In thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure, volume and temperature, in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then

Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction.

<span class="mw-page-title-main">Chemical reactor</span> Enclosed volume where interconversion of compounds takes place

A chemical reactor is an enclosed volume in which a chemical reaction takes place. In chemical engineering, it is generally understood to be a process vessel used to carry out a chemical reaction, which is one of the classic unit operations in chemical process analysis. The design of a chemical reactor deals with multiple aspects of chemical engineering. Chemical engineers design reactors to maximize net present value for the given reaction. Designers ensure that the reaction proceeds with the highest efficiency towards the desired output product, producing the highest yield of product while requiring the least amount of money to purchase and operate. Normal operating expenses include energy input, energy removal, raw material costs, labor, etc. Energy changes can come in the form of heating or cooling, pumping to increase pressure, frictional pressure loss or agitation.

<span class="mw-page-title-main">Absorption (chemistry)</span> Chemical process

In chemistry, absorption is a physical or chemical phenomenon or a process in which atoms, molecules or ions enter some bulk phase – liquid or solid material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface.

<span class="mw-page-title-main">Heterogeneous catalysis</span> Type of catalysis involving reactants & catalysts in different phases of matter

Heterogeneous catalysis is catalysis where the phase of catalysts differs from that of the reactants or products. The process contrasts with homogeneous catalysis where the reactants, products and catalyst exist in the same phase. Phase distinguishes between not only solid, liquid, and gas components, but also immiscible mixtures, or anywhere an interface is present.

<span class="mw-page-title-main">Chemical substance</span> Matter of constant chemical composition and properties

A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combined without reacting, they may form a chemical mixture. If a mixture is separated to isolate one chemical substance to a desired degree, the resulting substance is said to be chemically pure.

This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions; it features an extensive vocabulary and a significant amount of jargon.

Heterogeneity is a diverseness of constituent structure.

<span class="mw-page-title-main">Bubble column reactor</span>

A bubble column reactor is a chemical reactor that belongs to the general class of multiphase reactors, which consists of three main categories: trickle bed reactor, fluidized bed reactor, and bubble column reactor. A bubble column reactor is a very simple device consisting of a vertical vessel filled with water with a gas distributor at the inlet. Due to the ease of design and operation, which does not involve moving parts, they are widely used in the chemical, biochemical, petrochemical, and pharmaceutical industries to generate and control gas-liquid chemical reactions.

Heterogeneous combustion, otherwise known as combustion in porous media, is a type of combustion in which a solid and gas phase interact to promote the complete transfer of reactants to their lower energy potential products. In this type of combustion a high surface area solid is immersed into a gaseous reacting flow, additional fluid phases may or may not be present. Chemical reactions and heat transfer occur locally on each phase and between both phases. Heterogeneous Combustion differs from catalysis as there is no focus to either phase individually but rather both examined simultaneously. In some materials, such as silicon carbide (SiC), oxide layers, SiO and SiO2, which form on the surface enable the adsorption of water vapor from the gas phase onto the solid lowering partial pressures. In this regime of combustion, thermal heat released from the combustion byproducts are transferred into the solid phase by convection; conduction and radiation both then conduct heat upstream (along with adverse convection within the gas phase). Heat is then convectively transferred to the unburnt reactants.

Industrial separation processes are technical procedures which are used in industry to separate a product from impurities or other products. The original mixture may either be a natural resource or the product of a chemical reaction.

Heterogeneous catalytic reactors put emphasis on catalyst effectiveness factors and the heat and mass transfer implications. Heterogeneous catalytic reactors are among the most commonly utilized chemical reactors in the chemical engineering industry.

References

  1. "Webster's Revised Unabridged Dictionary (1913 + 1828)". Heterogeneity. The ARTFL Project, University of Chicago. September 2010. Archived from the original (Part of this paragraph is public domain material copyright 1828 and 1913) on 2011-07-28. Retrieved 2010-09-10.
  2. 1 2 "Webster's Revised Unabridged Dictionary (1913 + 1828)". Heterogeneous. The ARTFL Project, University of Chicago. September 2010. Archived from the original (Part of this paragraph is public domain material copyright 1828 and 1913) on 2011-07-28. Retrieved 2010-09-10.
  3. Heterogeneous: Definition in the Oxford English Dictionary
  4. Cambridge Dictionary: homogeneous
  5. Homogeneous: Definition in the Oxford England Dictionary
  6. Heterogeneous vs. heterogenous - Grammarist)
  7. 1 2 Guéguen, Yves; Palciauskas, Victor (May 1994). Introduction to the physics of rocks. Princeton University Press. pp. 53–72 (Chapter 3). ISBN   978-0-691-03452-2.Google Books preview download available
  8. Shadrivov, Ilya V.; Kozyrev, AB; Van Der Weide, DW; Kivshar, YS (2008-11-24). "Nonlinear magnetic metamaterials" (Introduction section. Free PDF download). Optics Express. 16 (25): 20266–71. Bibcode:2008OExpr..1620266S. doi: 10.1364/OE.16.020266 . hdl:10440/410. PMID   19065165 . Retrieved 2009-11-26.[ dead link ]
  9. Wan, Ji-Zhong; Wang, Chun-Jing; Marquet, Pablo A (December 2023). "Environmental heterogeneity as a driver of terrestrial biodiversity on a global scale". Progress in Physical Geography: Earth and Environment. 47 (6): 912–930. doi:10.1177/03091333231189045. ISSN   0309-1333.
  10. 1 2 Stein, Anke; Kreft, Holger (August 2015). "Terminology and quantification of environmental heterogeneity in species‐richness research". Biological Reviews. 90 (3): 815–836. doi:10.1111/brv.12135. ISSN   1464-7931.
  11. Gamow, George (April 1967). "Chapter VI, "Descending Staircase"". One Two Three... Infinity (Mass market paperback) (Bantam Science and Mathematics, 5th printing ed.). Bantam. p. 117. [Clam chowder] represents a nice example of what is known as a heterogeneous material.
  12. Schmidt, Gunther; Ströhlein, Thomas (2012). Relations and Graphs: Discrete Mathematics for Computer Scientists. Springer Science & Business Media. ISBN   978-3-642-77968-8.
  13. Bhatia, Sangeeta; John V Frangioni; Robert M Hoffman; A John Iafrate; Kornelia Polyak (10 July 2012). "The challenges posed by cancer heterogeneity". Nature Biotechnology. 30 (7): 604–610. doi:10.1038/nbt.2294. PMID   22781679. S2CID   15083285.
  14. Dictionary of Sociology . Routledge; 12 November 2012. ISBN   978-1-136-59845-6.