Homogeneity and heterogeneity are concepts relating to the uniformity of a substance, process or image. A homogeneous feature is uniform in composition or character (i.e. color, shape, size, weight, height, distribution, texture, language, income, disease, temperature, radioactivity, architectural design, etc.); one that is heterogeneous is distinctly nonuniform in at least one of these qualities. [1] [2]
The words homogeneous and heterogeneous come from Medieval Latin homogeneus and heterogeneus, from Ancient Greek ὁμογενής (homogenēs) and ἑτερογενής (heterogenēs), from ὁμός (homos, "same") and ἕτερος (heteros, "other, another, different") respectively, followed by γένος (genos, "kind"); -ous is an adjectival suffix. [3]
Alternate spellings omitting the last -e- (and the associated pronunciations) are common, but mistaken: [4] homogenous is strictly a biological/pathological term which has largely been replaced by homologous . But use of homogenous to mean homogeneous has seen a rise since 2000, enough for it to now be considered an "established variant". [5] Similarly, heterogenous is a spelling traditionally reserved to biology and pathology, referring to the property of an object in the body having its origin outside the body. [6]
The concepts are the same to every level of complexity. From atoms to galaxies, plants, animals, humans, and other living organisms all share both a common or unique set of complexities. Hence, an element may be homogeneous on a larger scale, compared to being heterogeneous on a smaller scale. This is known as an effective medium approximation. [7] [8]
Various disciplines understand heterogeneity, or being heterogeneous, in different ways. [2]
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Environmental heterogeneity (EH) is a hypernym for different environmental factors that contribute to the diversity of species, like climate, topography, and land cover. [9] Biodiversity is correlated with geodiversity on a global scale. Heterogeneity in geodiversity features and environmental variables are indicators of environmental heterogeneity. They drive biodiversity at local and regional scales.
Scientific literature in ecology contains a big number of different terms for environmental heterogeneity, often undefined or conflicting in their meaning. [10] Habitat diversity and habitat heterogeneity are a synonyms of environmental heterogeneity. [10]
In chemistry, a heterogeneous mixture consists of either or both of 1) multiple states of matter or 2) hydrophilic and hydrophobic substances in one mixture; an example of the latter would be a mixture of water, octane, and silicone grease. Heterogeneous solids, liquids, and gases may be made homogeneous by melting, stirring, or by allowing time to pass for diffusion to distribute the molecules evenly. For example, adding dye to water will create a heterogeneous solution at first, but will become homogeneous over time. Entropy allows for heterogeneous substances to become homogeneous over time. [11]
A heterogeneous mixture is a mixture of two or more compounds. Examples are: mixtures of sand and water or sand and iron filings, a conglomerate rock, water and oil, a salad, trail mix, and concrete (not cement). [12] A mixture can be determined to be homogeneous when everything is settled and equal, and the liquid, gas, the object is one color or the same form. Various models have been proposed to model the concentrations in different phases. The phenomena to be considered are mass rates and reaction.[ citation needed ]
Homogeneous reactions are chemical reactions in which the reactants and products are in the same phase, while heterogeneous reactions have reactants in two or more phases. Reactions that take place on the surface of a catalyst of a different phase are also heterogeneous. A reaction between two gases or two miscible liquids is homogeneous. A reaction between a gas and a liquid, a gas and a solid or a liquid and a solid is heterogeneous.[ citation needed ]
Earth is a heterogeneous substance in many aspects; for instance, rocks (geology) are inherently heterogeneous, usually occurring at the micro-scale and mini-scale. [7]
In formal semantics, homogeneity is the phenomenon in which plural expressions imply "all" when asserted but "none" when negated. For example, the English sentence "Robin read the books" means that Robin read all the books, while "Robin didn't read the books" means that she read none of them. Neither sentence can be asserted if Robin read exactly half of the books. This is a puzzle because the negative sentence does not appear to be the classical negation of the sentence. A variety of explanations have been proposed including that natural language operates on a trivalent logic. [13]
With information technology, heterogeneous computing occurs in a network comprising different types of computers, potentially with vastly differing memory sizes, processing power and even basic underlying architecture.[ citation needed ]
In algebra, homogeneous polynomials have the same number of factors of a given kind.
In the study of binary relations, a homogeneous relation R is on a single set (R ⊆ X × X) while a heterogeneous relation concerns possibly distinct sets (R ⊆ X × Y, X = Y or X ≠ Y). [14]
In statistical meta-analysis, study heterogeneity is when multiple studies on an effect are measuring somewhat different effects due to differences in subject population, intervention, choice of analysis, experimental design, etc.; this can cause problems in attempts to summarize the meaning of the studies.
In medicine and genetics, a genetic or allelic heterogeneous condition is one where the same disease or condition can be caused, or contributed to, by several factors, or in genetic terms, by varying or different genes or alleles.
In cancer research, cancer cell heterogeneity is thought to be one of the underlying reasons that make treatment of cancer difficult. [15]
In physics, "heterogeneous" is understood to mean "having physical properties that vary within the medium".
In sociology, "heterogeneous" may refer to a society or group that includes individuals of differing ethnicities, cultural backgrounds, sexes, or ages. Diverse is the more common synonym in the context. [16]
Catalysis is the increase in rate of a chemical reaction due to an added substance known as a catalyst. Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst.
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an energy change as new products are generated. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei, and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.
In chemistry, a solution is defined by IUPAC as "A liquid or solid phase containing more than one substance, when for convenience one substance, which is called the solvent, is treated differently from the other substances, which are called solutes. When, as is often but not necessarily the case, the sum of the mole fractions of solutes is small compared with unity, the solution is called a dilute solution. A superscript attached to the ∞ symbol for a property of a solution denotes the property in the limit of infinite dilution." One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used when one of the solvents is water.
In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal gas mixture is the sum of the partial pressures of the gases in the mixture.
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions at which thermodynamically distinct phases occur and coexist at equilibrium.
Homogeneity is a sameness of constituent structure.
In chemistry, a mixture is a material made up of two or more different chemical substances which can be separated by physical method. It's an impure substance made up of 2 or more elements or compounds mechanically mixed together in any proportion. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the form of solutions, suspensions or colloids.
In thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure, volume and temperature, in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then
In chemistry, the dispersity is a measure of the heterogeneity of sizes of molecules or particles in a mixture. A collection of objects is called uniform if the objects have the same size, shape, or mass. A sample of objects that have an inconsistent size, shape and mass distribution is called non-uniform. The objects can be in any form of chemical dispersion, such as particles in a colloid, droplets in a cloud, crystals in a rock, or polymer macromolecules in a solution or a solid polymer mass. Polymers can be described by molecular mass distribution; a population of particles can be described by size, surface area, and/or mass distribution; and thin films can be described by film thickness distribution.
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate. Chemical kinetics includes investigations of how experimental conditions influence the speed of a chemical reaction and yield information about the reaction's mechanism and transition states, as well as the construction of mathematical models that also can describe the characteristics of a chemical reaction.
In industrial process engineering, mixing is a unit operation that involves manipulation of a heterogeneous physical system with the intent to make it more homogeneous. Familiar examples include pumping of the water in a swimming pool to homogenize the water temperature, and the stirring of pancake batter to eliminate lumps (deagglomeration).
Absorption is a physical or chemical phenomenon or a process in which atoms, molecules or ions enter the liquid or solid bulk phase of a material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface.
Heterogeneous catalysis is catalysis where the phase of catalysts differs from that of the reagents or products. The process contrasts with homogeneous catalysis where the reagents, products and catalyst exist in the same phase. Phase distinguishes between not only solid, liquid, and gas components, but also immiscible mixtures, or anywhere an interface is present.
In chemistry, a phase-transfer catalyst or PTC is a catalyst that facilitates the transition of a reactant from one phase into another phase where reaction occurs. Phase-transfer catalysis is a special form of catalysis and can act through homogeneous catalysis or heterogeneous catalysis methods depending on the catalyst used. Ionic reactants are often soluble in an aqueous phase but insoluble in an organic phase in the absence of the phase-transfer catalyst. The catalyst functions like a detergent for solubilizing the salts into the organic phase. Phase-transfer catalysis refers to the acceleration of the reaction upon the addition of the phase-transfer catalyst.
A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combined without reacting, they may form a chemical mixture. If a mixture is separated to isolate one chemical substance to a desired degree, the resulting substance is said to be chemically pure.
This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions; it features an extensive vocabulary and a significant amount of jargon.
Heterogeneity is a diverseness of constituent structure.
A bubble column reactor is a chemical reactor that belongs to the general class of multiphase reactors, which consists of three main categories: trickle bed reactor, fluidized bed reactor, and bubble column reactor. A bubble column reactor is a very simple device consisting of a vertical vessel filled with water with a gas distributor at the inlet. Due to the ease of design and operation, which does not involve moving parts, they are widely used in the chemical, biochemical, petrochemical, and pharmaceutical industries to generate and control gas-liquid chemical reactions.
Heterogeneous combustion, otherwise known as combustion in porous media, is a type of combustion in which a solid and gas phase interact to promote the complete transfer of reactants to their lower energy potential products. In this type of combustion a high surface area solid is immersed into a gaseous reacting flow, additional fluid phases may or may not be present. Chemical reactions and heat transfer occur locally on each phase and between both phases. Heterogeneous Combustion differs from catalysis as there is no focus to either phase individually but rather both examined simultaneously. In some materials, such as silicon carbide (SiC), oxide layers, SiO and SiO2, which form on the surface enable the adsorption of water vapor from the gas phase onto the solid lowering partial pressures. In this regime of combustion, thermal heat released from the combustion byproducts are transferred into the solid phase by convection; conduction and radiation both then conduct heat upstream (along with adverse convection within the gas phase). Heat is then convectively transferred to the unburnt reactants.
Industrial separation processes are technical procedures which are used in industry to separate a product from impurities or other products. The original mixture may either be a natural resource or the product of a chemical reaction.
[Clam chowder] represents a nice example of what is known as a heterogeneous material.
Homogeneity in physics.